Reactor for tracking catalyst nanoparticles in liquid at high temperature under a high-pressure gas phase with X-ray absorption spectroscopy

Nguyen, Luan; Tao, Franklin (Feng)

doi:10.1063/1.5003184

Title: Reactor for tracking catalyst nanoparticles in liquid at high temperature under a high-pressure gas phase with X-ray absorption spectroscopy

Journal Article · 21 February 2018 · Review of Scientific Instruments

DOI: https://doi.org/10.1063/1.5003184 · OSTI ID:1540128

Nguyen, Luan ^[1]; Tao, Franklin (Feng) ^[1]

Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering; Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemistry

Structure of catalyst nanoparticles dispersed in liquid phase at high temperature under gas phase of reactant(s) at higher pressure (≥5 bars) is important for fundamental understanding of catalytic reactions performed on these catalyst nanoparticles. Most structural characterizations of a catalyst performing catalysis in liquid at high temperature under gas phase at high pressure were performed in an ex situ condition in terms of characterizations before or after catalysis since, from technical point of view, access to the catalyst nanoparticles during catalysis in liquid phase at high temperature under high pressure reactant gas is challenging. Here we designed a reactor which allows us to perform structural characterization using X-ray absorption spectroscopy including X-ray absorption near edge structure spectroscopy and extended X-ray absorption fine structure spectroscopy to study catalyst nanoparticles under harsh catalysis conditions in terms of liquid up to 350 °C under gas phase with a pressure up to 50 bars. Finally, this reactor remains nanoparticles of a catalyst homogeneously dispersed in liquid during catalysis and X-ray absorption spectroscopy characterization.

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Research Organization:: Univ. of Kansas, Lawrence, KS (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0014561

OSTI ID:: 1540128

Journal Information:: Review of Scientific Instruments, Vol. 89, Issue 2; ISSN 0034-6748

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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References (39)

Restructuring Transition Metal Oxide Nanorods for 100% Selectivity in Reduction of Nitric Oxide with Carbon Monoxide Zhang, Shiran; Shan, Junjun; Zhu, Yuan Nano Letters, Vol. 13, Issue 7 https://doi.org/10.1021/nl4015292	journal	June 2013
In Situ Surface Chemistries and Catalytic Performances of Ceria Doped with Palladium, Platinum, and Rhodium in Methane Partial Oxidation for the Production of Syngas Zhu, Yuan; Zhang, Shiran; Shan, Jun-jun ACS Catalysis, Vol. 3, Issue 11 https://doi.org/10.1021/cs400070y	journal	October 2013
Chemistry at the square nanometer: reactivity at liquid/solid interfaces revealed with an STM Münninghoff, Joris A. W.; Elemans, Johannes A. A. W. Chemical Communications, Vol. 53, Issue 11 https://doi.org/10.1039/c6cc07862a	journal	January 2017
Direct catalytic conversion of methane to acetic acid in an aqueous medium Lin, Minren; Sen, Ayusman Nature, Vol. 368, Issue 6472 https://doi.org/10.1038/368613a0	journal	April 1994
Water–Gas Shift Reaction on Metal Nanoclusters Encapsulated in Mesoporous Ceria Studied with Ambient-Pressure X-ray Photoelectron Spectroscopy Wen, Cun; Zhu, Yuan; Ye, Yingchun ACS Nano, Vol. 6, Issue 10 https://doi.org/10.1021/nn303901q	journal	September 2012
Catalysis and In Situ Studies of Rh ₁ /Co ₃ O ₄ Nanorods in Reduction of NO with H ₂ Wang, Lei; Zhang, Shiran; Zhu, Yuan ACS Catalysis, Vol. 3, Issue 5 https://doi.org/10.1021/cs300816u	journal	April 2013
Formation of Second-Generation Nanoclusters on Metal Nanoparticles Driven by Reactant Gases Tao, Franklin Feng; Nguyen, Luan; Zhang, Shiran Nano Letters, Vol. 16, Issue 8 https://doi.org/10.1021/acs.nanolett.6b01718	journal	July 2016
The Sonogashira Reaction: A Booming Methodology in Synthetic Organic Chemistry ^† Chinchilla, Rafael; Nájera, Carmen Chemical Reviews, Vol. 107, Issue 3 https://doi.org/10.1021/cr050992x	journal	March 2007
Catalytic Performance and in Situ Surface Chemistry of Pure α-MnO ₂ Nanorods in Selective Reduction of NO and N ₂ O with CO Shan, Junjun; Zhu, Yuan; Zhang, Shiran The Journal of Physical Chemistry C, Vol. 117, Issue 16 https://doi.org/10.1021/jp4018103	journal	April 2013
Formation of Nanometer-Sized Surface Platinum Oxide Clusters on a Stepped Pt(557) Single Crystal Surface Induced by Oxygen: A High-Pressure STM and Ambient-Pressure XPS Study Zhu, Zhongwei; Tao, Franklin (Feng); Zheng, Fan Nano Letters, Vol. 12, Issue 3 https://doi.org/10.1021/nl204242s	journal	February 2012
Theoretical Form Factor, Attenuation, and Scattering Tabulation for Z =1–92 from E =1–10 eV to E =0.4–1.0 MeV Chantler, C. T. Journal of Physical and Chemical Reference Data, Vol. 24, Issue 1 https://doi.org/10.1063/1.555974	journal	January 1995
The Nature of Water Nucleation Sites on TiO ₂ (110) Surfaces Revealed by Ambient Pressure X-ray Photoelectron Spectroscopy Ketteler, Guido; Yamamoto, Susumu; Bluhm, Hendrik The Journal of Physical Chemistry C, Vol. 111, Issue 23 https://doi.org/10.1021/jp068606i	journal	June 2007
Tuning Catalytic Performance through a Single or Sequential Post-Synthesis Reaction(s) in a Gas Phase Shan, Junjun; Zhang, Shiran; Choksi, Tej ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02054	journal	December 2016
Design of a high-temperature and high-pressure liquid flow cell for x-ray absorption fine structure measurements under catalytic reaction conditions Kawai, Toshihide; Chun, Wang-Jae; Asakura, Kiyotaka Review of Scientific Instruments, Vol. 79, Issue 1 https://doi.org/10.1063/1.2829156	journal	January 2008
Visualization of Colloidal Nanocrystal Formation and Electrode–Electrolyte Interfaces in Liquids Using TEM Zeng, Zhiyuan; Zheng, Wenjing; Zheng, Haimei Accounts of Chemical Research, Vol. 50, Issue 8 https://doi.org/10.1021/acs.accounts.7b00161	journal	July 2017
Design of an in-house ambient pressure AP-XPS using a bench-top X-ray source and the surface chemistry of ceria under reaction conditions Tao, Franklin (Feng) Chemical Communications, Vol. 48, Issue 32 https://doi.org/10.1039/c2cc17715c	journal	January 2012
Microscopic models of PdZn alloy catalysts: structure and reactivity in methanol decomposition Neyman, Konstantin M.; Lim, Kok Hwa; Chen, Zhao-Xu Phys. Chem. Chem. Phys., Vol. 9, Issue 27 https://doi.org/10.1039/b700548b	journal	January 2007
EXAFS measurements of a working catalyst in the liquid phase: An in situ study of a Ni2P hydrodesulfurization catalyst Kawai, T.; Bando, K.; Lee, Y. Journal of Catalysis, Vol. 241, Issue 1 https://doi.org/10.1016/j.jcat.2006.03.024	journal	July 2006
Catalyst Chemical State during CO Oxidation Reaction on Cu(111) Studied with Ambient-Pressure X-ray Photoelectron Spectroscopy and Near Edge X-ray Adsorption Fine Structure Spectroscopy Eren, Baran; Heine, Christian; Bluhm, Hendrik Journal of the American Chemical Society, Vol. 137, Issue 34 https://doi.org/10.1021/jacs.5b07451	journal	August 2015
Action of bimetallic nanocatalysts under reaction conditions and during catalysis: evolution of chemistry from high vacuum conditions to reaction conditions Tao, Franklin (Feng); Zhang, Shiran; Nguyen, Luan Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35185d	journal	January 2012
Methanol Dehydrogenation and Formation of Carbonaceous Overlayers on Pd(111) Studied by High-Pressure SFG and XPS Spectroscopy Morkel, M.; Kaichev, V. V.; Rupprechter, G. The Journal of Physical Chemistry B, Vol. 108, Issue 34 https://doi.org/10.1021/jp048149a	journal	August 2004
Ambient pressure photoelectron spectroscopy: A new tool for surface science and nanotechnology Salmeron, M.; Schlogl, R. Surface Science Reports, Vol. 63, Issue 4 https://doi.org/10.1016/j.surfrep.2008.01.001	journal	April 2008
Water Adsorption on α-Fe ₂ O ₃ (0001) at near Ambient Conditions Yamamoto, Susumu; Kendelewicz, Tom; Newberg, John T. The Journal of Physical Chemistry C, Vol. 114, Issue 5 https://doi.org/10.1021/jp909876t	journal	January 2010
Transmission and fluorescence X-ray absorption spectroscopy cell/flow reactor for powder samples under vacuum or in reactive atmospheres Hoffman, A. S.; Debefve, L. M.; Bendjeriou-Sedjerari, A. Review of Scientific Instruments, Vol. 87, Issue 7 https://doi.org/10.1063/1.4958824	journal	July 2016
Conversion of Methane to Methanol with a Bent Mono(μ-oxo)dinickel Anchored on the Internal Surfaces of Micropores Shan, Junjun; Huang, Weixin; Nguyen, Luan Langmuir, Vol. 30, Issue 28 https://doi.org/10.1021/la501184b	journal	July 2014
WGS Catalysis and In Situ Studies of CoO _{1– x} , PtCo _n /Co ₃ O ₄ , and Pt _m Co _{m ′} /CoO _{1– x} Nanorod Catalysts Zhang, Shiran; Shan, Jun-jun; Zhu, Yuan Journal of the American Chemical Society, Vol. 135, Issue 22 https://doi.org/10.1021/ja401967y	journal	May 2013
In Situ Studies of Chemistry and Structure of Materials in Reactive Environments Tao, F.; Salmeron, M. Science, Vol. 331, Issue 6014 https://doi.org/10.1126/science.1197461	journal	January 2011
Catalytic Conversion of Carbon Dioxide to Methane on Ruthenium–Cobalt Bimetallic Nanocatalysts and Correlation between Surface Chemistry of Catalysts under Reaction Conditions and Catalytic Performances Zhu, Yuan; Zhang, Shiran; Ye, Yingchun ACS Catalysis, Vol. 2, Issue 11 https://doi.org/10.1021/cs3005242	journal	September 2012
Recycling of CO ₂ : Probing the Chemical State of the Ni(111) Surface during the Methanation Reaction with Ambient-Pressure X-Ray Photoelectron Spectroscopy Heine, Christian; Lechner, Barbara A. J.; Bluhm, Hendrik Journal of the American Chemical Society, Vol. 138, Issue 40 https://doi.org/10.1021/jacs.6b06939	journal	September 2016
Formation of hydroxyl and water layers on MgO films studied with ambient pressure XPS Newberg, John T.; Starr, David E.; Yamamoto, Susumu Surface Science, Vol. 605, Issue 1-2 https://doi.org/10.1016/j.susc.2010.10.004	journal	January 2011
Atomic-Scale Structural Evolution of Rh(110) during Catalysis Nguyen, Luan; Liu, Lacheng; Assefa, Solomon ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02006	journal	December 2016
Probing the Low-Temperature Water–Gas Shift Activity of Alkali-Promoted Platinum Catalysts Stabilized on Carbon Supports Zugic, Branko; Zhang, Shiran; Bell, David C. Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja4123889	journal	February 2014
In Situ X-ray Absorption Fine Structure Studies on the Effect of pH on Pt Electronic Density during Aqueous Phase Reforming of Glycerol Karim, Ayman M.; Howard, Christopher; Roberts, Benjamin ACS Catalysis, Vol. 2, Issue 11 https://doi.org/10.1021/cs3005049	journal	September 2012
Photoelectron spectroscopic study of CO and NO adsorption on Pd(100) surface under ambient pressure conditions Toyoshima, Ryo; Yoshida, Masaaki; Monya, Yuji Surface Science, Vol. 615 https://doi.org/10.1016/j.susc.2013.04.009	journal	September 2013
Bimetallic RhRe/C catalysts for the production of biomass-derived chemicals Chia, Mei; O’Neill, Brandon J.; Alamillo, Ricardo Journal of Catalysis, Vol. 308 https://doi.org/10.1016/j.jcat.2013.08.008	journal	December 2013
Low-Temperature Transformation of Methane to Methanol on Pd ₁ O ₄ Single Sites Anchored on the Internal Surface of Microporous Silicate Huang, Weixin; Zhang, Shiran; Tang, Yu Angewandte Chemie International Edition, Vol. 55, Issue 43 https://doi.org/10.1002/anie.201604708	journal	September 2016
Carbon−Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts Chemical Reviews, Vol. 107, Issue 1 https://doi.org/10.1021/cr0505674	journal	January 2007
State of Supported Pd during Catalysis in Water Chase, Zizwe A.; Fulton, John L.; Camaioni, Donald M. The Journal of Physical Chemistry C, Vol. 117, Issue 34 https://doi.org/10.1021/jp404772p	journal	August 2013
Development of a reaction cell for in-situ/operando studies of surface of a catalyst under a reaction condition and during catalysis Nguyen, Luan; Tao, Franklin (Feng) Review of Scientific Instruments, Vol. 87, Issue 6 https://doi.org/10.1063/1.4946877	journal	June 2016

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