Regional Similarities and NOx-Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States

Liu, Jun; Russell, Lynn M.; Ruggeri, Giulia; Takahama, Satoshi; Claflin, Megan S.; Ziemann, Paul J.; Pye, Havala O.  T.; Murphy, Benjamin N.; Xu, Lu; Ng, Nga L.; McKinney, Karena A.; Budisulistiorini, Sri Hapsari; Bertram, Timothy H.; Nenes, Athanasios; Surratt, Jason D.

doi:10.1029/2018jd028491

Title: Regional Similarities and NO_x-Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States

Journal Article · 04 August 2018 · Journal of Geophysical Research. Atmospheres

DOI: https://doi.org/10.1029/2018jd028491 · OSTI ID:1539758

^[1];

^[2]; Ruggeri, Giulia ^[3];

^[3];

^[4]; Ziemann, Paul J. ^[4];

^[5]; Murphy, Benjamin N. ^[5]; Xu, Lu ^[6];

^[7];

^[8]; Budisulistiorini, Sri Hapsari ^[9];

^[10]; Nenes, Athanasios ^[7];

^[11]

Univ. of California, San Diego, CA (United States). Scripps Inst. of Oceanography; DOE/OSTI
Univ. of California, San Diego, CA (United States). Scripps Inst. of Oceanography
Federal Inst. of Technology, Lausanne (Switzerland)
Univ. of Colorado, Boulder, CO (United States)
U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). National Exposure Research Laboratory
California Inst. of Technology (CalTech), Pasadena, CA (United States)
Georgia Inst. of Technology, Atlanta, GA (United States)
Harvard Univ., Cambridge, MA (United States)
Nanyang Technological Univ. (Singapore)
Univ. of Wisconsin, Madison, WI (United States)
Univ. of North Carolina, Chapel Hill, NC (United States)

During the 2013 Southern Oxidant and Aerosol Study, Fourier transform infrared spectroscopy (FTIR) and aerosol mass spectrometer (AMS) measurements of submicron mass were collected at Look Rock (LRK), Tennessee, and Centreville (CTR), Alabama. Carbon monoxide and submicron sulfate and organic mass concentrations were 15–60% higher at CTR than at LRK, but their time series had moderate correlations (r ~ 0.5). However, NO_x had no correlation (r = 0.08) between the two sites with nighttime-to-early-morning peaks 3–10 times higher at CTR than at LRK. Organic mass (OM) sources identified by FTIR Positive Matrix Factorization (PMF) had three very similar factors at both sites: fossil fuel combustion-related organic aerosols, mixed organic aerosols, and biogenic organic aerosols (BOA). The BOA spectrum from FTIR is similar (cosine similarity > 0.6) to that of lab-generated particle mass from the photochemical oxidation of both isoprene and monoterpenes under high NO_x conditions from chamber experiments. The BOA mass fraction was highest during the night at CTR but in the afternoon at LRK.AMS PMF resulted in two similar pairs of factors at both sites and a third nighttime NO_x-related factor (33% of OM) at CTR but a daytime nitrate-related factor (28% of OM) at LRK. NO_x was correlated with BOA and LO-OOA for NO_x concentrations higher than 1 ppb at both sites, producing 0.5 ± 0.1 μg/m³ for CTR-LO-OOA and 1.0 ± 0.3 μg/m³ for CTR-BOA additional biogenic OM for each 1 ppb increase of NO_x.

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Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0006431

OSTI ID:: 1539758

Journal Information:: Journal of Geophysical Research. Atmospheres, Journal Name: Journal of Geophysical Research. Atmospheres Journal Issue: 18 Vol. 123; ISSN 2169-897X

Publisher:: American Geophysical UnionCopyright Statement

Country of Publication:: United States

Language:: English

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Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning Murphy, Benjamin N.; Woody, Matthew C.; Jimenez, Jose L. Atmospheric Chemistry and Physics, Vol. 17, Issue 18 https://doi.org/10.5194/acp-17-11107-2017	journal	January 2017
Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol Ng, Nga Lee; Brown, Steven S.; Archibald, Alexander T. Atmospheric Chemistry and Physics, Vol. 17, Issue 3 https://doi.org/10.5194/acp-17-2103-2017	journal	January 2017
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Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia de Sá, Suzane S.; Palm, Brett B.; Campuzano-Jost, Pedro Atmospheric Chemistry and Physics, Vol. 17, Issue 11 https://doi.org/10.5194/acp-17-6611-2017	journal	January 2017
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of O_x, HO_x, NO_x and SO_x species Atkinson, R.; Baulch, D. L.; Cox, R. A. Atmospheric Chemistry and Physics, Vol. 4, Issue 6 https://doi.org/10.5194/acp-4-1461-2004	journal	January 2004
Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature) Guenther, A.; Karl, T.; Harley, P. Atmospheric Chemistry and Physics, Vol. 6, Issue 11 https://doi.org/10.5194/acp-6-3181-2006	journal	January 2006
Source apportionment of submicron organic aerosols at an urban site by factor analytical modelling of aerosol mass spectra Lanz, V. A.; Alfarra, M. R.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 7, Issue 6 https://doi.org/10.5194/acp-7-1503-2007	journal	January 2007
Effect of NO_x level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes Ng, N. L.; Chhabra, P. S.; Chan, A. W. H. Atmospheric Chemistry and Physics, Vol. 7, Issue 19 https://doi.org/10.5194/acp-7-5159-2007	journal	January 2007
Secondary organic aerosol (SOA) formation from reaction of isoprene with nitrate radicals (NO ₃ ) Ng, N. L.; Kwan, A. J.; Surratt, J. D. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4117-2008	journal	January 2008
Interpretation of organic components from Positive Matrix Factorization of aerosol mass spectrometric data Ulbrich, I. M.; Canagaratna, M. R.; Zhang, Q. Atmospheric Chemistry and Physics, Vol. 9, Issue 9 https://doi.org/10.5194/acp-9-2891-2009	journal	January 2009
The formation, properties and impact of secondary organic aerosol: current and emerging issues Hallquist, M.; Wenger, J. C.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-5155-2009	journal	January 2009
Characterization of organic ambient aerosol during MIRAGE 2006 on three platforms Gilardoni, S.; Liu, S.; Takahama, S. Atmospheric Chemistry and Physics, Vol. 9, Issue 15 https://doi.org/10.5194/acp-9-5417-2009	journal	January 2009
Aerosol mass spectrometer constraint on the global secondary organic aerosol budget Spracklen, D. V.; Jimenez, J. L.; Carslaw, K. S. Atmospheric Chemistry and Physics Discussions, Vol. 11, Issue 2 https://doi.org/10.5194/acpd-11-5699-2011	journal	January 2011
Biogenic and biomass burning organic aerosol in a boreal forest at Hyytiälä, Finland, during HUMPPA-COPEC 2010 Corrigan, A. L.; Russell, L. M.; Takahama, S. Atmospheric Chemistry and Physics Discussions, Vol. 13, Issue 6 https://doi.org/10.5194/acpd-13-16151-2013	journal	January 2013
On the link between hygroscopicity, volatility, and oxidation state of ambient and water-soluble aerosol in the Southeastern United States Cerully, K. M.; Bougiatioti, A.; Hite Jr., J. R. Atmospheric Chemistry and Physics Discussions, Vol. 14, Issue 22 https://doi.org/10.5194/acpd-14-30835-2014	journal	January 2014
Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee, ground site Budisulistiorini, S. H.; Li, X.; Bairai, S. T. Atmospheric Chemistry and Physics Discussions, Vol. 15, Issue 5 https://doi.org/10.5194/acpd-15-7365-2015	journal	January 2015
Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature) Guenther, A.; Karl, T.; Harley, P. Atmospheric Chemistry and Physics Discussions, Vol. 6, Issue 1 https://doi.org/10.5194/acpd-6-107-2006	journal	January 2006
Effect of NO_x level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes Ng, N. L.; Chhabra, P. S.; Chan, A. W. H. Atmospheric Chemistry and Physics Discussions https://doi.org/10.5194/acpd-7-10131-2007	journal	July 2007
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd-5-1471-2012	journal	January 2012
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development Discussions, Vol. 5, Issue 2 https://doi.org/10.5194/gmdd-5-1503-2012	journal	January 2012

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