Regional Similarities and NOx-Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States

Liu, Jun; Russell, Lynn M.; Ruggeri, Giulia; Takahama, Satoshi; Claflin, Megan S.; Ziemann, Paul J.; Pye, Havala O.  T.; Murphy, Benjamin N.; Xu, Lu; Ng, Nga L.; McKinney, Karena A.; Budisulistiorini, Sri Hapsari; Bertram, Timothy H.; Nenes, Athanasios; Surratt, Jason D.

doi:10.1029/2018jd028491

Title: Regional Similarities and NO_x-Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States

Journal Article · 04 August 2018 · Journal of Geophysical Research: Atmospheres

DOI: https://doi.org/10.1029/2018jd028491 · OSTI ID:1539758

^[1];

^[1]; Ruggeri, Giulia ^[2];

^[2];

^[3]; Ziemann, Paul J. ^[3];

^[4]; Murphy, Benjamin N. ^[4]; Xu, Lu ^[5];

^[6];

^[7]; Budisulistiorini, Sri Hapsari ^[8];

^[9]; Nenes, Athanasios ^[6];

^[10]

Univ. of California, San Diego, CA (United States). Scripps Inst. of Oceanography
Federal Inst. of Technology, Lausanne (Switzerland)
Univ. of Colorado, Boulder, CO (United States)
U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). National Exposure Research Laboratory
California Inst. of Technology (CalTech), Pasadena, CA (United States)
Georgia Inst. of Technology, Atlanta, GA (United States)
Harvard Univ., Cambridge, MA (United States)
Nanyang Technological Univ. (Singapore)
Univ. of Wisconsin, Madison, WI (United States)
Univ. of North Carolina, Chapel Hill, NC (United States)

Abstract During the 2013 Southern Oxidant and Aerosol Study, Fourier transform infrared spectroscopy (FTIR) and aerosol mass spectrometer (AMS) measurements of submicron mass were collected at Look Rock (LRK), Tennessee, and Centreville (CTR), Alabama. Carbon monoxide and submicron sulfate and organic mass concentrations were 15–60% higher at CTR than at LRK, but their time series had moderate correlations ( r ~ 0.5). However, NO _x had no correlation ( r = 0.08) between the two sites with nighttime‐to‐early‐morning peaks 3–10 times higher at CTR than at LRK. Organic mass (OM) sources identified by FTIR Positive Matrix Factorization (PMF) had three very similar factors at both sites: fossil fuel combustion‐related organic aerosols, mixed organic aerosols, and biogenic organic aerosols (BOA). The BOA spectrum from FTIR is similar (cosine similarity > 0.6) to that of lab‐generated particle mass from the photochemical oxidation of both isoprene and monoterpenes under high NO _x conditions from chamber experiments. The BOA mass fraction was highest during the night at CTR but in the afternoon at LRK. AMS PMF resulted in two similar pairs of factors at both sites and a third nighttime NO _x ‐related factor (33% of OM) at CTR but a daytime nitrate‐related factor (28% of OM) at LRK. NO _x was correlated with BOA and LO‐OOA for NO _x concentrations higher than 1 ppb at both sites, producing 0.5 ± 0.1 μ g/m ³ for CTR‐LO‐OOA and 1.0 ± 0.3 μ g/m ³ for CTR‐BOA additional biogenic OM for each 1 ppb increase of NO _x .

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Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0006431; DE‐SC0006431

OSTI ID:: 1539758

Alternate ID(s):: OSTI ID: 1472149

Journal Information:: Journal of Geophysical Research: Atmospheres, Vol. 123, Issue 18; ISSN 2169-897X

Publisher:: American Geophysical UnionCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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