Double-ionization satellites in the x-ray emission spectrum of Ni metal
Abstract
We report measurements of the nonresonant x-ray emission spectroscopy (XES) from Ni metal in an energy range spanning the Kβ diagram line, valence-to-core emission, and double-ionization (DI) satellites that appear beyond the single-particle Fermi level. We make special use of a laboratory-based x-ray spectrometer capable of both x-ray emission and x-ray absorption measurements to accurately align the XES and x-ray absorption spectra to a common energy scale. The careful alignment of energy scales is requisite for correction of the strong sample absorption of DI fluorescence above the Ni K-edge energy. The successful correction of absorption effects allows a determination of the branching ratios for the [1s3d], [1s3p] , [1s2p] and [1s2s] satellites with respect to their corresponding diagram lines. We compare our results with other work, finding good agreement with prior experiments and with theoretical calculations in the multiconfiguration Dirac-Fock framework.
- Authors:
-
- Univ. of Washington, Seattle, WA (United States)
- Publication Date:
- Research Org.:
- Univ. of Washington, Seattle, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Fusion Energy Sciences (FES)
- OSTI Identifier:
- 1535754
- Alternate Identifier(s):
- OSTI ID: 1378411
- Grant/Contract Number:
- FG02-97ER45623; SC0002194; SC0016251
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review A
- Additional Journal Information:
- Journal Volume: 96; Journal Issue: 3; Journal ID: ISSN 2469-9926
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; Optics; Physics; Atomic spectra; Electronic transitions
Citation Formats
Valenza, Ryan A., Jahrman, Evan P., Kas, Joshua J., and Seidler, Gerald T. Double-ionization satellites in the x-ray emission spectrum of Ni metal. United States: N. p., 2017.
Web. doi:10.1103/physreva.96.032504.
Valenza, Ryan A., Jahrman, Evan P., Kas, Joshua J., & Seidler, Gerald T. Double-ionization satellites in the x-ray emission spectrum of Ni metal. United States. https://doi.org/10.1103/physreva.96.032504
Valenza, Ryan A., Jahrman, Evan P., Kas, Joshua J., and Seidler, Gerald T. Tue .
"Double-ionization satellites in the x-ray emission spectrum of Ni metal". United States. https://doi.org/10.1103/physreva.96.032504. https://www.osti.gov/servlets/purl/1535754.
@article{osti_1535754,
title = {Double-ionization satellites in the x-ray emission spectrum of Ni metal},
author = {Valenza, Ryan A. and Jahrman, Evan P. and Kas, Joshua J. and Seidler, Gerald T.},
abstractNote = {We report measurements of the nonresonant x-ray emission spectroscopy (XES) from Ni metal in an energy range spanning the Kβ diagram line, valence-to-core emission, and double-ionization (DI) satellites that appear beyond the single-particle Fermi level. We make special use of a laboratory-based x-ray spectrometer capable of both x-ray emission and x-ray absorption measurements to accurately align the XES and x-ray absorption spectra to a common energy scale. The careful alignment of energy scales is requisite for correction of the strong sample absorption of DI fluorescence above the Ni K-edge energy. The successful correction of absorption effects allows a determination of the branching ratios for the [1s3d], [1s3p] , [1s2p] and [1s2s] satellites with respect to their corresponding diagram lines. We compare our results with other work, finding good agreement with prior experiments and with theoretical calculations in the multiconfiguration Dirac-Fock framework.},
doi = {10.1103/physreva.96.032504},
journal = {Physical Review A},
number = 3,
volume = 96,
place = {United States},
year = {Tue Sep 05 00:00:00 EDT 2017},
month = {Tue Sep 05 00:00:00 EDT 2017}
}
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