Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H2/CO2 mixture separations at high pressure and high temperature

Perez, Edson V.; Kalaw, Grace J.D.; Ferraris, John P.; Balkus, Kenneth J.; Musselman, Inga H.

doi:10.1016/j.memsci.2017.02.003

Title: Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H₂/CO₂ mixture separations at high pressure and high temperature

Journal Article · 02 February 2017 · Journal of Membrane Science

DOI: https://doi.org/10.1016/j.memsci.2017.02.003 · OSTI ID:1534104

Perez, Edson V. ^[1]; Kalaw, Grace J.D. ^[2]; Ferraris, John P. ^[2]; Balkus, Kenneth J. ^[2]; Musselman, Inga H. ^[2]

University of Texas at Dallas, Richardson, TX (United States); DOE/OSTI
University of Texas at Dallas, Richardson, TX (United States)

In this report VTEC™ PI-1388 and 20 wt% (Al) NH₂-MIL-53/VTEC™ PI-1388 mixed-matrix membranes (MMMs) with different thicknesses were tested for gas permeation of H2 and CO₂ from 5 to 30 bar and from 35 to 300 °C. 50/50 H₂/CO₂ mixtures were also tested at 30 bar and 250 °C with stage cuts that ranged from 0.05 to 1. Gas permeation data show that the affinity of (Al) NH₂-MIL-53 for VTEC™ PI-1388 is strong enough to perform gas separations under these conditions. At 30 bar and at temperatures above 200 °C, the performance of the MMMs for H₂/CO₂ separation improved significantly with increasing temperature. Specifically, the H₂ permeability of the MMM at 300 °C increased by 70% with respect to that of VTEC™ PI-1388 (VTEC™ PI-1388: H₂ = 85 Barrer, H₂/CO₂ = 4.0; MMM: H₂ = 144 Barrer, H₂/CO₂ = 5.8). Gas mixture separations using VTEC™ PI-1388 and the MMM depended on the stage cut and reached a maximum H₂/CO₂ separation of 7.2 for VTEC™ PI-1388 and 7.5 for the MMM at a stage cut of 0.05.

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Research Organization:: University of Texas at Dallas, Richardson, TX (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)

Grant/Contract Number:: FE0001293; NT0007636

OSTI ID:: 1534104

Journal Information:: Journal of Membrane Science, Journal Name: Journal of Membrane Science Journal Issue: C Vol. 530; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Amine-functionalized (Al) MIL-53/VTEC™ mixed-matrix membranes for H₂/CO₂ mixture separations at high pressure and high temperature