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Title: Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li 1.25 Nb 0.25 Mn 0.5 O 2

Abstract

We demonstrate short-range ordering in Li-ion battery material Li 1.25 Nb 0.25 Mn 0.5 O 2 , and identify its local structure and correlation length—which is sensitive to synthesis conditions and has important consequences for the material's electrochemistry.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [2]; ORCiD logo [3];  [1]
  1. Department of Chemistry, University of Cambridge, Cambridge, UK
  2. School of Chemistry, University of Nottingham, University Park, Nottingham, UK
  3. Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1532792
Grant/Contract Number:  
SC0012583
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 55 Journal Issue: 61; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Jones, Michael A., Reeves, Philip J., Seymour, Ieuan D., Cliffe, Matthew J., Dutton, Siân E., and Grey, Clare P. Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li 1.25 Nb 0.25 Mn 0.5 O 2. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC04250D.
Jones, Michael A., Reeves, Philip J., Seymour, Ieuan D., Cliffe, Matthew J., Dutton, Siân E., & Grey, Clare P. Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li 1.25 Nb 0.25 Mn 0.5 O 2. United Kingdom. doi:10.1039/C9CC04250D.
Jones, Michael A., Reeves, Philip J., Seymour, Ieuan D., Cliffe, Matthew J., Dutton, Siân E., and Grey, Clare P. Thu . "Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li 1.25 Nb 0.25 Mn 0.5 O 2". United Kingdom. doi:10.1039/C9CC04250D.
@article{osti_1532792,
title = {Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li 1.25 Nb 0.25 Mn 0.5 O 2},
author = {Jones, Michael A. and Reeves, Philip J. and Seymour, Ieuan D. and Cliffe, Matthew J. and Dutton, Siân E. and Grey, Clare P.},
abstractNote = {We demonstrate short-range ordering in Li-ion battery material Li 1.25 Nb 0.25 Mn 0.5 O 2 , and identify its local structure and correlation length—which is sensitive to synthesis conditions and has important consequences for the material's electrochemistry.},
doi = {10.1039/C9CC04250D},
journal = {Chemical Communications},
number = 61,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {7}
}

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Works referenced in this record:

A profile refinement method for nuclear and magnetic structures
journal, June 1969