skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes

Authors:
 [1];  [2];  [3];  [1];  [4];  [2];  [2];  [2];  [1];  [1];  [1];  [1];  [3];  [2];  [3];  [1];  [1]; ORCiD logo [1]
  1. Energy and Environment DirectoratePacific Northwest National Laboratory Richland WA 99354 USA
  2. Environmental Molecular Sciences LaboratoryPacific Northwest National Laboratory Richland WA 99354 USA
  3. Physical and Computational Sciences DirectoratePacific Northwest National Laboratory Richland WA 99354 USA
  4. Energy and Environment DirectoratePacific Northwest National Laboratory Richland WA 99354 USA, Department of Energy EngineeringHanyang University Seoul 04763 South Korea
Publication Date:
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Science (SC), Biological and Environmental Research (BER)
OSTI Identifier:
1532577
Grant/Contract Number:  
DE‐AC05‐76RLO1830
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 31; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Jia, Haiping, Zou, Lianfeng, Gao, Peiyuan, Cao, Xia, Zhao, Wengao, He, Yang, Engelhard, Mark H., Burton, Sarah D., Wang, Hui, Ren, Xiaodi, Li, Qiuyan, Yi, Ran, Zhang, Xin, Wang, Chongmin, Xu, Zhijie, Li, Xiaolin, Zhang, Ji‐Guang, and Xu, Wu. High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes. Germany: N. p., 2019. Web. doi:10.1002/aenm.201900784.
Jia, Haiping, Zou, Lianfeng, Gao, Peiyuan, Cao, Xia, Zhao, Wengao, He, Yang, Engelhard, Mark H., Burton, Sarah D., Wang, Hui, Ren, Xiaodi, Li, Qiuyan, Yi, Ran, Zhang, Xin, Wang, Chongmin, Xu, Zhijie, Li, Xiaolin, Zhang, Ji‐Guang, & Xu, Wu. High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes. Germany. doi:10.1002/aenm.201900784.
Jia, Haiping, Zou, Lianfeng, Gao, Peiyuan, Cao, Xia, Zhao, Wengao, He, Yang, Engelhard, Mark H., Burton, Sarah D., Wang, Hui, Ren, Xiaodi, Li, Qiuyan, Yi, Ran, Zhang, Xin, Wang, Chongmin, Xu, Zhijie, Li, Xiaolin, Zhang, Ji‐Guang, and Xu, Wu. Tue . "High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes". Germany. doi:10.1002/aenm.201900784.
@article{osti_1532577,
title = {High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes},
author = {Jia, Haiping and Zou, Lianfeng and Gao, Peiyuan and Cao, Xia and Zhao, Wengao and He, Yang and Engelhard, Mark H. and Burton, Sarah D. and Wang, Hui and Ren, Xiaodi and Li, Qiuyan and Yi, Ran and Zhang, Xin and Wang, Chongmin and Xu, Zhijie and Li, Xiaolin and Zhang, Ji‐Guang and Xu, Wu},
abstractNote = {},
doi = {10.1002/aenm.201900784},
journal = {Advanced Energy Materials},
number = 31,
volume = 9,
place = {Germany},
year = {2019},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/aenm.201900784

Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

High performance silicon nanoparticle anode in fluoroethylene carbonate-based electrolyte for Li-ion batteries
journal, January 2012

  • Lin, Yong-Mao; Klavetter, Kyle C.; Abel, Paul R.
  • Chemical Communications, Vol. 48, Issue 58
  • DOI: 10.1039/c2cc31712e

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Projector augmented-wave method
journal, December 1994


Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016

  • Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12032

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

  • Chan, Candace K.; Peng, Hailin; Liu, Gao
  • Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
  • DOI: 10.1038/nnano.2007.411

Comparative Study of Fluoroethylene Carbonate and Vinylene Carbonate for Silicon Anodes in Lithium Ion Batteries
journal, January 2014

  • Nguyen, Cao Cuong; Lucht, Brett L.
  • Journal of The Electrochemical Society, Vol. 161, Issue 12
  • DOI: 10.1149/2.0731412jes

Safety mechanisms in lithium-ion batteries
journal, April 2006


Battery materials for ultrafast charging and discharging
journal, March 2009

  • Kang, Byoungwoo; Ceder, Gerbrand
  • Nature, Vol. 458, Issue 7235, p. 190-193
  • DOI: 10.1038/nature07853

Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries
journal, March 2014

  • Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro
  • Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046
  • DOI: 10.1021/ja412807w

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015


Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries
journal, December 2008

  • Kim, Hyunjung; Han, Byunghee; Choo, Jaebum
  • Angewandte Chemie International Edition, Vol. 47, Issue 52, p. 10151-10154
  • DOI: 10.1002/anie.200804355

Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, January 2018


Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014


Stable cycling of high-voltage lithium metal batteries in ether electrolytes
journal, July 2018


Insight into the interaction between layered lithium-rich oxide and additive-containing electrolyte
journal, February 2017


Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries
journal, July 2017


High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

  • Chen, Shuru; Zheng, Jianming; Mei, Donghai
  • Advanced Materials, Vol. 30, Issue 21
  • DOI: 10.1002/adma.201706102

Characteristics of lithium-ion battery with non-flammable electrolyte
journal, April 2009


Self-healing SEI enables full-cell cycling of a silicon-majority anode with a coulombic efficiency exceeding 99.9%
journal, January 2017

  • Jin, Yang; Li, Sa; Kushima, Akihiro
  • Energy & Environmental Science, Vol. 10, Issue 2
  • DOI: 10.1039/C6EE02685K

General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes
journal, March 2014

  • Yamada, Yuki; Usui, Kenji; Chiang, Ching Hua
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 14, p. 10892-10899
  • DOI: 10.1021/am5001163

Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
journal, January 2007


Novel Three-Dimensional Mesoporous Silicon for High Power Lithium-Ion Battery Anode Material
journal, October 2011

  • Jia, Haiping; Gao, Pengfei; Yang, Jun
  • Advanced Energy Materials, Vol. 1, Issue 6
  • DOI: 10.1002/aenm.201100485

Reversible Storage of Lithium in Silver-Coated Three-Dimensional Macroporous Silicon
journal, May 2010


Erratum: High-performance lithium-ion anodes using a hierarchical bottom-up approach
journal, March 2010

  • Magasinski, A.; Dixon, P.; Hertzberg, B.
  • Nature Materials, Vol. 9, Issue 5
  • DOI: 10.1038/nmat2749

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries
journal, August 2018


High Voltage Operation of Ni-Rich NMC Cathodes Enabled by Stable Electrode/Electrolyte Interphases
journal, March 2018

  • Zhao, Wengao; Zheng, Jianming; Zou, Lianfeng
  • Advanced Energy Materials, Vol. 8, Issue 19
  • DOI: 10.1002/aenm.201800297

Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes
journal, December 2011

  • Etacheri, Vinodkumar; Haik, Ortal; Goffer, Yossi
  • Langmuir, Vol. 28, Issue 1
  • DOI: 10.1021/la203712s

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Fire-extinguishing organic electrolytes for safe batteries
journal, November 2017


High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes
journal, August 2018


Lithium-ion batteries. A look into the future
journal, January 2011

  • Scrosati, Bruno; Hassoun, Jusef; Sun, Yang-Kook
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01388b

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
journal, July 2018


A Critical Size of Silicon Nano-Anodes for Lithium Rechargeable Batteries
journal, March 2010

  • Kim, Hyejung; Seo, Minho; Park, Mi-Hee
  • Angewandte Chemie International Edition, Vol. 49, Issue 12
  • DOI: 10.1002/anie.200906287

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011


Stabilization of Li Metal Anode in DMSO-Based Electrolytes via Optimization of Salt-Solvent Coordination for Li-O 2 Batteries
journal, March 2017


A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes
journal, February 2014


A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
journal, May 2012

  • Liu, Nian; Wu, Hui; McDowell, Matthew T.
  • Nano Letters, Vol. 12, Issue 6
  • DOI: 10.1021/nl3014814

Scalable synthesis of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries
journal, August 2016


Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
journal, January 2004

  • Obrovac, M. N.; Christensen, Leif
  • Electrochemical and Solid-State Letters, Vol. 7, Issue 5
  • DOI: 10.1149/1.1652421

High rate and stable cycling of lithium metal anode
journal, February 2015

  • Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7362

Understanding Li + –Solvent Interaction in Nonaqueous Carbonate Electrolytes with 17 O NMR
journal, May 2013

  • Bogle, Xavier; Vazquez, Rafael; Greenbaum, Steven
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 10
  • DOI: 10.1021/jz400661k