High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes

Jia, Haiping; Zou, Lianfeng; Gao, Peiyuan; Cao, Xia; Zhao, Wengao; He, Yang; Engelhard, Mark H.; Burton, Sarah D.; Wang, Hui; Ren, Xiaodi; Li, Qiuyan; Yi, Ran; Zhang, Xin; Wang, Chongmin; Xu, Zhijie; Li, Xiaolin; Zhang, Ji‐Guang; Xu, Wu

doi:10.1002/aenm.201900784

Title: High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes

Authors:

Jia, Haiping ^[1]; Zou, Lianfeng ^[2]; Gao, Peiyuan ^[3]; Cao, Xia ^[1]; Zhao, Wengao ^[4]; He, Yang ^[2]; Engelhard, Mark H. ^[2]; Burton, Sarah D. ^[2]; Wang, Hui ^[1]; Ren, Xiaodi ^[1]; Li, Qiuyan ^[1]; Yi, Ran ^[1]; Zhang, Xin ^[3]; Wang, Chongmin ^[2]; Xu, Zhijie ^[3]; Li, Xiaolin ^[1]; Zhang, Ji‐Guang ^[1];

^[1]

Energy and Environment Directorate Pacific Northwest National Laboratory Richland WA 99354 USA
Environmental Molecular Sciences Laboratory Pacific Northwest National Laboratory Richland WA 99354 USA
Physical and Computational Sciences Directorate Pacific Northwest National Laboratory Richland WA 99354 USA
Energy and Environment Directorate Pacific Northwest National Laboratory Richland WA 99354 USA, Department of Energy Engineering Hanyang University Seoul 04763 South Korea

Publication Date:: 2019-07-09

Sponsoring Org.:: USDOE

OSTI Identifier:: 1532577

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Energy Materials

Additional Journal Information:: Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 31; Journal ID: ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Jia, Haiping, Zou, Lianfeng, Gao, Peiyuan, Cao, Xia, Zhao, Wengao, He, Yang, Engelhard, Mark H., Burton, Sarah D., Wang, Hui, Ren, Xiaodi, Li, Qiuyan, Yi, Ran, Zhang, Xin, Wang, Chongmin, Xu, Zhijie, Li, Xiaolin, Zhang, Ji‐Guang, and Xu, Wu. High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes.  Germany: N. p., 2019. 
Web.  doi:10.1002/aenm.201900784.

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                    Jia, Haiping, Zou, Lianfeng, Gao, Peiyuan, Cao, Xia, Zhao, Wengao, He, Yang, Engelhard, Mark H., Burton, Sarah D., Wang, Hui, Ren, Xiaodi, Li, Qiuyan, Yi, Ran, Zhang, Xin, Wang, Chongmin, Xu, Zhijie, Li, Xiaolin, Zhang, Ji‐Guang, & Xu, Wu. High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes.  Germany.  https://doi.org/10.1002/aenm.201900784

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                    Jia, Haiping, Zou, Lianfeng, Gao, Peiyuan, Cao, Xia, Zhao, Wengao, He, Yang, Engelhard, Mark H., Burton, Sarah D., Wang, Hui, Ren, Xiaodi, Li, Qiuyan, Yi, Ran, Zhang, Xin, Wang, Chongmin, Xu, Zhijie, Li, Xiaolin, Zhang, Ji‐Guang, and Xu, Wu. Tue .  
"High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes".  Germany.  https://doi.org/10.1002/aenm.201900784.

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@article{osti_1532577,

  title        = {High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes},

  author       = {Jia, Haiping and Zou, Lianfeng and Gao, Peiyuan and Cao, Xia and Zhao, Wengao and He, Yang and Engelhard, Mark H. and Burton, Sarah D. and Wang, Hui and Ren, Xiaodi and Li, Qiuyan and Yi, Ran and Zhang, Xin and Wang, Chongmin and Xu, Zhijie and Li, Xiaolin and Zhang, Ji‐Guang and Xu, Wu},

  abstractNote = {},

  doi          = {10.1002/aenm.201900784},

  journal      = {Advanced Energy Materials},

  number       = 31,

  volume       = 9,

  place        = {Germany},

  year         = {2019},

  month        = {7}

}

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https://doi.org/10.1002/aenm.201900784

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Cited by: 12 works

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Title: High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes

Citation Formats

High performance silicon nanoparticle anode in fluoroethylene carbonate-based electrolyte for Li-ion batteries journal, January 2012

Generalized Gradient Approximation Made Simple journal, October 1996

Projector augmented-wave method journal, December 1994

Superconcentrated electrolytes for a high-voltage lithium-ion battery journal, June 2016

High-performance lithium battery anodes using silicon nanowires journal, December 2007

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Comparative Study of Fluoroethylene Carbonate and Vinylene Carbonate for Silicon Anodes in Lithium Ion Batteries journal, January 2014

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Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes journal, January 2018

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Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive journal, March 2015

Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries journal, July 2017

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes journal, March 2018

Characteristics of lithium-ion battery with non-flammable electrolyte journal, April 2009

Self-healing SEI enables full-cell cycling of a silicon-majority anode with a coulombic efficiency exceeding 99.9% journal, January 2017

General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes journal, March 2014

Influence of the Discretization Methods on the Distribution of Relaxation Times Deconvolution: Implementing Radial Basis Functions with DRTtools journal, December 2015

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Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries journal, August 2018

High Voltage Operation of Ni-Rich NMC Cathodes Enabled by Stable Electrode/Electrolyte Interphases journal, March 2018

Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes journal, December 2011

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Fire-extinguishing organic electrolytes for safe batteries journal, November 2017

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Structural Changes in Silicon Anodes during Lithium Insertion/Extraction journal, January 2004

High rate and stable cycling of lithium metal anode journal, February 2015

Understanding Li + –Solvent Interaction in Nonaqueous Carbonate Electrolytes with 17 O NMR journal, May 2013

High performance silicon nanoparticle anode in fluoroethylene carbonate-based electrolyte for Li-ion batteries
journal, January 2012

Generalized Gradient Approximation Made Simple
journal, October 1996

Projector augmented-wave method
journal, December 1994

Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016

High-performance lithium battery anodes using silicon nanowires
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Investigation of the Solid Electrolyte Interphase Formation at Graphite Anodes in Lithium-Ion Batteries with Electrochemical Impedance Spectroscopy
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journal, February 2017

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Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries
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journal, November 2015

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journal, December 2008

Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, January 2018

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014

Stable cycling of high-voltage lithium metal batteries in ether electrolytes
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Insight into the interaction between layered lithium-rich oxide and additive-containing electrolyte
journal, February 2017

Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive
journal, March 2015

Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries
journal, July 2017

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

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journal, April 2009

Self-healing SEI enables full-cell cycling of a silicon-majority anode with a coulombic efficiency exceeding 99.9%
journal, January 2017

General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes
journal, March 2014

Influence of the Discretization Methods on the Distribution of Relaxation Times Deconvolution: Implementing Radial Basis Functions with DRTtools
journal, December 2015

Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
journal, January 2007

Novel Three-Dimensional Mesoporous Silicon for High Power Lithium-Ion Battery Anode Material
journal, October 2011

Reversible Storage of Lithium in Silver-Coated Three-Dimensional Macroporous Silicon
journal, May 2010

Erratum: High-performance lithium-ion anodes using a hierarchical bottom-up approach
journal, March 2010

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries
journal, August 2018

High Voltage Operation of Ni-Rich NMC Cathodes Enabled by Stable Electrode/Electrolyte Interphases
journal, March 2018

Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes
journal, December 2011

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Fire-extinguishing organic electrolytes for safe batteries
journal, November 2017

High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes
journal, August 2018

Lithium-ion batteries. A look into the future
journal, January 2011

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
journal, July 2018

A Critical Size of Silicon Nano-Anodes for Lithium Rechargeable Batteries
journal, March 2010

Building better batteries
journal, February 2008

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011

Stabilization of Li Metal Anode in DMSO-Based Electrolytes via Optimization of Salt-Solvent Coordination for Li-O ₂ Batteries
journal, March 2017

A novel approach to synthesize micrometer-sized porous silicon as a high performance anode for lithium-ion batteries
journal, August 2018

A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes
journal, February 2014

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
journal, May 2012

Scalable synthesis of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries
journal, August 2016

Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
journal, January 2004

High rate and stable cycling of lithium metal anode
journal, February 2015

Understanding Li ⁺ –Solvent Interaction in Nonaqueous Carbonate Electrolytes with ¹⁷ O NMR
journal, May 2013