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Title: Spectroscopic, thermodynamic and computational evidence of the locations of the FADs in the nitrogen fixation-associated electron transfer flavoprotein

Abstract

Experiments and computation establish the locations of the two flavins whose contrasting reactivities produce electron bifurcation in ETFs. They confirm the accepted model and support homologies & distinctions between bifurcating and canonical ETFs.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [3]
  1. Dept. Chemistry, University of Kentucky, Lexington, USA
  2. Max Volmer Laboratorum für Biophysikalische Chemie, Technische Universität – Berlin, 10623 Berlin, Germany
  3. Dept. Chemistry, University of Kentucky, Lexington, USA, Max Volmer Laboratorum für Biophysikalische Chemie
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1532431
Grant/Contract Number:  
SC0012518
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Mohamed-Raseek, Nishya, Duan, H. Diessel, Hildebrandt, Peter, Mroginski, Maria Andrea, and Miller, Anne-Frances. Spectroscopic, thermodynamic and computational evidence of the locations of the FADs in the nitrogen fixation-associated electron transfer flavoprotein. United Kingdom: N. p., 2019. Web. doi:10.1039/C9SC00942F.
Mohamed-Raseek, Nishya, Duan, H. Diessel, Hildebrandt, Peter, Mroginski, Maria Andrea, & Miller, Anne-Frances. Spectroscopic, thermodynamic and computational evidence of the locations of the FADs in the nitrogen fixation-associated electron transfer flavoprotein. United Kingdom. doi:10.1039/C9SC00942F.
Mohamed-Raseek, Nishya, Duan, H. Diessel, Hildebrandt, Peter, Mroginski, Maria Andrea, and Miller, Anne-Frances. Tue . "Spectroscopic, thermodynamic and computational evidence of the locations of the FADs in the nitrogen fixation-associated electron transfer flavoprotein". United Kingdom. doi:10.1039/C9SC00942F.
@article{osti_1532431,
title = {Spectroscopic, thermodynamic and computational evidence of the locations of the FADs in the nitrogen fixation-associated electron transfer flavoprotein},
author = {Mohamed-Raseek, Nishya and Duan, H. Diessel and Hildebrandt, Peter and Mroginski, Maria Andrea and Miller, Anne-Frances},
abstractNote = {Experiments and computation establish the locations of the two flavins whose contrasting reactivities produce electron bifurcation in ETFs. They confirm the accepted model and support homologies & distinctions between bifurcating and canonical ETFs.},
doi = {10.1039/C9SC00942F},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SC00942F

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Works referenced in this record:

Self‐consistent molecular orbital methods. XXIII. A polarization‐type basis set for second‐row elements
journal, October 1982

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Density‐functional thermochemistry. III. The role of exact exchange
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