Reactivity of lithium and platinum at elevated densities

Binns, Jack; Marqués, Miriam; Dalladay-Simpson, Philip; Turnbull, Robin; Frost, Mungo; Gregoryanz, Eugene; Howie, Ross T.

doi:10.1103/physrevb.99.220101

Title: Reactivity of lithium and platinum at elevated densities

Journal Article · 10 June 2019 · Physical Review B

DOI: https://doi.org/10.1103/physrevb.99.220101 · OSTI ID:1532403

Binns, Jack ^[1]; Marqués, Miriam ^[2]; Dalladay-Simpson, Philip ^[1]; Turnbull, Robin ^[2]; Frost, Mungo ^[3]; Gregoryanz, Eugene ^[4]; Howie, Ross T. ^[1]

Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai (People's Republic of China)
The Univ. of Edinburgh, Edinburgh (United Kingdom)
The Univ. of Edinburgh, Edinburgh (United Kingdom); SLAC National Accelerator Lab., Menlo Park, CA (United States)
The Univ. of Edinburgh, Edinburgh (United Kingdom); Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai (People's Republic of China)

Through a series of x-ray diffraction experiments, combined with first-principles calculations, we show that the nobility of platinum can be overcome, reacting with lithium under compression at room temperature. Pressures as low as 2.3 GPa lead to the synthesis of Li₁₁Pt₂, exhibiting the highest lithium content of any known intermetallic compound. Above 16 GPa, Li₁₁Pt₂ expels Li and transforms to Li₂Pt. As a result, this change is accompanied by a transformation in bonding characterized by the formation of one-dimensional Pt-Pt bonds with increasingly covalent character at higher densities.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515; EP/P022561/1; EP/L504956/1; EP/M506515/1

OSTI ID:: 1532403

Journal Information:: Physical Review B, Vol. 99, Issue 22; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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