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Title: Facet-selective adsorption of Fe( ii ) on hematite visualized by nanoscale secondary ion mass spectrometry

Abstract

Novel isotopic labelling and imaging techniques are used to directly observe the autocatalytic reaction and facet-selective adsorption of Fe( ii ) onto individual hematite (Fe 2 O 3 ) crystallites.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Physical Sciences Division, Pacific Northwest National Laboratory, Richland, USA
  2. Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, Richland, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1531183
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Environmental Science: Nano
Additional Journal Information:
Journal Name: Environmental Science: Nano Journal Volume: 6 Journal Issue: 8; Journal ID: ISSN 2051-8153
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Taylor, Sandra D., Kovarik, Libor, Cliff, John B., and Rosso, Kevin M. Facet-selective adsorption of Fe( ii ) on hematite visualized by nanoscale secondary ion mass spectrometry. United Kingdom: N. p., 2019. Web. doi:10.1039/C9EN00562E.
Taylor, Sandra D., Kovarik, Libor, Cliff, John B., & Rosso, Kevin M. Facet-selective adsorption of Fe( ii ) on hematite visualized by nanoscale secondary ion mass spectrometry. United Kingdom. doi:10.1039/C9EN00562E.
Taylor, Sandra D., Kovarik, Libor, Cliff, John B., and Rosso, Kevin M. Thu . "Facet-selective adsorption of Fe( ii ) on hematite visualized by nanoscale secondary ion mass spectrometry". United Kingdom. doi:10.1039/C9EN00562E.
@article{osti_1531183,
title = {Facet-selective adsorption of Fe( ii ) on hematite visualized by nanoscale secondary ion mass spectrometry},
author = {Taylor, Sandra D. and Kovarik, Libor and Cliff, John B. and Rosso, Kevin M.},
abstractNote = {Novel isotopic labelling and imaging techniques are used to directly observe the autocatalytic reaction and facet-selective adsorption of Fe( ii ) onto individual hematite (Fe 2 O 3 ) crystallites.},
doi = {10.1039/C9EN00562E},
journal = {Environmental Science: Nano},
number = 8,
volume = 6,
place = {United Kingdom},
year = {2019},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9EN00562E

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Cited by: 2 works
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Works referenced in this record:

Shape-Controlled Synthesis of Polyhedral Nanocrystals and Their Facet-Dependent Properties
journal, September 2011


Charge transport in metal oxides: A theoretical study of hematite α-Fe2O3
journal, April 2005

  • Iordanova, N.; Dupuis, M.; Rosso, K. M.
  • The Journal of Chemical Physics, Vol. 122, Issue 14
  • DOI: 10.1063/1.1869492

Resolving Iron(II) Sorption and Oxidative Growth on Hematite (001) Using Atom Probe Tomography
journal, February 2018

  • Taylor, Sandra D.; Liu, Jia; Arey, Bruce W.
  • The Journal of Physical Chemistry C, Vol. 122, Issue 7
  • DOI: 10.1021/acs.jpcc.7b11989

Fast Synthesis of Gibbsite Nanoplates and Process Optimization using Box-Behnken Experimental Design
journal, October 2017

  • Zhang, Xin; Zhang, Xianwen; Graham, Trent R.
  • Crystal Growth & Design, Vol. 17, Issue 12
  • DOI: 10.1021/acs.cgd.7b01400

Agglomeration in colloidal hematite dispersions due to weak magnetic interactions
journal, November 1988

  • Ozaki, Masataka; Egami, Tamami; Sugiyama, Noriko
  • Journal of Colloid and Interface Science, Vol. 126, Issue 1
  • DOI: 10.1016/0021-9797(88)90114-2

A review of focused ion beam milling techniques for TEM specimen preparation
journal, June 1999


An ab initio model of electron transport in hematite (α-Fe2O3) basal planes
journal, April 2003

  • Rosso, Kevin M.; Smith, Dayle M. A.; Dupuis, Michel
  • The Journal of Chemical Physics, Vol. 118, Issue 14, p. 6455-6466
  • DOI: 10.1063/1.1558534

Nanoparticle Aggregation: Challenges to Understanding Transport and Reactivity in the Environment
journal, January 2010

  • Hotze, Ernest M.; Phenrat, Tanapon; Lowry, Gregory V.
  • Journal of Environment Quality, Vol. 39, Issue 6
  • DOI: 10.2134/jeq2009.0462

Systematic control of size, shape and internal structure of monodisperse α-Fe2O3 particles
journal, March 1998

  • Sugimoto, Tadao; Wang, Yinsheng; Itoh, Hiroyuki
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 134, Issue 3
  • DOI: 10.1016/S0927-7757(97)00103-9

Connecting Observations of Hematite (α-Fe 2 O 3 ) Growth Catalyzed by Fe(II)
journal, January 2010

  • Rosso, Kevin M.; Yanina, Svetlana V.; Gorski, Christopher A.
  • Environmental Science & Technology, Vol. 44, Issue 1
  • DOI: 10.1021/es901882a

Preparation of well-defined colloidal particles by thermal decomposition of metal chelates. I. Iron oxides
journal, April 1980


Facet-Engineered Surface and Interface Design of Photocatalytic Materials
journal, August 2016


Energetics and the Role of Defects in Fe(II)-Catalyzed Goethite Recrystallization from Molecular Simulations
journal, January 2019


Reductive Dissolution Mechanisms at the Hematite-Electrolyte Interface Probed by in Situ X-ray Scattering
journal, October 2018

  • McBriarty, Martin E.; Stubbs, Joanne E.; Eng, Peter J.
  • The Journal of Physical Chemistry C, Vol. 123, Issue 13
  • DOI: 10.1021/acs.jpcc.8b07413

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011


Heterogeneous oxidation of Fe(II) on iron oxides in aqueous systems: Identification and controls of Fe(III) product formation
journal, August 2012

  • Larese-Casanova, Philip; Kappler, Andreas; Haderlein, Stefan B.
  • Geochimica et Cosmochimica Acta, Vol. 91
  • DOI: 10.1016/j.gca.2012.05.031

Linked Reactivity at Mineral-Water Interfaces Through Bulk Crystal Conduction
journal, March 2008


Anisotropic photocatalytic properties of hematite
journal, May 2009

  • Eggleston, Carrick M.; Shankle, Angela J. A.; Moyer, Amanda J.
  • Aquatic Sciences, Vol. 71, Issue 2
  • DOI: 10.1007/s00027-009-9191-5

Potential-Specific Structure at the Hematite-Electrolyte Interface
journal, December 2017

  • McBriarty, Martin E.; Stubbs, Joanne E.; Eng, Peter J.
  • Advanced Functional Materials, Vol. 28, Issue 8
  • DOI: 10.1002/adfm.201705618

Ascorbate-Promoted Surface Iron Cycle for Efficient Heterogeneous Fenton Alachlor Degradation with Hematite Nanocrystals
journal, March 2017

  • Huang, Xiaopeng; Hou, Xiaojing; Jia, Falong
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 10
  • DOI: 10.1021/acsami.6b16600

Mineral surface catalysis of reactions between FeII and oxime carbamate pesticides
journal, August 2003


Revisiting the Twin Plane Re-entrant Edge Growth Mechanism at an Atomic Scale by Electron Microscopy
journal, August 2014

  • Yu, Zhiyang; Fu, Xin; Zhu, Jing
  • Crystal Growth & Design, Vol. 14, Issue 9
  • DOI: 10.1021/cg500514c

Structure and reactivity of the hydrated hematite (0001) surface
journal, December 2004


Dynamic Stabilization of Metal Oxide–Water Interfaces
journal, February 2017

  • McBriarty, Martin E.; von Rudorff, Guido Falk; Stubbs, Joanne E.
  • Journal of the American Chemical Society, Vol. 139, Issue 7
  • DOI: 10.1021/jacs.6b13096

The structure of hematite (α-Fe2O3) (001) surfaces in aqueous media: scanning tunneling microscopy and resonant tunneling calculations of coexisting O and Fe terminations
journal, March 2003


Fe(II) Sorption on Hematite:  New Insights Based on Spectroscopic Measurements
journal, January 2007

  • Larese-Casanova, Philip; Scherer, Michelle M.
  • Environmental Science & Technology, Vol. 41, Issue 2
  • DOI: 10.1021/es0617035

Surface potentials of (001), (012), (113) hematite (α-Fe2O3) crystal faces in aqueous solution
journal, January 2013

  • Chatman, Shawn; Zarzycki, Piotr; Rosso, Kevin M.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 33
  • DOI: 10.1039/c3cp52592a

Heterogeneous reduction of Tc(VII) by Fe(II) at the solid–water interface
journal, March 2008

  • Peretyazhko, T.; Zachara, J. M.; Heald, S. M.
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 6
  • DOI: 10.1016/j.gca.2008.01.004

Fe 2 O 3 nanocrystals anchored onto graphene nanosheets as the anode material for low-cost sodium-ion batteries
journal, January 2014

  • Jian, Zelang; Zhao, Bin; Liu, Pan
  • Chem. Commun., Vol. 50, Issue 10
  • DOI: 10.1039/C3CC47977C

Proton Dynamics on Goethite Nanoparticles and Coupling to Electron Transport
journal, March 2015

  • Zarzycki, Piotr; Smith, Dayle M.; Rosso, Kevin M.
  • Journal of Chemical Theory and Computation, Vol. 11, Issue 4
  • DOI: 10.1021/ct500891a

Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: Application to Iron (Hydr)oxides
journal, February 1998

  • Venema, Peter; Hiemstra, Tjisse; Weidler, Peter G.
  • Journal of Colloid and Interface Science, Vol. 198, Issue 2
  • DOI: 10.1006/jcis.1997.5245

Surface diffraction study of the hydrated hematite surface
journal, January 2007


Structural study of Fe(II) adsorption on hematite
journal, July 2008

  • Tanwar, Kunaljeet S.; Petitto, Sarah C.; Ghose, Sanjit K.
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 14
  • DOI: 10.1016/j.gca.2008.04.020

Characterization of Hematite Particles of Different Shapes
journal, July 1993

  • Sugimoto, Tadao; Muramatsu, Atsushi; Sakata, Kazuo
  • Journal of Colloid and Interface Science, Vol. 158, Issue 2
  • DOI: 10.1006/jcis.1993.1274

Hematite facet confined ferrous ions as high efficient Fenton catalysts to degrade organic contaminants by lowering H2O2 decomposition energetic span
journal, February 2016


Top-Down Fabrication of α-Fe 2 O 3 Single-Crystal Nanodiscs and Microparticles with Tunable Porosity for Largely Improved Lithium Storage Properties
journal, September 2010

  • Chen, Jun Song; Zhu, Ting; Yang, Xiao Hua
  • Journal of the American Chemical Society, Vol. 132, Issue 38
  • DOI: 10.1021/ja1060438

Crystal facet engineering of semiconductor photocatalysts: motivations, advances and unique properties
journal, January 2011

  • Liu, Gang; Yu, Jimmy C.; Lu, Gao Qing (Max)
  • Chemical Communications, Vol. 47, Issue 24
  • DOI: 10.1039/c1cc10665a

Visualizing the iron atom exchange front in the Fe(II)-catalyzed recrystallization of goethite by atom probe tomography
journal, February 2019

  • Taylor, Sandra D.; Liu, Jia; Zhang, Xin
  • Proceedings of the National Academy of Sciences, Vol. 116, Issue 8
  • DOI: 10.1073/pnas.1816620116

Solar Water Splitting: Progress Using Hematite (α-Fe2O3) Photoelectrodes
journal, March 2011

  • Sivula, Kevin; Le Formal, Florian; Grätzel, Michael
  • ChemSusChem, Vol. 4, Issue 4
  • DOI: 10.1002/cssc.201000416

Fe(II) adsorption on hematite (0001)
journal, August 2009

  • Tanwar, Kunaljeet S.; Petitto, Sarah C.; Ghose, Sanjit K.
  • Geochimica et Cosmochimica Acta, Vol. 73, Issue 15
  • DOI: 10.1016/j.gca.2009.04.024

Electron Mobility and Trapping in Ferrihydrite Nanoparticles
journal, May 2017


Computational Molecular Simulation of the Oxidative Adsorption of Ferrous Iron at the Hematite (001)–Water Interface
journal, April 2015

  • Kerisit, Sebastien; Zarzycki, Piotr; Rosso, Kevin M.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 17
  • DOI: 10.1021/jp512422h

Anisotropic Magnetic Colloids: A Strategy to Form Complex Structures Using Nonspherical Building Blocks
journal, September 2009


Second Harmonic Generation Studies of Fe(II) Interactions with Hematite (α-Fe 2 O 3 )
journal, February 2013

  • Jordan, David S.; Hull, Christopher J.; Troiano, Julianne M.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 8
  • DOI: 10.1021/jp3113057

Surface catalysis of uranium(VI) reduction by iron(II)
journal, October 1999

  • Liger, Emmanuelle; Charlet, Laurent; Van Cappellen, Philippe
  • Geochimica et Cosmochimica Acta, Vol. 63, Issue 19-20
  • DOI: 10.1016/S0016-7037(99)00265-3

Fe(II)-Catalyzed Recrystallization of Goethite Revisited
journal, September 2014

  • Handler, Robert M.; Frierdich, Andrew J.; Johnson, Clark M.
  • Environmental Science & Technology, Vol. 48, Issue 19
  • DOI: 10.1021/es503084u

Facet-Dependent Electrical, Photocatalytic, and Optical Properties of Semiconductor Crystals and Their Implications for Applications
journal, December 2017

  • Huang, Michael H.; Naresh, Gollapally; Chen, Hsiang-Sheng
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 1
  • DOI: 10.1021/acsami.7b15828

Heterogeneous photo-Fenton reaction on hematite (α-Fe 2 O 3 ){104}, {113} and {001} surface facets
journal, January 2015

  • Chan, J. Y. T.; Ang, S. Y.; Ye, E. Y.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 38
  • DOI: 10.1039/C5CP03332B

Ascorbate Induced Facet Dependent Reductive Dissolution of Hematite Nanocrystals
journal, January 2017

  • Huang, Xiaopeng; Hou, Xiaojing; Song, Fahui
  • The Journal of Physical Chemistry C, Vol. 121, Issue 2
  • DOI: 10.1021/acs.jpcc.6b09281

Facet-Dependent Cr(VI) Adsorption of Hematite Nanocrystals
journal, January 2016

  • Huang, Xiaopeng; Hou, Xiaojing; Song, Fahui
  • Environmental Science & Technology, Vol. 50, Issue 4
  • DOI: 10.1021/acs.est.5b05111

High-precision SIMS oxygen, sulfur and iron stable isotope analyses of geological materials: accuracy, surface topography and crystal orientation
journal, May 2010

  • Kita, N. T.; Huberty, J. M.; Kozdon, R.
  • Surface and Interface Analysis, Vol. 43, Issue 1-2
  • DOI: 10.1002/sia.3424

In Situ Grazing-Incidence Extended X-ray Absorption Fine Structure Study of Pb(II) Chemisorption on Hematite (0001) and (1-102) Surfaces
journal, March 2004

  • Bargar, John R.; Trainor, Thomas P.; Fitts, Jeffery P.
  • Langmuir, Vol. 20, Issue 5
  • DOI: 10.1021/la0354133

Crystal orientation effects in δ18O for magnetite and hematite by SIMS
journal, September 2010


Iron Atom Exchange between Hematite and Aqueous Fe(II)
journal, June 2015

  • Frierdich, Andrew J.; Helgeson, Maria; Liu, Chengshuai
  • Environmental Science & Technology, Vol. 49, Issue 14
  • DOI: 10.1021/acs.est.5b01276

Nonlocal bacterial electron transfer to hematite surfaces
journal, March 2003


Kinetics of chromate reduction by ferrous ions derived from hematite and biotite at 25 degrees C
journal, February 1989


Spontaneous Water Oxidation at Hematite (α-Fe 2 O 3 ) Crystal Faces
journal, January 2015

  • Chatman, S.; Zarzycki, P.; Rosso, K. M.
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 3
  • DOI: 10.1021/am5067783

Facet-Mediated Photodegradation of Organic Dye over Hematite Architectures by Visible Light
journal, November 2011

  • Zhou, Xuemei; Lan, Jinyao; Liu, Gang
  • Angewandte Chemie International Edition, Vol. 51, Issue 1
  • DOI: 10.1002/anie.201105028

Adatom Fe(III) on the hematite surface: Observation of a key reactive surface species
journal, June 2004

  • Eggleston, Carrick M.; Stack, Andrew G.; Rosso, Kevin M.
  • Geochemical Transactions, Vol. 5, Issue 2
  • DOI: 10.1186/1467-4866-5-33

Structure and oxidation state of hematite surfaces reacted with aqueous Fe(II) at acidic and neutral pH
journal, March 2010

  • Catalano, Jeffrey G.; Fenter, Paul; Park, Changyong
  • Geochimica et Cosmochimica Acta, Vol. 74, Issue 5
  • DOI: 10.1016/j.gca.2009.12.018

Size and Morphology Controlled Synthesis of Boehmite Nanoplates and Crystal Growth Mechanisms
journal, April 2018

  • Zhang, Xin; Cui, Wenwen; Page, Katharine L.
  • Crystal Growth & Design, Vol. 18, Issue 6
  • DOI: 10.1021/acs.cgd.8b00394

Spectroscopic Evidence for Fe(II)−Fe(III) Electron Transfer at the Iron Oxide−Water Interface
journal, September 2004

  • Williams, Aaron G. B.; Scherer, Michelle M.
  • Environmental Science & Technology, Vol. 38, Issue 18
  • DOI: 10.1021/es049373g

Re-investigation of the re-entrant corner effect in twinned crystals
journal, July 1979


The Role of Defects in Fe(II)–Goethite Electron Transfer
journal, February 2018

  • Notini, Luiza; Latta, Drew E.; Neumann, Anke
  • Environmental Science & Technology, Vol. 52, Issue 5
  • DOI: 10.1021/acs.est.7b05772