In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features

Zhou, Hongyao; Liu, Haodong; Li, Yejing; Yue, Xiujun; Wang, Xuefeng; Gonzalez, Matthew; Meng, Ying Shirley; Liu, Ping

doi:10.1039/C9TA02341K

Title: In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features

Abstract

An in situ formed poly(vinylene carbonate)–lithium iodide gel electrolyte enables stable cycling of lithium metal and a thermal shutdown function.

Authors:

Zhou, Hongyao ^[1]; Liu, Haodong ^[1]; Li, Yejing ^[1]; Yue, Xiujun ^[1];

^[1]; Gonzalez, Matthew ^[1]; Meng, Ying Shirley ^[1];

^[1]

Department of NanoEngineering, University of California San Diego, La Jolla, USA

Publication Date:: 2019-07-16

Sponsoring Org.:: USDOE

OSTI Identifier:: 1530897

Grant/Contract Number:: EE0007764

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 28; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Zhou, Hongyao, Liu, Haodong, Li, Yejing, Yue, Xiujun, Wang, Xuefeng, Gonzalez, Matthew, Meng, Ying Shirley, and Liu, Ping. In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9TA02341K.

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                    Zhou, Hongyao, Liu, Haodong, Li, Yejing, Yue, Xiujun, Wang, Xuefeng, Gonzalez, Matthew, Meng, Ying Shirley, & Liu, Ping. In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features.  United Kingdom.  https://doi.org/10.1039/C9TA02341K

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                    Zhou, Hongyao, Liu, Haodong, Li, Yejing, Yue, Xiujun, Wang, Xuefeng, Gonzalez, Matthew, Meng, Ying Shirley, and Liu, Ping. Tue .  
"In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features".  United Kingdom.  https://doi.org/10.1039/C9TA02341K.

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@article{osti_1530897,

  title        = {In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features},

  author       = {Zhou, Hongyao and Liu, Haodong and Li, Yejing and Yue, Xiujun and Wang, Xuefeng and Gonzalez, Matthew and Meng, Ying Shirley and Liu, Ping},

  abstractNote = {An in situ formed poly(vinylene carbonate)–lithium iodide gel electrolyte enables stable cycling of lithium metal and a thermal shutdown function.},

  doi          = {10.1039/C9TA02341K},

  journal      = {Journal of Materials Chemistry. A},

  number       = 28,

  volume       = 7,

  place        = {United Kingdom},

  year         = {2019},

  month        = {7}

}

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https://doi.org/10.1039/C9TA02341K

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Title: In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features

Abstract

Citation Formats

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes journal, March 2018

Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode journal, January 2015

Room-Temperature Performance of Poly(Ethylene Ether Carbonate)-Based Solid Polymer Electrolytes for All-Solid-State Lithium Batteries journal, December 2017

Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries journal, January 2018

Polymerization of vinylene carbonate as well as aminolysis and hydrolysis of poly(vinylene carbonate) journal, December 2001

Electroconvection and Morphological Instabilities in Potentiostatic Electrodeposition across Liquid Electrolytes with Polymer Additives journal, January 2018

Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries journal, October 2017

A scalable 3D lithium metal anode journal, January 2019

Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries journal, October 2017

High molecular weight poly(vinylene carbonate) and derivatives journal, April 1962

A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal Batteries journal, July 2018

Effect of vinylene carbonate as additive to electrolyte for lithium metal anode journal, February 2004

Stabilizing electrochemical interfaces in viscoelastic liquid electrolytes journal, March 2018

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Polymerization of vinylene carbonate in dimethyl sulfoxide journal, April 1978

Reviving the lithium metal anode for high-energy batteries journal, March 2017

Cryogenic Electron Microscopy for Characterizing and Diagnosing Batteries journal, November 2018

Fire-extinguishing organic electrolytes for safe batteries journal, November 2017

What Makes Fluoroethylene Carbonate Different? journal, June 2015

High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes journal, August 2018

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A Comparative Study of Synthetic Graphite and Li Electrodes in Electrolyte Solutions Based on Ethylene Carbonate-Dimethyl Carbonate Mixtures journal, January 1996

2D MoS2 as an efficient protective layer for lithium metal anodes in high-performance Li–S batteries journal, February 2018

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Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition journal, April 2018

The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries journal, January 1994

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review journal, July 2017

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Structure and Solution Dynamics of Lithium Methyl Carbonate as a Protective Layer For Lithium Metal journal, April 2018

New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM journal, November 2017

Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF 6 and Cyclic Carbonate Additives journal, November 2017

Electrolytes and Interphases in Li-Ion Batteries and Beyond journal, October 2014

Suppression of Dendritic Lithium Growth by in Situ Formation of a Chemically Stable and Mechanically Strong Solid Electrolyte Interphase journal, December 2017

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy journal, October 2017

Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer journal, March 2017

Synthetic applications and mechanism studies of the decarbalkoxylations of geminal diesters and related systems effected in dimethyl sulfoxide by water and/or by water with added salts journal, January 1978

Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries journal, January 2018

Flammability of Li-Ion Battery Electrolytes: Flash Point and Self-Extinguishing Time Measurements journal, January 2015

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries journal, December 2017

High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes journal, March 2015

A Review of Solid Electrolyte Interphases on Lithium Metal Anode journal, November 2015

High rate and stable cycling of lithium metal anode journal, February 2015

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode
journal, January 2015

Room-Temperature Performance of Poly(Ethylene Ether Carbonate)-Based Solid Polymer Electrolytes for All-Solid-State Lithium Batteries
journal, December 2017

Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries
journal, January 2018

Polymerization of vinylene carbonate as well as aminolysis and hydrolysis of poly(vinylene carbonate)
journal, December 2001

Electroconvection and Morphological Instabilities in Potentiostatic Electrodeposition across Liquid Electrolytes with Polymer Additives
journal, January 2018

Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries
journal, October 2017

A scalable 3D lithium metal anode
journal, January 2019

Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries
journal, October 2017

High molecular weight poly(vinylene carbonate) and derivatives
journal, April 1962

A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal Batteries
journal, July 2018

Effect of vinylene carbonate as additive to electrolyte for lithium metal anode
journal, February 2004

Stabilizing electrochemical interfaces in viscoelastic liquid electrolytes
journal, March 2018

Self-Stabilized Solid Electrolyte Interface on a Host-Free Li-Metal Anode toward High Areal Capacity and Rate Utilization
journal, May 2018

Polymerization of vinylene carbonate in dimethyl sulfoxide
journal, April 1978

Reviving the lithium metal anode for high-energy batteries
journal, March 2017

Cryogenic Electron Microscopy for Characterizing and Diagnosing Batteries
journal, November 2018

Fire-extinguishing organic electrolytes for safe batteries
journal, November 2017

What Makes Fluoroethylene Carbonate Different?
journal, June 2015

High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes
journal, August 2018

The Effect of Carbon Dioxide on the Cycle Life and Electrolyte Stability of Li-Ion Full Cells Containing Silicon Alloy
journal, January 2017

Solid-state polymer electrolytes with in-built fast interfacial transport for secondary lithium batteries
journal, March 2019

Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon
journal, May 2017

Ring-Opening Polymerization of Ethylene Carbonate and Depolymerization of Poly(ethylene oxide- c o -ethylene carbonate)
journal, March 2000

A Comparative Study of Synthetic Graphite and Li Electrodes in Electrolyte Solutions Based on Ethylene Carbonate-Dimethyl Carbonate Mixtures
journal, January 1996

2D MoS2 as an efficient protective layer for lithium metal anodes in high-performance Li–S batteries
journal, February 2018

Lithium Iodide as a Promising Electrolyte Additive for Lithium-Sulfur Batteries: Mechanisms of Performance Enhancement
journal, November 2014

Design principles for electrolytes and interfaces for stable lithium-metal batteries
journal, September 2016

Suppressing Lithium Dendrite Growth with a Single-Component Coating
journal, August 2017

Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition
journal, April 2018

The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries
journal, January 1994

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
journal, July 2017

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

Structure and Solution Dynamics of Lithium Methyl Carbonate as a Protective Layer For Lithium Metal
journal, April 2018

New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM
journal, November 2017

Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF ₆ and Cyclic Carbonate Additives
journal, November 2017

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014

Suppression of Dendritic Lithium Growth by in Situ Formation of a Chemically Stable and Mechanically Strong Solid Electrolyte Interphase
journal, December 2017

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
journal, October 2017

Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer
journal, March 2017

Synthetic applications and mechanism studies of the decarbalkoxylations of geminal diesters and related systems effected in dimethyl sulfoxide by water and/or by water with added salts
journal, January 1978

Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries
journal, January 2018

Flammability of Li-Ion Battery Electrolytes: Flash Point and Self-Extinguishing Time Measurements
journal, January 2015

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017

High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes
journal, March 2015

A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015

High rate and stable cycling of lithium metal anode
journal, February 2015