Electrochemical Hole Injection Selectively Expels Iodide from Mixed Halide Perovskite Films

Samu, Gergely F.; Balog, Ádám; De Angelis, Filippo; Meggiolaro, Daniele; Kamat, Prashant V.; Janáky, Csaba

doi:10.1021/jacs.9b04568

Title: Electrochemical Hole Injection Selectively Expels Iodide from Mixed Halide Perovskite Films

Journal Article · 18 June 2019 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.9b04568 · OSTI ID:1530479

^[1]; Balog, Ádám ^[2];

^[3];

^[4];

^[5];

^[6]

Department of Physical Chemistry and Materials Science, Interdisciplinary Excellence Centre, University of Szeged, Rerrich Square 1, Szeged, H-6720, Hungary, ELI-ALPS Research Institute, Dugonics Square 13, Szeged, 6720, Hungary, Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, United States
Department of Physical Chemistry and Materials Science, Interdisciplinary Excellence Centre, University of Szeged, Rerrich Square 1, Szeged, H-6720, Hungary
Department of Chemistry, Biology and Biotechnology, University of Perugia, Via Elce di Sotto, 8I-06123 Perugia, Italy, Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), CNR-ISTM, Via Elce di Sotto 8, 06123 Perugia, Italy, CompuNet, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy
Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), CNR-ISTM, Via Elce di Sotto 8, 06123 Perugia, Italy, CompuNet, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, United States, Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States
Department of Physical Chemistry and Materials Science, Interdisciplinary Excellence Centre, University of Szeged, Rerrich Square 1, Szeged, H-6720, Hungary, ELI-ALPS Research Institute, Dugonics Square 13, Szeged, 6720, Hungary

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: FC02-04ER15533

OSTI ID:: 1530479

Alternate ID(s):: OSTI ID: 1542124

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 27 Vol. 141; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (49)

Current-Induced Phase Segregation in Mixed Halide Hybrid Perovskites and its Impact on Two-Terminal Tandem Solar Cell Design Braly, Ian L.; Stoddard, Ryan J.; Rajagopal, Adharsh ACS Energy Letters, Vol. 2, Issue 8 https://doi.org/10.1021/acsenergylett.7b00525	journal	July 2017
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃ Xing, G.; Mathews, N.; Sun, S. Science, Vol. 342, Issue 6156, p. 344-347 https://doi.org/10.1126/science.1243167	journal	October 2013
Controlling the Phase Segregation in Mixed Halide Perovskites through Nanocrystal Size Gualdrón-Reyes, Andrés. F.; Yoon, Seog Joon; Barea, Eva M. ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b02207	journal	November 2018
To Exchange or Not to Exchange . Suppressing Anion Exchange in Cesium Lead Halide Perovskites with PbSO ₄ –Oleate Capping Ravi, Vikash Kumar; Scheidt, Rebecca A.; Nag, Angshuman ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00380	journal	March 2018
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells McMeekin, D. P.; Sadoughi, G.; Rehman, W. Science, Vol. 351, Issue 6269 https://doi.org/10.1126/science.aad5845	journal	January 2016
Impact of Surfaces on Photoinduced Halide Segregation in Mixed-Halide Perovskites Belisle, Rebecca A.; Bush, Kevin A.; Bertoluzzi, Luca ACS Energy Letters, Vol. 3, Issue 11 https://doi.org/10.1021/acsenergylett.8b01562	journal	October 2018
Four-Terminal All-Perovskite Tandem Solar Cells Achieving Power Conversion Efficiencies Exceeding 23% Zhao, Dewei; Wang, Changlei; Song, Zhaoning ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01287	journal	January 2018
Light and Electrically Induced Phase Segregation and Its Impact on the Stability of Quadruple Cation High Bandgap Perovskite Solar Cells Duong, The; Mulmudi, Hemant Kumar; Wu, YiLiang ACS Applied Materials & Interfaces, Vol. 9, Issue 32 https://doi.org/10.1021/acsami.7b06816	journal	August 2017
Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation Yoon, Seog Joon; Draguta, Sergiu; Manser, Joseph S. ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00158	journal	June 2016
Cesium Lead Halide Perovskites with Improved Stability for Tandem Solar Cells Beal, Rachel E.; Slotcavage, Daniel J.; Leijtens, Tomas The Journal of Physical Chemistry Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acs.jpclett.6b00002	journal	February 2016
Large polarons in lead halide perovskites Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1701217	journal	August 2017
Visualizing Phase Segregation in Mixed-Halide Perovskite Single Crystals Mao, Wenxin; Hall, Christopher R.; Chesman, Anthony S. R. Angewandte Chemie International Edition, Vol. 58, Issue 9 https://doi.org/10.1002/anie.201810193	journal	January 2019
A Victim of Halide Ion Segregation. How Light Soaking Affects Solar Cell Performance of Mixed Halide Lead Perovskites Samu, Gergely F.; Janáky, Csaba; Kamat, Prashant V. ACS Energy Letters, Vol. 2, Issue 8 https://doi.org/10.1021/acsenergylett.7b00589	journal	July 2017
Transformation of Sintered CsPbBr ₃ Nanocrystals to Cubic CsPbI ₃ and Gradient CsPbBr _x I _{3– x} through Halide Exchange Hoffman, Jacob B.; Schleper, A. Lennart; Kamat, Prashant V. Journal of the American Chemical Society, Vol. 138, Issue 27 https://doi.org/10.1021/jacs.6b04661	journal	June 2016
Tunable Polaron Distortions Control the Extent of Halide Demixing in Lead Halide Perovskites Bischak, Connor G.; Wong, Andrew B.; Lin, Elbert The Journal of Physical Chemistry Letters, Vol. 9, Issue 14 https://doi.org/10.1021/acs.jpclett.8b01512	journal	June 2018
Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability Yuan, Yongbo; Huang, Jinsong Accounts of Chemical Research, Vol. 49, Issue 2 https://doi.org/10.1021/acs.accounts.5b00420	journal	January 2016
Modulation of Charge Recombination in CsPbBr ₃ Perovskite Films with Electrochemical Bias Scheidt, Rebecca A.; Samu, Gergely F.; Janáky, Csaba Journal of the American Chemical Society, Vol. 140, Issue 1 https://doi.org/10.1021/jacs.7b10958	journal	November 2017
Origin of Reversible Photoinduced Phase Separation in Hybrid Perovskites Bischak, Connor G.; Hetherington, Craig L.; Wu, Hao Nano Letters, Vol. 17, Issue 2 https://doi.org/10.1021/acs.nanolett.6b04453	journal	January 2017
Impact of microstructure on local carrier lifetime in perovskite solar cells de Quilettes, D. W.; Vorpahl, S. M.; Stranks, S. D. Science, Vol. 348, Issue 6235 https://doi.org/10.1126/science.aaa5333	journal	April 2015
Perovskite-perovskite tandem photovoltaics with optimized band gaps Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A. Science, Vol. 354, Issue 6314 https://doi.org/10.1126/science.aaf9717	journal	October 2016
Rationalizing the light-induced phase separation of mixed halide organic–inorganic perovskites Draguta, Sergiu; Sharia, Onise; Yoon, Seog Joon Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00284-2	journal	August 2017
Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics Hoke, Eric T.; Slotcavage, Daniel J.; Dohner, Emma R. Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC03141E	journal	January 2015
Shift Happens . How Halide Ion Defects Influence Photoinduced Segregation in Mixed Halide Perovskites Yoon, Seog Joon; Kuno, Masaru; Kamat, Prashant V. ACS Energy Letters, Vol. 2, Issue 7 https://doi.org/10.1021/acsenergylett.7b00357	journal	June 2017
Visualization and Studies of Ion-Diffusion Kinetics in Cesium Lead Bromide Perovskite Nanowires Pan, Dongxu; Fu, Yongping; Chen, Jie Nano Letters, Vol. 18, Issue 3 https://doi.org/10.1021/acs.nanolett.7b05023	journal	February 2018
First-Principles Modeling of Defects in Lead Halide Perovskites: Best Practices and Open Issues Meggiolaro, Daniele; De Angelis, Filippo ACS Energy Letters, Vol. 3, Issue 9 https://doi.org/10.1021/acsenergylett.8b01212	journal	August 2018
Ionic transport in hybrid lead iodide perovskite solar cells Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8497	journal	June 2015
Large tunable photoeffect on ion conduction in halide perovskites and implications for photodecomposition Kim, Gee Yeong; Senocrate, Alessandro; Yang, Tae-Youl Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0038-0	journal	March 2018
Local Observation of Phase Segregation in Mixed-Halide Perovskite Tang, Xiaofeng; van den Berg, Marius; Gu, Ening Nano Letters, Vol. 18, Issue 3 https://doi.org/10.1021/acs.nanolett.8b00505	journal	February 2018
Illumination‐Induced Halide Segregation in Gradient Bandgap Mixed‐Halide Perovskite Nanoplatelets Zhou, Chunhua; Ou, Qingdong; Chen, Weijian Advanced Optical Materials, Vol. 6, Issue 24 https://doi.org/10.1002/adom.201801107	journal	October 2018
Quantification of Ionic Diffusion in Lead Halide Perovskite Single Crystals Peng, Wei; Aranda, Clara; Bakr, Osman M. ACS Energy Letters, Vol. 3, Issue 7 https://doi.org/10.1021/acsenergylett.8b00641	journal	May 2018
Opportunities and challenges for tandem solar cells using metal halide perovskite semiconductors Leijtens, Tomas; Bush, Kevin A.; Prasanna, Rohit Nature Energy, Vol. 3, Issue 10 https://doi.org/10.1038/s41560-018-0190-4	journal	July 2018
Iodine chemistry determines the defect tolerance of lead-halide perovskites Meggiolaro, Daniele; Motti, Silvia G.; Mosconi, Edoardo Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/C8EE00124C	journal	January 2018
Vacancy-Mediated Anion Photosegregation Kinetics in Mixed Halide Hybrid Perovskites: Coupled Kinetic Monte Carlo and Optical Measurements Ruth, Anthony; Brennan, Michael C.; Draguta, Sergiu ACS Energy Letters, Vol. 3, Issue 10 https://doi.org/10.1021/acsenergylett.8b01369	journal	September 2018
Electronic Traps and Phase Segregation in Lead Mixed-Halide Perovskite Knight, Alexander J.; Wright, Adam D.; Patel, Jay B. ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b02002	journal	November 2018
Stabilized Wide Bandgap MAPbBr _x I _{3- x} Perovskite by Enhanced Grain Size and Improved Crystallinity Hu, Miao; Bi, Cheng; Yuan, Yongbo Advanced Science, Vol. 3, Issue 6 https://doi.org/10.1002/advs.201500301	journal	December 2015
How Lead Halide Complex Chemistry Dictates the Composition of Mixed Halide Perovskites Yoon, Seog Joon; Stamplecoskie, Kevin G.; Kamat, Prashant V. The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00433	journal	March 2016
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Modeling the Interaction of Molecular Iodine with MAPbI ₃ : A Probe of Lead-Halide Perovskites Defect Chemistry Meggiolaro, Daniele; Mosconi, Edoardo; De Angelis, Filippo ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01244	journal	January 2018
Density Functional Calculations of Native Defects in CH ₃ NH ₃ PbI ₃ : Effects of Spin–Orbit Coupling and Self-Interaction Error Du, Mao-Hua The Journal of Physical Chemistry Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acs.jpclett.5b00199	journal	April 2015
The Bandgap as a Moving Target: Reversible Bandgap Instabilities in Multiple-Cation Mixed-Halide Perovskite Solar Cells Ruf, Fabian; Rietz, Pascal; Aygüler, Meltem F. ACS Energy Letters, Vol. 3, Issue 12 https://doi.org/10.1021/acsenergylett.8b01857	journal	November 2018
23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability Bush, Kevin A.; Palmstrom, Axel F.; Yu, Zhengshan J. Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.9	journal	February 2017
Light induced metastable modification of optical properties in CH3NH3PbI3−xBrx perovskite films: Two-step mechanism Yang, Xiao; Yan, Xiaoliang; Wang, Wei Organic Electronics, Vol. 34 https://doi.org/10.1016/j.orgel.2016.04.020	journal	July 2016
Making and Breaking of Lead Halide Perovskites Manser, Joseph S.; Saidaminov, Makhsud I.; Christians, Jeffrey A. Accounts of Chemical Research, Vol. 49, Issue 2 https://doi.org/10.1021/acs.accounts.5b00455	journal	January 2016
Excess charge-carrier induced instability of hybrid perovskites Lin, Yuze; Chen, Bo; Fang, Yanjun Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07438-w	journal	November 2018
Halogen Migration in Hybrid Perovskites: The Organic Cation Matters Oranskaia, Aleksandra; Yin, Jun; Bakr, Osman M. The Journal of Physical Chemistry Letters, Vol. 9, Issue 18 https://doi.org/10.1021/acs.jpclett.8b02522	journal	September 2018
Light-Induced Phase Segregation in Halide-Perovskite Absorbers Slotcavage, Daniel J.; Karunadasa, Hemamala I.; McGehee, Michael D. ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00495	journal	November 2016
Defect-Assisted Photoinduced Halide Segregation in Mixed-Halide Perovskite Thin Films Barker, Alex J.; Sadhanala, Aditya; Deschler, Felix ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00282	journal	May 2017
Electrochemistry and Spectroelectrochemistry of Lead Halide Perovskite Films: Materials Science Aspects and Boundary Conditions Samu, Gergely F.; Scheidt, Rebecca A.; Kamat, Prashant V. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b04321	journal	December 2017
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck Nano Letters, Vol. 13, Issue 4, p. 1764-1769 https://doi.org/10.1021/nl400349b	journal	March 2013

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