Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: High relaxation barrier in neodymium furoate-based field-induced SMMs

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/C9DT02047K · OSTI ID:1530468
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [4]; ORCiD logo [5]; ORCiD logo [6]; ORCiD logo [6]; ORCiD logo [7]; ORCiD logo [7]
  1. Escola Universitària Salesiana de Sarrià (EUSS), 08017-Barcelona, Spain
  2. Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain, Servicio de Medidas Físicas. Universidad de Zaragoza
  3. Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain, Centro Universitario de la Defensa. Academia General Militar
  4. Institute of Chemistry, Academy of Sciences of Moldova, Chisinau, Republic of Moldova
  5. “Petru Poni” Institute of Macromolecular Chemistry, 700487 Iasi, Romania
  6. Ames Laboratory, US Department of Energy and Critical Materials Institute, Ames, USA
  7. Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain
+ Show Author Affiliations

Two new neodymium molecular magnets of formula {[Nd(α-fur) 3 (H 2 O) 2 ]·DMF} n ( 1 ) and {[Nd 0.065 La 0.935 (α-fur) 3 (H 2 O) 2 ]} n ( 2 ), α-fur = C 4 H 3 OCOO, have been synthesized and characterized.

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI ID:
1530468
Alternate ID(s):
OSTI ID: 1542877
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 41 Vol. 48; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (39)

Field-Induced SMM and Visible/NIR-Luminescence Behaviour of Dinuclear Ln III Complexes with 2-Fluorobenzoate : Field-Induced SMM and Visible/NIR-Luminescence Behaviour of Dinuclear Ln journal May 2018
Relativistic quantum chemistry: the multiconfigurational approach journal January 2004
Hybrid organic–inorganic connectivity of Nd III (pyrazine- N , N ′-dioxide)[Co III (CN) 6 ] 3− coordination chains for creating near-infrared emissive Nd( iii ) showing field-induced slow magnetic relaxation journal January 2018
Slow magnetic relaxation of light lanthanide-based linear LnZn 2 trinuclear complexes journal January 2015
Structural and magnetic properties of some lanthanide (Ln = Eu( iii ), Gd( iii ) and Nd( iii )) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and Nd substitutions journal January 2014
Slow relaxation in a {Tb 2 Ba(α-fur) 8 } n polymer with Ln = Tb( iii ) non-Kramers ions journal January 2019
Synthesis, crystal structure, magnetic and luminescence investigations of new 2Ln3+–Sr2+ heteronuclear polymers with 2-furoic acid journal June 2007
Exploiting single-ion anisotropy in the design of f-element single-molecule magnets journal January 2011
Heterobimetallic hexanuclear [Mn ΙΙΙ 4 Ln ΙΙΙ 2 ] clusters: A rare Mn ΙΙΙ 4 Nd ΙΙΙ 2 example exhibiting slow relaxation of magnetization journal January 2012
A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior journal January 2018
Slow magnetic relaxation in homoleptic trispyrazolylborate complexes of neodymium(iii) and uranium(iii) journal January 2012
Low-Temperature Quantum Relaxation in a System of Magnetic Nanomolecules journal June 1998
The Crystal and Molecular Structure of Praseodymium(Iii) 2-Furancarboxylate Dihydrate journal February 1987
Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes journal January 2014
Slow magnetic relaxation in a neodymium metallocene tetraphenylborate complex journal February 2018
Antiferromagnetic single-chain magnet slow relaxation in the {Tb(α-fur) 3 } n polymer with non-Kramers ions journal January 2016
Magnetic Anisotropy in a Dysprosium/DOTA Single-Molecule Magnet: Beyond Simple Magneto-Structural Correlations journal January 2012
MOLCAS 7: The Next Generation journal January 2010
OLEX2 : a complete structure solution, refinement and analysis program journal January 2009
Neodymium 1D systems: targeting new sources for field-induced slow magnetization relaxation journal January 2015
Construction of a General Library for the Rational Design of Nanomagnets and Spin Qubits Based on Mononuclear f-Block Complexes. The Polyoxometalate Case journal August 2014
Controlled Synthesis of Heterotrimetallic Single-Chain Magnets from Anisotropic High-Spin 3 d-4 f Nodes and Paramagnetic Spacers journal December 2012
A short history of SHELX journal December 2007
Crystal data of hydrates of yttrium(III) and lanthanide(III) complexes with 2-furancarboxylic acid, Ln(C 5 H 3 O 3 ) 3 · n H 2 O ( n = 2 or 3) journal January 1986
Slow Magnetic Relaxation in Uranium(III) and Neodymium(III) Cyclooctatetraenyl Complexes journal April 2015
An unprecedented zero field neodymium( iii ) single-ion magnet based on a phosphonic diamide journal January 2016
An empirical correction for absorption anisotropy journal January 1995
{Dy(α-fur)3}n: from double relaxation single-ion magnet behavior to 3D ordering journal January 2013
Synthesis, structure and magnetic properties of unsymmetrical dodecanuclear Mn–Ln clusters journal August 2008
Closing the Circle of the Lanthanide-Murexide Series: Single-Molecule Magnet Behavior and Near-Infrared Emission of the NdIII Derivative journal October 2018
Magnetic anisotropy investigation on light lanthanide complexes journal January 2018
Uncommon lanthanide ions in purely 4 f Single Molecule Magnets journal September 2017
Magnetic relaxation versus 3D long-range ordering in {Dy 2 Ba(α-fur) 8 } n furoate polymers journal January 2014
Dinuclear Ln III Complexes with 9-Anthracenecarboxylate Showing Field-Induced SMM and Visible/NIR Luminescence : Dinuclear Ln journal August 2018
Heteronuclear {Tb x Eu 1−x } furoate 1D polymers presenting luminescent properties and SMM behavior journal January 2018
Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand journal December 2016
Light Lanthanide Complexes with Crown Ether and Its Aza Derivative Which Show Slow Magnetic Relaxation Behaviors journal December 2016
Structural diversity and photo-physical and magnetic properties of dimeric to 1D polymeric coordination polymers of lighter lanthanide( iii ) dinitrobenzoates journal January 2018
Initial Observation of Magnetization Hysteresis and Quantum Tunneling in Mixed Manganese−Lanthanide Single-Molecule Magnets journal December 2004

Similar Records

Lanthanide N,N'-piperazine-bis(methylenephosphonates) (Ln=La, Ce, Nd) that display flexible frameworks, reversible hydration and cation exchange
Journal Article · 2009 · Journal of Solid State Chemistry · OSTI ID:21372344
+3 more
Lanthanum and neodymium solubility in simplified SiO{sub 2}-B{sub 2}O{sub 3}-Na{sub 2}O-Al{sub 2}O{sub 3}-CaO high level waste glass
Journal Article · 2012 · Journal of the American Ceramic Society · OSTI ID:22273969
+3 more
Structural and Spectroscopic Comparison of Soft‐Se vs. Hard‐O Donor Bonding in Trivalent Americium/Neodymium Molecules
Journal Article · 2021 · Angewandte Chemie · OSTI ID:1786144
+8 more

Related Subjects