skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High relaxation barrier in neodymium furoate-based field-induced SMMs

Abstract

Two new neodymium molecular magnets of formula {[Nd(α-fur) 3 (H 2 O) 2 ]·DMF} n ( 1 ) and {[Nd 0.065 La 0.935 (α-fur) 3 (H 2 O) 2 ]} n ( 2 ), α-fur = C 4 H 3 OCOO, have been synthesized and characterized.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [4]; ORCiD logo [5]; ORCiD logo [6]; ORCiD logo [6]; ORCiD logo [7]; ORCiD logo [7]
  1. Escola Universitària Salesiana de Sarrià (EUSS), 08017-Barcelona, Spain
  2. Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain, Servicio de Medidas Físicas. Universidad de Zaragoza
  3. Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain, Centro Universitario de la Defensa. Academia General Militar
  4. Institute of Chemistry, Academy of Sciences of Moldova, Chisinau, Republic of Moldova
  5. “Petru Poni” Institute of Macromolecular Chemistry, 700487 Iasi, Romania
  6. Ames Laboratory, US Department of Energy and Critical Materials Institute, Ames, USA
  7. Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1530468
Alternate Identifier(s):
OSTI ID: 1542877
Report Number(s):
IS-J-9969
Journal ID: ISSN 1477-9226; ICHBD9
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Published Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 41; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Bartolomé, E., Arauzo, A., Luzón, J., Melnic, S., Shova, S., Prodius, D., Nlebedim, I. C., Bartolomé, F., and Bartolomé, J. High relaxation barrier in neodymium furoate-based field-induced SMMs. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT02047K.
Bartolomé, E., Arauzo, A., Luzón, J., Melnic, S., Shova, S., Prodius, D., Nlebedim, I. C., Bartolomé, F., & Bartolomé, J. High relaxation barrier in neodymium furoate-based field-induced SMMs. United Kingdom. doi:10.1039/C9DT02047K.
Bartolomé, E., Arauzo, A., Luzón, J., Melnic, S., Shova, S., Prodius, D., Nlebedim, I. C., Bartolomé, F., and Bartolomé, J. Tue . "High relaxation barrier in neodymium furoate-based field-induced SMMs". United Kingdom. doi:10.1039/C9DT02047K.
@article{osti_1530468,
title = {High relaxation barrier in neodymium furoate-based field-induced SMMs},
author = {Bartolomé, E. and Arauzo, A. and Luzón, J. and Melnic, S. and Shova, S. and Prodius, D. and Nlebedim, I. C. and Bartolomé, F. and Bartolomé, J.},
abstractNote = {Two new neodymium molecular magnets of formula {[Nd(α-fur) 3 (H 2 O) 2 ]·DMF} n ( 1 ) and {[Nd 0.065 La 0.935 (α-fur) 3 (H 2 O) 2 ]} n ( 2 ), α-fur = C 4 H 3 OCOO, have been synthesized and characterized.},
doi = {10.1039/C9DT02047K},
journal = {Dalton Transactions},
number = 41,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9DT02047K

Figures / Tables:

Table 1 Table 1: Literature review of Nd‐based SMMs; in italic font: ab initio‐calculated values. Temperature dependence of the relaxation rate:more » $\tau^{-1}=\tau_{QT}$$^{-1}$exp(-U/K$_B$T).« less

Save / Share:

Works referenced in this record:

Slow relaxation in a {Tb 2 Ba(α-fur) 8 } n polymer with Ln = Tb( iii ) non-Kramers ions
journal, January 2019

  • Bartolomé, E.; Arauzo, A.; Luzón, J.
  • Dalton Transactions, Vol. 48, Issue 15
  • DOI: 10.1039/C8DT05044A

Slow magnetic relaxation of light lanthanide-based linear LnZn 2 trinuclear complexes
journal, January 2015

  • Takehara, Chika; Then, Poh Ling; Kataoka, Yumiko
  • Dalton Transactions, Vol. 44, Issue 41
  • DOI: 10.1039/C5DT03148F

Slow magnetic relaxation in a neodymium metallocene tetraphenylborate complex
journal, February 2018


Initial Observation of Magnetization Hysteresis and Quantum Tunneling in Mixed Manganese−Lanthanide Single-Molecule Magnets
journal, December 2004

  • Mishra, Abhudaya; Wernsdorfer, Wolfgang; Abboud, Khalil A.
  • Journal of the American Chemical Society, Vol. 126, Issue 48
  • DOI: 10.1021/ja0452727

An empirical correction for absorption anisotropy
journal, January 1995

  • Blessing, R. H.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 51, Issue 1
  • DOI: 10.1107/S0108767394005726

MOLCAS 7: The Next Generation
journal, January 2010

  • Aquilante, Francesco; De Vico, Luca; Ferré, Nicolas
  • Journal of Computational Chemistry, Vol. 31, Issue 1
  • DOI: 10.1002/jcc.21318

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Slow magnetic relaxation in homoleptic trispyrazolylborate complexes of neodymium(iii) and uranium(iii)
journal, January 2012

  • Rinehart, Jeffrey D.; Long, Jeffrey R.
  • Dalton Transactions, Vol. 41, Issue 44
  • DOI: 10.1039/c2dt31352a

Neodymium 1D systems: targeting new sources for field-induced slow magnetization relaxation
journal, January 2015

  • Jassal, Amanpreet Kaur; Aliaga-Alcalde, Núria; Corbella, Montserrat
  • Dalton Transactions, Vol. 44, Issue 36
  • DOI: 10.1039/C5DT02533H

Structural diversity and photo-physical and magnetic properties of dimeric to 1D polymeric coordination polymers of lighter lanthanide( iii ) dinitrobenzoates
journal, January 2018

  • Jassal, Amanpreet Kaur; Sran, Balkaran Singh; Suffren, Yan
  • Dalton Transactions, Vol. 47, Issue 13
  • DOI: 10.1039/C7DT04596D

Crystal data of hydrates of yttrium(III) and lanthanide(III) complexes with 2-furancarboxylic acid, Ln(C 5 H 3 O 3 ) 3 · n H 2 O ( n = 2 or 3)
journal, January 1986

  • Klimek, Bożena; Kozioł, Anna E.; St[unk]pniak, Krystyna
  • Zeitschrift für Kristallographie, Vol. 174, Issue 1-4
  • DOI: 10.1524/zkri.1986.174.1-4.305

Heteronuclear {Tb x Eu 1−x } furoate 1D polymers presenting luminescent properties and SMM behavior
journal, January 2018

  • Bartolomé, E.; Bartolomé, J.; Arauzo, A.
  • Journal of Materials Chemistry C, Vol. 6, Issue 19
  • DOI: 10.1039/C8TC00832A

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets
journal, January 2011

  • Rinehart, Jeffrey D.; Long, Jeffrey R.
  • Chemical Science, Vol. 2, Issue 11
  • DOI: 10.1039/c1sc00513h

Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes
journal, January 2014

  • Lucaccini, Eva; Sorace, Lorenzo; Perfetti, Mauro
  • Chem. Commun., Vol. 50, Issue 14
  • DOI: 10.1039/C3CC48866G

A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior
journal, January 2018

  • Zhang, Hai-Long; Wu, Xiao-Yuan; Liao, Jian-Zhen
  • Dalton Transactions, Vol. 47, Issue 6
  • DOI: 10.1039/C7DT04908K

Slow Magnetic Relaxation in Uranium(III) and Neodymium(III) Cyclooctatetraenyl Complexes
journal, April 2015

  • Le Roy, Jennifer J.; Gorelsky, Serge I.; Korobkov, Ilia
  • Organometallics, Vol. 34, Issue 8
  • DOI: 10.1021/om501214c

Antiferromagnetic single-chain magnet slow relaxation in the {Tb(α-fur) 3 } n polymer with non-Kramers ions
journal, January 2016

  • Bartolomé, E.; Bartolomé, J.; Arauzo, A.
  • Journal of Materials Chemistry C, Vol. 4, Issue 22
  • DOI: 10.1039/C6TC00919K

Uncommon lanthanide ions in purely 4 f Single Molecule Magnets
journal, September 2017

  • Pointillart, Fabrice; Cador, Olivier; Le Guennic, Boris
  • Coordination Chemistry Reviews, Vol. 346
  • DOI: 10.1016/j.ccr.2016.12.017

Construction of a General Library for the Rational Design of Nanomagnets and Spin Qubits Based on Mononuclear f-Block Complexes. The Polyoxometalate Case
journal, August 2014

  • Baldoví, José J.; Clemente-Juan, Juan M.; Coronado, Eugenio
  • Inorganic Chemistry, Vol. 53, Issue 18
  • DOI: 10.1021/ic501867d

The Crystal and Molecular Structure of Praseodymium(Iii) 2-Furancarboxylate Dihydrate
journal, February 1987


Magnetic Anisotropy in a Dysprosium/DOTA Single-Molecule Magnet: Beyond Simple Magneto-Structural Correlations
journal, January 2012

  • Cucinotta, Giuseppe; Perfetti, Mauro; Luzon, Javier
  • Angewandte Chemie International Edition, Vol. 51, Issue 7
  • DOI: 10.1002/anie.201107453

Magnetic relaxation versus 3D long-range ordering in {Dy 2 Ba(α-fur) 8 } n furoate polymers
journal, January 2014

  • Bartolomé, E.; Bartolomé, J.; Melnic, S.
  • Dalton Trans., Vol. 43, Issue 28
  • DOI: 10.1039/C4DT00538D

OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009

  • Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J.
  • Journal of Applied Crystallography, Vol. 42, Issue 2
  • DOI: 10.1107/S0021889808042726

An unprecedented zero field neodymium( iii ) single-ion magnet based on a phosphonic diamide
journal, January 2016

  • Gupta, Sandeep K.; Rajeshkumar, Thayalan; Rajaraman, Gopalan
  • Chemical Communications, Vol. 52, Issue 44
  • DOI: 10.1039/C6CC03066A

Relativistic quantum chemistry: the multiconfigurational approach
journal, January 2004

  • Roos, Bj�rn O.; Malmqvist, Per-�ke
  • Physical Chemistry Chemical Physics, Vol. 6, Issue 11
  • DOI: 10.1039/b401472n

Magnetic anisotropy investigation on light lanthanide complexes
journal, January 2018

  • Xu, Mei-Xing; Meng, Yin-Shan; Xiong, Jin
  • Dalton Transactions, Vol. 47, Issue 6
  • DOI: 10.1039/C7DT04351A

Controlled Synthesis of Heterotrimetallic Single-Chain Magnets from Anisotropic High-Spin 3 d-4 f Nodes and Paramagnetic Spacers
journal, December 2012

  • Yao, Min-Xia; Zheng, Qi; Qian, Kang
  • Chemistry - A European Journal, Vol. 19, Issue 1
  • DOI: 10.1002/chem.201203361

Dinuclear Ln III Complexes with 9-Anthracenecarboxylate Showing Field-Induced SMM and Visible/NIR Luminescence : Dinuclear Ln
journal, August 2018

  • Casanovas, Berta; Speed, Saskia; Maury, Olivier
  • European Journal of Inorganic Chemistry, Vol. 2018, Issue 34
  • DOI: 10.1002/ejic.201800624

Synthesis, crystal structure, magnetic and luminescence investigations of new 2Ln3+–Sr2+ heteronuclear polymers with 2-furoic acid
journal, June 2007

  • Turta, Constantin; Melnic, Silvia; Bettinelli, Marco
  • Inorganica Chimica Acta, Vol. 360, Issue 9
  • DOI: 10.1016/j.ica.2007.02.045

{Dy(α-fur)3}n: from double relaxation single-ion magnet behavior to 3D ordering
journal, January 2013

  • Bartolomé, Elena; Bartolomé, Juan; Melnic, Silvia
  • Dalton Transactions, Vol. 42, Issue 28
  • DOI: 10.1039/c3dt51080h

Field-Induced SMM and Visible/NIR-Luminescence Behaviour of Dinuclear Ln III Complexes with 2-Fluorobenzoate : Field-Induced SMM and Visible/NIR-Luminescence Behaviour of Dinuclear Ln
journal, May 2018

  • Casanovas, Berta; Font-Bardía, Mercè; Speed, Saskia
  • European Journal of Inorganic Chemistry, Vol. 2018, Issue 18
  • DOI: 10.1002/ejic.201800229

Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand
journal, December 2016


Light Lanthanide Complexes with Crown Ether and Its Aza Derivative Which Show Slow Magnetic Relaxation Behaviors
journal, December 2016


Synthesis, structure and magnetic properties of unsymmetrical dodecanuclear Mn–Ln clusters
journal, August 2008


Low-Temperature Quantum Relaxation in a System of Magnetic Nanomolecules
journal, June 1998


    Works referencing / citing this record:

    Magnetic Anisotropy in a Dysprosium/DOTA Single-Molecule Magnet: Beyond Simple Magneto-Structural Correlations
    journal, January 2012

    • Cucinotta, Giuseppe; Perfetti, Mauro; Luzon, Javier
    • Angewandte Chemie International Edition, Vol. 51, Issue 7
    • DOI: 10.1002/anie.201107453

    Controlled Synthesis of Heterotrimetallic Single-Chain Magnets from Anisotropic High-Spin 3 d-4 f Nodes and Paramagnetic Spacers
    journal, December 2012

    • Yao, Min-Xia; Zheng, Qi; Qian, Kang
    • Chemistry - A European Journal, Vol. 19, Issue 1
    • DOI: 10.1002/chem.201203361

    Field-Induced SMM and Visible/NIR-Luminescence Behaviour of Dinuclear Ln III Complexes with 2-Fluorobenzoate : Field-Induced SMM and Visible/NIR-Luminescence Behaviour of Dinuclear Ln
    journal, May 2018

    • Casanovas, Berta; Font-Bardía, Mercè; Speed, Saskia
    • European Journal of Inorganic Chemistry, Vol. 2018, Issue 18
    • DOI: 10.1002/ejic.201800229

    MOLCAS 7: The Next Generation
    journal, January 2010

    • Aquilante, Francesco; De Vico, Luca; Ferré, Nicolas
    • Journal of Computational Chemistry, Vol. 31, Issue 1
    • DOI: 10.1002/jcc.21318

    Uncommon lanthanide ions in purely 4 f Single Molecule Magnets
    journal, September 2017

    • Pointillart, Fabrice; Cador, Olivier; Le Guennic, Boris
    • Coordination Chemistry Reviews, Vol. 346
    • DOI: 10.1016/j.ccr.2016.12.017

    Synthesis, crystal structure, magnetic and luminescence investigations of new 2Ln3+–Sr2+ heteronuclear polymers with 2-furoic acid
    journal, June 2007

    • Turta, Constantin; Melnic, Silvia; Bettinelli, Marco
    • Inorganica Chimica Acta, Vol. 360, Issue 9
    • DOI: 10.1016/j.ica.2007.02.045

    Slow magnetic relaxation in a neodymium metallocene tetraphenylborate complex
    journal, February 2018


    Synthesis, structure and magnetic properties of unsymmetrical dodecanuclear Mn–Ln clusters
    journal, August 2008


    Light Lanthanide Complexes with Crown Ether and Its Aza Derivative Which Show Slow Magnetic Relaxation Behaviors
    journal, December 2016


    Construction of a General Library for the Rational Design of Nanomagnets and Spin Qubits Based on Mononuclear f-Block Complexes. The Polyoxometalate Case
    journal, August 2014

    • Baldoví, José J.; Clemente-Juan, Juan M.; Coronado, Eugenio
    • Inorganic Chemistry, Vol. 53, Issue 18
    • DOI: 10.1021/ic501867d

    Initial Observation of Magnetization Hysteresis and Quantum Tunneling in Mixed Manganese−Lanthanide Single-Molecule Magnets
    journal, December 2004

    • Mishra, Abhudaya; Wernsdorfer, Wolfgang; Abboud, Khalil A.
    • Journal of the American Chemical Society, Vol. 126, Issue 48
    • DOI: 10.1021/ja0452727

    Slow Magnetic Relaxation in Uranium(III) and Neodymium(III) Cyclooctatetraenyl Complexes
    journal, April 2015

    • Le Roy, Jennifer J.; Gorelsky, Serge I.; Korobkov, Ilia
    • Organometallics, Vol. 34, Issue 8
    • DOI: 10.1021/om501214c

    Relativistic quantum chemistry: the multiconfigurational approach
    journal, January 2004

    • Roos, Bj�rn O.; Malmqvist, Per-�ke
    • Physical Chemistry Chemical Physics, Vol. 6, Issue 11
    • DOI: 10.1039/b401472n

    Exploiting single-ion anisotropy in the design of f-element single-molecule magnets
    journal, January 2011

    • Rinehart, Jeffrey D.; Long, Jeffrey R.
    • Chemical Science, Vol. 2, Issue 11
    • DOI: 10.1039/c1sc00513h

    Slow magnetic relaxation in homoleptic trispyrazolylborate complexes of neodymium(iii) and uranium(iii)
    journal, January 2012

    • Rinehart, Jeffrey D.; Long, Jeffrey R.
    • Dalton Transactions, Vol. 41, Issue 44
    • DOI: 10.1039/c2dt31352a

    {Dy(α-fur)3}n: from double relaxation single-ion magnet behavior to 3D ordering
    journal, January 2013

    • Bartolomé, Elena; Bartolomé, Juan; Melnic, Silvia
    • Dalton Transactions, Vol. 42, Issue 28
    • DOI: 10.1039/c3dt51080h

    The Crystal and Molecular Structure of Praseodymium(Iii) 2-Furancarboxylate Dihydrate
    journal, February 1987


    Crystal data of hydrates of yttrium(III) and lanthanide(III) complexes with 2-furancarboxylic acid, Ln(C 5 H 3 O 3 ) 3 · n H 2 O ( n = 2 or 3)
    journal, January 1986

    • Klimek, Bożena; Kozioł, Anna E.; St[unk]pniak, Krystyna
    • Zeitschrift für Kristallographie, Vol. 174, Issue 1-4
    • DOI: 10.1524/zkri.1986.174.1-4.305

    Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand
    journal, December 2016


      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.