Tracking the Chemical and Structural Evolution of the TiS2 Electrode in the Lithium-Ion Cell Using Operando X-ray Absorption Spectroscopy

Zhang, Liang; Sun, Dan; Kang, Jun; Wang, Hsiao-Tsu; Hsieh, Shang-Hsien; Pong, Way-Faung; Bechtel, Hans A.; Feng, Jun; Wang, Lin-Wang; Cairns, Elton J.; Guo, Jinghua

doi:10.1021/acs.nanolett.8b01680

Title: Tracking the Chemical and Structural Evolution of the TiS₂ Electrode in the Lithium-Ion Cell Using Operando X-ray Absorption Spectroscopy

Journal Article · 01 June 2018 · Nano Letters

DOI: https://doi.org/10.1021/acs.nanolett.8b01680 · OSTI ID:1530367

^[1]; Sun, Dan ^[1]; Kang, Jun ^[1]; Wang, Hsiao-Tsu ^[2]; Hsieh, Shang-Hsien ^[3]; Pong, Way-Faung ^[4]; Bechtel, Hans A. ^[1]; Feng, Jun ^[1]; Wang, Lin-Wang ^[1];

^[5];

^[6]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
National Tsing Hua Univ., Hsinchu (Taiwan)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Tamkang Univ., Tamsui (Taiwan)
Tamkang Univ., Tamsui (Taiwan)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Santa Cruz, CA (United States)

As the lightest and cheapest transition metal dichalcogenide, TiS₂ possesses great potential as an electrode material for lithium batteries due to the advantages of high energy density storage capability, fast ion diffusion rate, and low volume expansion. Despite the extensive investigation of its electrochemical properties, the fundamental discharge-charge reaction mechanism of the TiS₂ electrode is still elusive. In this paper, by a combination of ex situ and operando X-ray absorption spectroscopy with density functional theory calculations, we have clearly elucidated the evolution of the structural and chemical properties of TiS₂ during the discharge-charge processes. The lithium intercalation reaction is highly reversible and both Ti and sulfur are involved in the redox reaction during the discharge and charge processes. In contrast, the conversion reaction of TiS₂ is partially reversible in the first cycle. However, Ti–O related compounds are developed during electrochemical cycling over extended cycles, which results in the decrease of the conversion reaction reversibility and the rapid capacity fading. In addition, the solid electrolyte interphase formed on the electrode surface is found to be highly dynamic in the initial cycles and then gradually becomes more stable upon further cycling. Finally, such understanding is important for the future design and optimization of TiS₂ based electrodes for lithium batteries.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1530367

Journal Information:: Nano Letters, Vol. 18, Issue 7; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 49 works

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References (63)

Recent Developments on and Prospects for Electrode Materials with Hierarchical Structures for Lithium-Ion Batteries Zhou, Limin; Zhang, Kai; Hu, Zhe Advanced Energy Materials, Vol. 8, Issue 6 https://doi.org/10.1002/aenm.201701415	journal	November 2017
Design of Complex Nanomaterials for Energy Storage: Past Success and Future Opportunity Liu, Yayuan; Zhou, Guangmin; Liu, Kai Accounts of Chemical Research, Vol. 50, Issue 12 https://doi.org/10.1021/acs.accounts.7b00450	journal	December 2017
The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
Recent Advances in Ultrathin Two-Dimensional Nanomaterials Tan, Chaoliang; Cao, Xiehong; Wu, Xue-Jun Chemical Reviews, Vol. 117, Issue 9 https://doi.org/10.1021/acs.chemrev.6b00558	journal	March 2017
Nanostructured Metal Chalcogenides for Energy Storage and Electrocatalysis Zhang, Yu; Zhou, Qian; Zhu, Jixin Advanced Functional Materials, Vol. 27, Issue 35 https://doi.org/10.1002/adfm.201702317	journal	August 2017
MoS ₂ -Based Nanocomposites for Electrochemical Energy Storage Wang, Tianyi; Chen, Shuangqiang; Pang, Huan Advanced Science, Vol. 4, Issue 2 https://doi.org/10.1002/advs.201600289	journal	December 2016
Electrical Energy Storage and Intercalation Chemistry Whittingham, M. S. Science, Vol. 192, Issue 4244 https://doi.org/10.1126/science.192.4244.1126	journal	June 1976
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
A facile surface chemistry route to a stabilized lithium metal anode Liang, Xiao; Pang, Quan; Kochetkov, Ivan R. Nature Energy, Vol. 2, Issue 9 https://doi.org/10.1038/nenergy.2017.119	journal	July 2017
Titanium Disulfide Coated Carbon Nanotube Hybrid Electrodes Enable High Energy Density Symmetric Pseudocapacitors Zang, Xining; Shen, Caiwei; Kao, Emmeline Advanced Materials, Vol. 30, Issue 5 https://doi.org/10.1002/adma.201704754	journal	December 2017
All-solid-state disordered LiTiS ₂ pseudocapacitor Whiteley, Justin M.; Hafner, Simon; Han, Sang Sub Journal of Materials Chemistry A, Vol. 5, Issue 30 https://doi.org/10.1039/C7TA03756B	journal	January 2017
Unveiling two-dimensional TiS ₂ as an insertion host for the construction of high energy Li-ion capacitors Chaturvedi, Apoorva; Hu, Peng; Aravindan, Vanchiappan Journal of Materials Chemistry A, Vol. 5, Issue 19 https://doi.org/10.1039/C7TA01594A	journal	January 2017
All-solid-state lithium-ion batteries with TiS ₂ nanosheets and sulphide solid electrolytes Oh, Dae Yang; Choi, Young Eun; Kim, Dong Hyeon Journal of Materials Chemistry A, Vol. 4, Issue 26 https://doi.org/10.1039/C6TA01628F	journal	January 2016
The lithium intercalates of the transition metal dichalcogenides Whittingham, M. Stanley; Gamble, Fred R. Materials Research Bulletin, Vol. 10, Issue 5 https://doi.org/10.1016/0025-5408(75)90006-9	journal	May 1975
Hybrid Mg ²⁺ /Li ⁺ Battery with Long Cycle Life and High Rate Capability Gao, Tao; Han, Fudong; Zhu, Yujie Advanced Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aenm.201401507	journal	November 2014
High Power Nanocomposite TiS2 Cathodes for All-Solid-State Lithium Batteries Trevey, James E.; Stoldt, Conrad R.; Lee, Se-Hee Journal of The Electrochemical Society, Vol. 158, Issue 12 https://doi.org/10.1149/2.017112jes	journal	January 2011
TiS2–MWCNT hybrid as high performance anode in lithium-ion battery Kartick, B.; Srivastava, Suneel Kumar; Mahanty, Sourindra Journal of Nanoparticle Research, Vol. 15, Issue 9 https://doi.org/10.1007/s11051-013-1950-5	journal	August 2013
Fabrication of nanostructured silicon by metal-assisted etching and its effects on matrix-free laser desorption/ionization mass spectrometry Chen, W. Y.; Huang, J. T.; Cheng, Y. C. Analytica Chimica Acta, Vol. 687, Issue 2 https://doi.org/10.1016/j.aca.2010.11.041	journal	February 2011
“Water-in-Salt” electrolyte enabled LiMn2O4/TiS2 Lithium-ion batteries Sun, Wei; Suo, Liumin; Wang, Fei Electrochemistry Communications, Vol. 82 https://doi.org/10.1016/j.elecom.2017.07.016	journal	September 2017
Electrochemical determination of the lithium ion diffusion coefficient in TiS2 Vaccaro, A.; Palanisamy, T.; Kerr, R. Solid State Ionics, Vol. 2, Issue 4 https://doi.org/10.1016/0167-2738(81)90036-9	journal	November 1981
Transition metal sulfides as cathodes for secondary lithium batteries—II. titanium sulfides Holleck, G. L.; Driscoll, J. R. Electrochimica Acta, Vol. 22, Issue 6 https://doi.org/10.1016/0013-4686(77)85134-7	journal	June 1977
Dynamic X‐Ray Diffraction Chianelli, R. R.; Scanlon, J. C.; Rao, B. M. L. Journal of The Electrochemical Society, Vol. 125, Issue 10 https://doi.org/10.1149/1.2131244	journal	October 1978
Experimental and theoretical studies of the electronic structure of Ti S 2 Wu, Z. Y.; Lemoigno, F.; Gressier, P. Physical Review B, Vol. 54, Issue 16 https://doi.org/10.1103/PhysRevB.54.R11009	journal	October 1996
Sulfur K -Edge X-Ray-Absorption Study of the Charge Transfer upon Lithium Intercalation into Titanium Disulfide Wu, Z. Y.; Ouvrard, G.; Lemaux, S. Physical Review Letters, Vol. 77, Issue 10 https://doi.org/10.1103/PhysRevLett.77.2101	journal	September 1996
Electronic structures and charge transfer in lithium and mercury intercalated titanium disulfides Moreau, P.; Ouvrard, G.; Gressier, P. Journal of Physics and Chemistry of Solids, Vol. 57, Issue 6-8 https://doi.org/10.1016/0022-3697(95)00408-4	journal	June 1996
State-of-the-art characterization techniques for advanced lithium-ion batteries Lu, Jun; Wu, Tianpin; Amine, Khalil Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.11	journal	March 2017
Application of Synchrotron Radiation Technologies to Electrode Materials for Li- and Na-Ion Batteries Huang, Weifeng; Marcelli, Augusto; Xia, Dingguo Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201700460	journal	July 2017
Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries Lin, Feng; Liu, Yijin; Yu, Xiqian Chemical Reviews, Vol. 117, Issue 21 https://doi.org/10.1021/acs.chemrev.7b00007	journal	September 2017
Li Intercalation into 1D TiS ₂ (en) Chains Li, Tianyang; Liu, Yi-Hsin; Chitara, Basant Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja4132399	journal	February 2014
Phase evolution for conversion reaction electrodes in lithium-ion batteries Lin, Feng; Nordlund, Dennis; Weng, Tsu-Chien Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4358	journal	February 2014
In Situ X-Ray Absorption Spectroscopic Study of Li[sub 1.05]Ni[sub 0.35]Co[sub 0.25]Mn[sub 0.4]O[sub 2] Cathode Material Coated with LiCoO[sub 2] Deb, Aniruddha; Bergmann, Uwe; Cramer, Stephen P. Journal of The Electrochemical Society, Vol. 154, Issue 6 https://doi.org/10.1149/1.2720762	journal	January 2007
Na-Ion Intercalation and Charge Storage Mechanism in 2D Vanadium Carbide Bak, Seong-Min; Qiao, Ruimin; Yang, Wanli Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201700959	journal	July 2017
In Situ Electrochemistry of Rechargeable Battery Materials: Status Report and Perspectives Yang, Yijun; Liu, Xizheng; Dai, Zhonghua Advanced Materials, Vol. 29, Issue 31 https://doi.org/10.1002/adma.201606922	journal	June 2017
Investigation of electronic and local structural changes during lithium uptake and release of nano-crystalline NiFe2O4 by X-ray absorption spectroscopy Zhou, Dong; Permien, Stefan; Rana, Jatinkumar Journal of Power Sources, Vol. 342 https://doi.org/10.1016/j.jpowsour.2016.12.038	journal	February 2017
In Situ X-ray Absorption Spectroscopic Study on LiNi _0.5 Mn _0.5 O ₂ Cathode Material during Electrochemical Cycling Yoon, Won-Sub; Grey, Clare P.; Balasubramanian, Mahalingam Chemistry of Materials, Vol. 15, Issue 16 https://doi.org/10.1021/cm030220m	journal	August 2003
First principles study of nanostructured TiS2 electrodes for Na and Mg ion storage Li, S. N.; Liu, J. B.; Liu, B. X. Journal of Power Sources, Vol. 320 https://doi.org/10.1016/j.jpowsour.2016.04.122	journal	July 2016
The electronic structure and ionic diffusion of nanoscale LiTiO2 anatase Borghols, W. J. H.; Lützenkirchen-Hecht, D.; Haake, U. Physical Chemistry Chemical Physics, Vol. 11, Issue 27 https://doi.org/10.1039/b823142g	journal	January 2009
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions (Adv. Mater. 35/2010) Cabana, Jordi; Monconduit, Laure; Larcher, Dominique Advanced Materials, Vol. 22, Issue 35 https://doi.org/10.1002/adma.201090116	journal	September 2010
Catalytic oxidation of Li ₂ S on the surface of metal sulfides for Li−S batteries Zhou, Guangmin; Tian, Hongzhen; Jin, Yang Proceedings of the National Academy of Sciences, Vol. 114, Issue 5 https://doi.org/10.1073/pnas.1615837114	journal	January 2017
Sulfiphilic Nickel Phosphosulfide Enabled Li ₂ S Impregnation in 3D Graphene Cages for Li-S Batteries Zhou, Guangmin; Sun, Jie; Jin, Yang Advanced Materials, Vol. 29, Issue 12 https://doi.org/10.1002/adma.201603366	journal	January 2017
Amorphous Metal Polysulfides: Electrode Materials with Unique Insertion/Extraction Reactions Sakuda, Atsushi; Ohara, Koji; Fukuda, Katsutoshi Journal of the American Chemical Society, Vol. 139, Issue 26 https://doi.org/10.1021/jacs.7b03909	journal	June 2017
Electrochemically Induced High Capacity Displacement Reaction of PEO/MoS2/Graphene Nanocomposites with Lithium Xiao, Jie; Wang, Xiaojian; Yang, Xiao-Qing Advanced Functional Materials, Vol. 21, Issue 15 https://doi.org/10.1002/adfm.201002752	journal	May 2011
Multiple Redox Modes in the Reversible Lithiation of High-Capacity, Peierls-Distorted Vanadium Sulfide Britto, Sylvia; Leskes, Michal; Hua, Xiao Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b03395	journal	June 2015
Revealing the Electrochemical Charging Mechanism of Nanosized Li ₂ S by in Situ and Operando X-ray Absorption Spectroscopy Zhang, Liang; Sun, Dan; Feng, Jun Nano Letters, Vol. 17, Issue 8 https://doi.org/10.1021/acs.nanolett.7b02381	journal	July 2017
Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy Gorlin, Yelena; Patel, Manu U. M.; Freiberg, Anna Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.0631606jes	journal	January 2016
Electrochemical Reaction Mechanism of the MoS ₂ Electrode in a Lithium-Ion Cell Revealed by in Situ and Operando X-ray Absorption Spectroscopy Zhang, Liang; Sun, Dan; Kang, Jun Nano Letters, Vol. 18, Issue 2 https://doi.org/10.1021/acs.nanolett.7b05246	journal	January 2018
Lithium ion battery applications of molybdenum disulfide (MoS ₂ ) nanocomposites Stephenson, Tyler; Li, Zhi; Olsen, Brian Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42591F	journal	January 2014
Structure and Electrochemistry of Copper Fluoride Nanocomposites Utilizing Mixed Conducting Matrices Badway, F.; Mansour, A. N.; Pereira, N. Chemistry of Materials, Vol. 19, Issue 17, p. 4129-4141 https://doi.org/10.1021/cm070421g	journal	August 2007
Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes Wang, Feng; Robert, Rosa; Chernova, Natasha A. Journal of the American Chemical Society, Vol. 133, Issue 46 https://doi.org/10.1021/ja206268a	journal	November 2011
Breathing and oscillating growth of solid-electrolyte-interphase upon electrochemical cycling Zhuo, Zengqing; Lu, Peng; Delacourt, Charles Chemical Communications, Vol. 54, Issue 7 https://doi.org/10.1039/C7CC07082A	journal	January 2018
Review—SEI: Past, Present and Future Peled, E.; Menkin, S. Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.1441707jes	journal	January 2017
Conversion Reaction-Based Oxide Nanomaterials for Lithium Ion Battery Anodes Yu, Seung-Ho; Lee, Soo Hong; Lee, Dong Jun Small, Vol. 12, Issue 16 https://doi.org/10.1002/smll.201502299	journal	December 2015
Unstable Single‐Layered Colloidal TiS ₂ Nanodisks Park, Kang Hyun; Choi, Jaewon; Kim, Hae Jin Small, Vol. 4, Issue 7 https://doi.org/10.1002/smll.200700804	journal	July 2008
Evaluation of High-Resolution X-ray Absorption and Emission Spectroscopy for the Chemical Speciation of Binary Titanium Compounds Reinhardt, F.; Beckhoff, B.; Eba, H. Analytical Chemistry, Vol. 81, Issue 5 https://doi.org/10.1021/ac8018069	journal	March 2009
XAFS Study on the Specific Deoxidation Behavior of Iron Titanate Catalyst for the Selective Catalytic Reduction of NO _x with NH ₃ Liu, Fudong; He, Hong; Xie, Lijuan ChemCatChem, Vol. 5, Issue 12 https://doi.org/10.1002/cctc.201300565	journal	October 2013
Phase Transformations in TiS ₂ during K Intercalation Tian, Bingbing; Tang, Wei; Leng, Kai ACS Energy Letters, Vol. 2, Issue 8 https://doi.org/10.1021/acsenergylett.7b00529	journal	July 2017
Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries Yoo, Hyun Deog; Liang, Yanliang; Dong, Hui Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00431-9	journal	August 2017
Layered TiS ₂ Positive Electrode for Mg Batteries Sun, Xiaoqi; Bonnick, Patrick; Nazar, Linda F. ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00145	journal	June 2016
Air-stable and freestanding lithium alloy/graphene foil as an alternative to lithium metal anodes Zhao, Jie; Zhou, Guangmin; Yan, Kai Nature Nanotechnology, Vol. 12, Issue 10 https://doi.org/10.1038/nnano.2017.129	journal	July 2017
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994

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36 MATERIALS SCIENCE
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Lithium ion batteries
TiS2
electronic structure
in situ and operando
X-ray absorption spectroscopy

Title: Tracking the Chemical and Structural Evolution of the TiS2 Electrode in the Lithium-Ion Cell Using Operando X-ray Absorption Spectroscopy

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