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Title: Postmodification of a supramolecular organic framework: Visible-light-induced recyclable heterogeneous photocatalysis for the reduction of azides to amines

Abstract

In this work, we present the postmodification of a diamondoid 3D supramolecular organic framework (SOF) to append [Ru(BPY)3]2+ groups through the formation of a hydrazone bond. The resulting SOF works as an efficient recyclable heterogeneous catalyst for visible-light-induced reduction of aromatic azides to amines.

Authors:
 [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Fudan Univ., Shanghai (China)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1530278
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 100; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wu, Yi-Peng, Yang, Bo, Tian, Jia, Yu, Shang-Bo, Wang, Hui, Zhang, Dan-Wei, Liu, Yi, and Li, Zhan-Ting. Postmodification of a supramolecular organic framework: Visible-light-induced recyclable heterogeneous photocatalysis for the reduction of azides to amines. United States: N. p., 2017. Web. doi:10.1039/c7cc08824h.
Wu, Yi-Peng, Yang, Bo, Tian, Jia, Yu, Shang-Bo, Wang, Hui, Zhang, Dan-Wei, Liu, Yi, & Li, Zhan-Ting. Postmodification of a supramolecular organic framework: Visible-light-induced recyclable heterogeneous photocatalysis for the reduction of azides to amines. United States. doi:10.1039/c7cc08824h.
Wu, Yi-Peng, Yang, Bo, Tian, Jia, Yu, Shang-Bo, Wang, Hui, Zhang, Dan-Wei, Liu, Yi, and Li, Zhan-Ting. Mon . "Postmodification of a supramolecular organic framework: Visible-light-induced recyclable heterogeneous photocatalysis for the reduction of azides to amines". United States. doi:10.1039/c7cc08824h. https://www.osti.gov/servlets/purl/1530278.
@article{osti_1530278,
title = {Postmodification of a supramolecular organic framework: Visible-light-induced recyclable heterogeneous photocatalysis for the reduction of azides to amines},
author = {Wu, Yi-Peng and Yang, Bo and Tian, Jia and Yu, Shang-Bo and Wang, Hui and Zhang, Dan-Wei and Liu, Yi and Li, Zhan-Ting},
abstractNote = {In this work, we present the postmodification of a diamondoid 3D supramolecular organic framework (SOF) to append [Ru(BPY)3]2+ groups through the formation of a hydrazone bond. The resulting SOF works as an efficient recyclable heterogeneous catalyst for visible-light-induced reduction of aromatic azides to amines.},
doi = {10.1039/c7cc08824h},
journal = {ChemComm},
number = 100,
volume = 53,
place = {United States},
year = {2017},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 16 works
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Figures / Tables:

Figure 1 Figure 1: The formation of 3D diamondoid SOF-CHO from 1 and CB[8] and its postsynthetic modification with [Ru(BPY)3]2+-attached acylhydrazine 2 to afford SOF-CH=N-[Ru(BPY)3].

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