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Title: Infrared vibrational nano-crystallography and nano-imaging

Abstract

Molecular solids and polymers can form low-symmetry crystal structures that exhibit anisotropic electron and ion mobility in engineered devices or biological systems. The distribution of molecular orientation and disorder then controls the macroscopic material response, yet it is difficult to image with conventional techniques on the nanoscale. We demonstrated a new form of optical nanocrystallography that combines scattering-type scanning near-field optical microscopy with both optical antenna and tip-selective infrared vibrational spectroscopy. From the symmetry-selective probing of molecular bond orientation with nanometer spatial resolution, we determined crystalline phases and orientation in aggregates and films of the organic electronic material perylenetetracarboxylic dianhydride. Mapping disorder within and between individual nanoscale domains, the correlative hybrid imaging of nanoscale heterogeneity provides insight into defect formation and propagation during growth in functional molecular solids.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [1];  [1]
  1. Univ. of Colorado, Boulder, CO (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1530255
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Science Advances
Additional Journal Information:
Journal Volume: 2; Journal Issue: 10; Journal ID: ISSN 2375-2548
Publisher:
AAAS
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Muller, Eric A., Pollard, Benjamin, Bechtel, Hans A., van Blerkom, Peter, and Raschke, Markus B. Infrared vibrational nano-crystallography and nano-imaging. United States: N. p., 2016. Web. doi:10.1126/sciadv.1601006.
Muller, Eric A., Pollard, Benjamin, Bechtel, Hans A., van Blerkom, Peter, & Raschke, Markus B. Infrared vibrational nano-crystallography and nano-imaging. United States. doi:10.1126/sciadv.1601006.
Muller, Eric A., Pollard, Benjamin, Bechtel, Hans A., van Blerkom, Peter, and Raschke, Markus B. Fri . "Infrared vibrational nano-crystallography and nano-imaging". United States. doi:10.1126/sciadv.1601006. https://www.osti.gov/servlets/purl/1530255.
@article{osti_1530255,
title = {Infrared vibrational nano-crystallography and nano-imaging},
author = {Muller, Eric A. and Pollard, Benjamin and Bechtel, Hans A. and van Blerkom, Peter and Raschke, Markus B.},
abstractNote = {Molecular solids and polymers can form low-symmetry crystal structures that exhibit anisotropic electron and ion mobility in engineered devices or biological systems. The distribution of molecular orientation and disorder then controls the macroscopic material response, yet it is difficult to image with conventional techniques on the nanoscale. We demonstrated a new form of optical nanocrystallography that combines scattering-type scanning near-field optical microscopy with both optical antenna and tip-selective infrared vibrational spectroscopy. From the symmetry-selective probing of molecular bond orientation with nanometer spatial resolution, we determined crystalline phases and orientation in aggregates and films of the organic electronic material perylenetetracarboxylic dianhydride. Mapping disorder within and between individual nanoscale domains, the correlative hybrid imaging of nanoscale heterogeneity provides insight into defect formation and propagation during growth in functional molecular solids.},
doi = {10.1126/sciadv.1601006},
journal = {Science Advances},
number = 10,
volume = 2,
place = {United States},
year = {2016},
month = {10}
}

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Cited by: 29 works
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    Works referencing / citing this record:

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    Ultrafast structural molecular dynamics investigated with 2D infrared spectroscopy methods
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