Infrared vibrational nano-crystallography and nano-imaging
Abstract
Molecular solids and polymers can form low-symmetry crystal structures that exhibit anisotropic electron and ion mobility in engineered devices or biological systems. The distribution of molecular orientation and disorder then controls the macroscopic material response, yet it is difficult to image with conventional techniques on the nanoscale. We demonstrated a new form of optical nanocrystallography that combines scattering-type scanning near-field optical microscopy with both optical antenna and tip-selective infrared vibrational spectroscopy. From the symmetry-selective probing of molecular bond orientation with nanometer spatial resolution, we determined crystalline phases and orientation in aggregates and films of the organic electronic material perylenetetracarboxylic dianhydride. Mapping disorder within and between individual nanoscale domains, the correlative hybrid imaging of nanoscale heterogeneity provides insight into defect formation and propagation during growth in functional molecular solids.
- Authors:
-
- Univ. of Colorado, Boulder, CO (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1530255
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 10; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Muller, Eric A., Pollard, Benjamin, Bechtel, Hans A., van Blerkom, Peter, and Raschke, Markus B. Infrared vibrational nano-crystallography and nano-imaging. United States: N. p., 2016.
Web. doi:10.1126/sciadv.1601006.
Muller, Eric A., Pollard, Benjamin, Bechtel, Hans A., van Blerkom, Peter, & Raschke, Markus B. Infrared vibrational nano-crystallography and nano-imaging. United States. https://doi.org/10.1126/sciadv.1601006
Muller, Eric A., Pollard, Benjamin, Bechtel, Hans A., van Blerkom, Peter, and Raschke, Markus B. Fri .
"Infrared vibrational nano-crystallography and nano-imaging". United States. https://doi.org/10.1126/sciadv.1601006. https://www.osti.gov/servlets/purl/1530255.
@article{osti_1530255,
title = {Infrared vibrational nano-crystallography and nano-imaging},
author = {Muller, Eric A. and Pollard, Benjamin and Bechtel, Hans A. and van Blerkom, Peter and Raschke, Markus B.},
abstractNote = {Molecular solids and polymers can form low-symmetry crystal structures that exhibit anisotropic electron and ion mobility in engineered devices or biological systems. The distribution of molecular orientation and disorder then controls the macroscopic material response, yet it is difficult to image with conventional techniques on the nanoscale. We demonstrated a new form of optical nanocrystallography that combines scattering-type scanning near-field optical microscopy with both optical antenna and tip-selective infrared vibrational spectroscopy. From the symmetry-selective probing of molecular bond orientation with nanometer spatial resolution, we determined crystalline phases and orientation in aggregates and films of the organic electronic material perylenetetracarboxylic dianhydride. Mapping disorder within and between individual nanoscale domains, the correlative hybrid imaging of nanoscale heterogeneity provides insight into defect formation and propagation during growth in functional molecular solids.},
doi = {10.1126/sciadv.1601006},
journal = {Science Advances},
number = 10,
volume = 2,
place = {United States},
year = {Fri Oct 07 00:00:00 EDT 2016},
month = {Fri Oct 07 00:00:00 EDT 2016}
}
Web of Science
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