An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode

Shin, Woochul; So, Kang Pyo; Stickle, William F.; Su, Cong; Lu, Jun; Li, Ju; Ji, Xiulei

doi:10.1039/c9cc00046a

Title: An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode

Abstract

Lithium metal anodes suffer from a short cycle life, and the parasitic reactions of lithium with electrolytes are widely observed. Common sense is to avoid such reactions. Here in this paper, we head in the opposite direction by using an oxidizing co-solvent, ethyl methyl sulfone, in the electrolyte, which addresses the ‘dendrite’ issue entirely, resulting in a dense and macroscopically smooth surface morphology of the plated lithium. However, a dendrite-free lithium metal anode does not necessarily exhibit a high coulombic efficiency.

Authors:

Shin, Woochul ^[1]; So, Kang Pyo ^[2]; Stickle, William F. ^[3]; Su, Cong ^[2];

^[4];

^[2];

^[1]

Oregon State Univ., Corvallis, OR (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Hewlett-Packard Co., Corvallis, OR (Untied States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Thu Feb 21 00:00:00 EST 2019

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1530189

Alternate Identifier(s):: OSTI ID: 1497428

Grant/Contract Number:: AC02-06CH11357; EE0008194

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 55; Journal Issue: 23; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Shin, Woochul, So, Kang Pyo, Stickle, William F., Su, Cong, Lu, Jun, Li, Ju, and Ji, Xiulei. An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode.  United States: N. p., 2019. 
Web.  doi:10.1039/c9cc00046a.

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                    Shin, Woochul, So, Kang Pyo, Stickle, William F., Su, Cong, Lu, Jun, Li, Ju, & Ji, Xiulei. An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode.  United States.  https://doi.org/10.1039/c9cc00046a

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                    Shin, Woochul, So, Kang Pyo, Stickle, William F., Su, Cong, Lu, Jun, Li, Ju, and Ji, Xiulei. Thu .  
"An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode".  United States.  https://doi.org/10.1039/c9cc00046a.  https://www.osti.gov/servlets/purl/1530189.

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@article{osti_1530189,

  title        = {An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode},

  author       = {Shin, Woochul and So, Kang Pyo and Stickle, William F. and Su, Cong and Lu, Jun and Li, Ju and Ji, Xiulei},

  abstractNote = {Lithium metal anodes suffer from a short cycle life, and the parasitic reactions of lithium with electrolytes are widely observed. Common sense is to avoid such reactions. Here in this paper, we head in the opposite direction by using an oxidizing co-solvent, ethyl methyl sulfone, in the electrolyte, which addresses the ‘dendrite’ issue entirely, resulting in a dense and macroscopically smooth surface morphology of the plated lithium. However, a dendrite-free lithium metal anode does not necessarily exhibit a high coulombic efficiency.},

  doi          = {10.1039/c9cc00046a},

  journal      = {ChemComm},

  number       = 23,

  volume       = 55,

  place        = {United States},

  year         = {Thu Feb 21 00:00:00 EST 2019},

  month        = {Thu Feb 21 00:00:00 EST 2019}

}

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Works referenced in this record:

Developing High-Performance Lithium Metal Anode in Liquid Electrolytes: Challenges and Progress
journal, March 2018

Li, Sa; Jiang, Mengwen; Xie, Yong
Advanced Materials, Vol. 30, Issue 17
DOI: 10.1002/adma.201706375

Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating
journal, February 2016

Liang, Zheng; Lin, Dingchang; Zhao, Jie
Proceedings of the National Academy of Sciences, Vol. 113, Issue 11
DOI: 10.1073/pnas.1518188113

High-capacity, low-tortuosity, and channel-guided lithium metal anode
journal, March 2017

Zhang, Ying; Luo, Wei; Wang, Chengwei
Proceedings of the National Academy of Sciences, Vol. 114, Issue 14
DOI: 10.1073/pnas.1618871114

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
Nature Nanotechnology, Vol. 9, Issue 8
DOI: 10.1038/nnano.2014.152

Spatially heterogeneous carbon-fiber papers as surface dendrite-free current collectors for lithium deposition
journal, February 2012

Ji, Xiulei; Liu, De-Yu; Prendiville, Daniel G.
Nano Today, Vol. 7, Issue 1
DOI: 10.1016/j.nantod.2011.11.002

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013

Ding, Fei; Xu, Wu; Graff, Gordon L.
Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
DOI: 10.1021/ja312241y

Implantable Solid Electrolyte Interphase in Lithium-Metal Batteries
journal, February 2017

Cheng, Xin-Bing; Yan, Chong; Chen, Xiang
Chem, Vol. 2, Issue 2
DOI: 10.1016/j.chempr.2017.01.003

An improved high-performance lithium–air battery
journal, June 2012

Jung, Hun-Gi; Hassoun, Jusef; Park, Jin-Bum
Nature Chemistry, Vol. 4, Issue 7
DOI: 10.1038/nchem.1376

The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries
journal, January 1995

Aurbach, Doron
Journal of The Electrochemical Society, Vol. 142, Issue 9
DOI: 10.1149/1.2048658

Insight into lithium–metal anodes in lithium–sulfur batteries with a fluorinated ether electrolyte
journal, January 2015

Zu, Chenxi; Azimi, Nasim; Zhang, Zhengcheng
Journal of Materials Chemistry A, Vol. 3, Issue 28
DOI: 10.1039/C5TA03195H

Application of the N-propyl-N-methyl-pyrrolidinium Bis(fluorosulfonyl)imide RTIL Containing Lithium Bis(fluorosulfonyl)imide in Ionic Liquid Based Lithium Batteries
journal, January 2010

Bhatt, Anand I.; Best, Adam S.; Huang, Junhua
Journal of The Electrochemical Society, Vol. 157, Issue 1
DOI: 10.1149/1.3257978

Ionic Liquid Electrolyte for Lithium Metal Batteries: Physical, Electrochemical, and Interfacial Studies of N -Methyl- N -butylmorpholinium Bis(fluorosulfonyl)imide
journal, November 2010

Lane, George H.; Bayley, Paul M.; Clare, Bronya R.
The Journal of Physical Chemistry C, Vol. 114, Issue 49
DOI: 10.1021/jp1054809

Sulfone-based electrolytes for high-voltage Li-ion batteries
journal, May 2009

Abouimrane, A.; Belharouak, I.; Amine, K.
Electrochemistry Communications, Vol. 11, Issue 5
DOI: 10.1016/j.elecom.2009.03.020

Sulfone-Based Electrolytes for Lithium-Ion Batteries
journal, January 2002

Xu, Kang; Angell, C. Austen
Journal of The Electrochemical Society, Vol. 149, Issue 7, p. A920-A926
DOI: 10.1149/1.1483866

Electrochemical Windows of Sulfone-Based Electrolytes for High-Voltage Li-Ion Batteries
journal, October 2011

Shao, Nan; Sun, Xiao-Guang; Dai, Sheng
The Journal of Physical Chemistry B, Vol. 115, Issue 42
DOI: 10.1021/jp204401t

A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries
journal, May 2018

Alvarado, Judith; Schroeder, Marshall A.; Zhang, Minghao
Materials Today, Vol. 21, Issue 4
DOI: 10.1016/j.mattod.2018.02.005

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries
journal, August 2018

Ren, Xiaodi; Chen, Shuru; Lee, Hongkyung
Chem, Vol. 4, Issue 8
DOI: 10.1016/j.chempr.2018.05.002

Liquid cell transmission electron microscopy observation of lithium metal growth and dissolution: Root growth, dead lithium and lithium flotsams
journal, February 2017

Kushima, Akihiro; So, Kang Pyo; Su, Cong
Nano Energy, Vol. 32
DOI: 10.1016/j.nanoen.2016.12.001

Design principles for electrolytes and interfaces for stable lithium-metal batteries
journal, September 2016

Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan
Nature Energy, Vol. 1, Issue 9
DOI: 10.1038/nenergy.2016.114

III. On the concentration at the electrodes in a solution, with special reference to the liberation of hydrogen by electrolysis of a mixture of copper sulphate and sulphuric acid
journal, January 1901

Sand, Henry J. S.
The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 1, Issue 1
DOI: 10.1080/14786440109462590

The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries
journal, January 1995

Aurbach, Doron
Journal of The Electrochemical Society, Vol. 142, Issue 9
DOI: 10.1149/1.2048659

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Title: An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode

Abstract

Citation Formats

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