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Title: Improved Sodium-Ion Storage Performance of Ultrasmall Iron Selenide Nanoparticles

Abstract

Sodium-ion batteries are potential low-cost alternatives to current lithium-ion technology, yet their performances still fall short of expectation due to the lack of suitable electrode materials with large capacity, long-term cycling stability, and high-rate performance. In this work, we demonstrated that ultrasmall (similar to 5 nm) iron selenide (FeSe2) nanoparticles exhibited a remarkable activity for sodium-ion storage. Here, they were prepared from a high-temperature solution method with a narrow; size distribution and high yield and could be readily redispersed in nonpolar organic solvents. In ether-based electrolyte, FeSe2 nanoparticles exhibited a large specific capacity of similar to 500 mAh/g (close to the theoretical limit), high rate capability with, similar to 250 mAh/g retained at 10 A/g, and excellent cycling stability at both low and high current rates by virtue of their advantageous nanositing effect. Full sodium-ion batteries were also constructed from coupling FeSe2 with NASICON-type Na3V2(PO4)3 cathode and demonstrated impressive capacity and cycle ability.

Authors:
 [1];  [1];  [1];  [2];  [1];  [1];  [1];  [2]; ORCiD logo [1]; ORCiD logo [2]
  1. Soochow Univ., Suzhou (China)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1529968
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Nano Letters
Additional Journal Information:
Journal Volume: 17; Journal Issue: 7; Journal ID: ISSN 1530-6984
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; full battery; iron selenide; nanosizing effect; sodium-ion battery; ultrasmall nanoparticles

Citation Formats

Zhao, Feipeng, Shen, Sida, Cheng, Liang, Ma, Lu, Zhou, Junhua, Ye, Hualin, Han, Na, Wu, Tianpin, Li, Yanguang, and Lu, Jun. Improved Sodium-Ion Storage Performance of Ultrasmall Iron Selenide Nanoparticles. United States: N. p., 2017. Web. doi:10.1021/acs.nanolett.7b00915.
Zhao, Feipeng, Shen, Sida, Cheng, Liang, Ma, Lu, Zhou, Junhua, Ye, Hualin, Han, Na, Wu, Tianpin, Li, Yanguang, & Lu, Jun. Improved Sodium-Ion Storage Performance of Ultrasmall Iron Selenide Nanoparticles. United States. https://doi.org/10.1021/acs.nanolett.7b00915
Zhao, Feipeng, Shen, Sida, Cheng, Liang, Ma, Lu, Zhou, Junhua, Ye, Hualin, Han, Na, Wu, Tianpin, Li, Yanguang, and Lu, Jun. Mon . "Improved Sodium-Ion Storage Performance of Ultrasmall Iron Selenide Nanoparticles". United States. https://doi.org/10.1021/acs.nanolett.7b00915. https://www.osti.gov/servlets/purl/1529968.
@article{osti_1529968,
title = {Improved Sodium-Ion Storage Performance of Ultrasmall Iron Selenide Nanoparticles},
author = {Zhao, Feipeng and Shen, Sida and Cheng, Liang and Ma, Lu and Zhou, Junhua and Ye, Hualin and Han, Na and Wu, Tianpin and Li, Yanguang and Lu, Jun},
abstractNote = {Sodium-ion batteries are potential low-cost alternatives to current lithium-ion technology, yet their performances still fall short of expectation due to the lack of suitable electrode materials with large capacity, long-term cycling stability, and high-rate performance. In this work, we demonstrated that ultrasmall (similar to 5 nm) iron selenide (FeSe2) nanoparticles exhibited a remarkable activity for sodium-ion storage. Here, they were prepared from a high-temperature solution method with a narrow; size distribution and high yield and could be readily redispersed in nonpolar organic solvents. In ether-based electrolyte, FeSe2 nanoparticles exhibited a large specific capacity of similar to 500 mAh/g (close to the theoretical limit), high rate capability with, similar to 250 mAh/g retained at 10 A/g, and excellent cycling stability at both low and high current rates by virtue of their advantageous nanositing effect. Full sodium-ion batteries were also constructed from coupling FeSe2 with NASICON-type Na3V2(PO4)3 cathode and demonstrated impressive capacity and cycle ability.},
doi = {10.1021/acs.nanolett.7b00915},
journal = {Nano Letters},
number = 7,
volume = 17,
place = {United States},
year = {2017},
month = {6}
}

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Cited by: 68 works
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Figures / Tables:

Figure 1 Figure 1: Structural characterizations of FeSe2 NPs. (a) A photograph showing ~100 ml FeSe2 NP hexane solution from a single reaction batch. (b) XRD of FeSe2 NPs, (c) low-magnification TEM image and (d) corresponding size distribution histogram of FeSe2 NPs, and (e) high-magnification TEM image of FeSe2 NPs.

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Works referenced in this record:

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014


Electrochemical Energy Storage for Green Grid
journal, May 2011

  • Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
  • Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
  • DOI: 10.1021/cr100290v

Recent advances in zinc–air batteries
journal, January 2014


An ultrafast rechargeable aluminium-ion battery
journal, April 2015

  • Lin, Meng-Chang; Gong, Ming; Lu, Bingan
  • Nature, Vol. 520, Issue 7547
  • DOI: 10.1038/nature14340

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

  • Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
  • Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
  • DOI: 10.1002/aenm.201200026

Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012

  • Palomares, Verónica; Serras, Paula; Villaluenga, Irune
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02781j

Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f

The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage
journal, February 2015

  • Kundu, Dipan; Talaie, Elahe; Duffort, Victor
  • Angewandte Chemie International Edition, Vol. 54, Issue 11
  • DOI: 10.1002/anie.201410376

Recent Progress in Electrode Materials for Sodium-Ion Batteries
journal, July 2016

  • Kim, Hyungsub; Kim, Haegyeom; Ding, Zhang
  • Advanced Energy Materials, Vol. 6, Issue 19
  • DOI: 10.1002/aenm.201600943

High Capacity and Rate Capability of Amorphous Phosphorus for Sodium Ion Batteries
journal, March 2013

  • Qian, Jiangfeng; Wu, Xianyong; Cao, Yuliang
  • Angewandte Chemie International Edition, Vol. 52, Issue 17
  • DOI: 10.1002/anie.201209689

Uniform yolk–shell Sn 4 P 3 @C nanospheres as high-capacity and cycle-stable anode materials for sodium-ion batteries
journal, January 2015

  • Liu, Jun; Kopold, Peter; Wu, Chao
  • Energy & Environmental Science, Vol. 8, Issue 12
  • DOI: 10.1039/C5EE02074C

Electrospun Sb/C Fibers for a Stable and Fast Sodium-Ion Battery Anode
journal, June 2013

  • Zhu, Yujie; Han, Xiaogang; Xu, Yunhua
  • ACS Nano, Vol. 7, Issue 7
  • DOI: 10.1021/nn4025674

Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011

  • Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
  • Advanced Functional Materials, Vol. 21, Issue 20
  • DOI: 10.1002/adfm.201100854

Hard Carbon Microtubes Made from Renewable Cotton as High-Performance Anode Material for Sodium-Ion Batteries
journal, June 2016

  • Li, Yunming; Hu, Yong-Sheng; Titirici, Maria-Magdalena
  • Advanced Energy Materials, Vol. 6, Issue 18
  • DOI: 10.1002/aenm.201600659

FeS 2 microspheres with an ether-based electrolyte for high-performance rechargeable lithium batteries
journal, January 2015

  • Hu, Zhe; Zhang, Kai; Zhu, Zhiqiang
  • Journal of Materials Chemistry A, Vol. 3, Issue 24
  • DOI: 10.1039/C5TA02169C

Electrospun FeS 2 @Carbon Fiber Electrode as a High Energy Density Cathode for Rechargeable Lithium Batteries
journal, December 2015


Nano-FeS[sub 2] for Commercial Li/FeS[sub 2] Primary Batteries
journal, January 2002

  • Shao-Horn, Yang; Osmialowski, Steve; Horn, Quinn C.
  • Journal of The Electrochemical Society, Vol. 149, Issue 11
  • DOI: 10.1149/1.1513558

Nanooctahedra Particles Assembled FeSe 2 Microspheres Embedded into Sulfur-Doped Reduced Graphene Oxide Sheets As a Promising Anode for Sodium Ion Batteries
journal, May 2016

  • Zhang, Zhian; Shi, Xiaodong; Yang, Xing
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 22
  • DOI: 10.1021/acsami.5b12148

FeSe 2 Microspheres as a High-Performance Anode Material for Na-Ion Batteries
journal, April 2015


Nanomaterials for energy conversion and storage
journal, January 2013

  • Zhang, Qifeng; Uchaker, Evan; Candelaria, Stephanie L.
  • Chemical Society Reviews, Vol. 42, Issue 7
  • DOI: 10.1039/c3cs00009e

Stabilizing nickel sulfide nanoparticles with an ultrathin carbon layer for improved cycling performance in sodium ion batteries
journal, August 2016


Nanostructured CuP 2 /C composites as high-performance anode materials for sodium ion batteries
journal, January 2015

  • Zhao, Feipeng; Han, Na; Huang, Wenjing
  • Journal of Materials Chemistry A, Vol. 3, Issue 43
  • DOI: 10.1039/C5TA05781G

TiS 2 nanoplates: A high-rate and stable electrode material for sodium ion batteries
journal, February 2016


Pt-Decorated highly porous flower-like Ni particles with high mass activity for ammonia electro-oxidation
journal, January 2016

  • Liu, Jie; Chen, Bin; Kou, Yue
  • Journal of Materials Chemistry A, Vol. 4, Issue 28
  • DOI: 10.1039/C6TA02284G

Preparation of iron selenide films by selenization technique
journal, June 2002


Phase-Selective Growth of Assembled FeSe 2 Nanorods from Organometallic Polymers and Their Surface Magnetism
journal, July 2011

  • Xu, Juan; Jang, Kwonho; Lee, Jeho
  • Crystal Growth & Design, Vol. 11, Issue 7
  • DOI: 10.1021/cg2005562

A Highly Reversible Room-Temperature Sodium Metal Anode
journal, November 2015


Ultrafast Solvent-Assisted Sodium Ion Intercalation into Highly Crystalline Few-Layered Graphene
journal, December 2015


Nanostructured Mo-based electrode materials for electrochemical energy storage
journal, January 2015

  • Hu, Xianluo; Zhang, Wei; Liu, Xiaoxiao
  • Chemical Society Reviews, Vol. 44, Issue 8
  • DOI: 10.1039/C4CS00350K

Tin and Tin Compounds for Sodium Ion Battery Anodes: Phase Transformations and Performance
journal, May 2015


The Application of Metal Sulfides in Sodium Ion Batteries
journal, November 2016

  • Xiao, Ying; Lee, Seon Hwa; Sun, Yang-Kook
  • Advanced Energy Materials, Vol. 7, Issue 3
  • DOI: 10.1002/aenm.201601329

Two-Dimensional Materials for Beyond-Lithium-Ion Batteries
journal, March 2016


Advanced Organic Electrode Materials for Rechargeable Sodium-Ion Batteries
journal, December 2016


Structural studies of iron selenides prepared by mechanical alloying
journal, July 2002


Synthesis of Cubic-Shaped Pt Particles with (100) Preferential Orientation by a Quick, One-Step and Clean Electrochemical Method
journal, May 2017

  • Liu, Jie; Fan, Xiayue; Liu, Xiaorui
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 22
  • DOI: 10.1021/acsami.7b04267

Nanoarchitectured Array Electrodes for Rechargeable Lithium- and Sodium-Ion Batteries
journal, March 2016


The First Report on Excellent Cycling Stability and Superior Rate Capability of Na 3 V 2 (PO 4 ) 3 for Sodium Ion Batteries
journal, November 2012

  • Saravanan, Kuppan; Mason, Chad W.; Rudola, Ashish
  • Advanced Energy Materials, Vol. 3, Issue 4
  • DOI: 10.1002/aenm.201200803

Superior Electrochemical Performance and Storage Mechanism of Na 3 V 2 (PO 4 ) 3 Cathode for Room-Temperature Sodium-Ion Batteries
journal, October 2012


Nanoconfined Carbon-Coated Na 3 V 2 (PO 4 ) 3 Particles in Mesoporous Carbon Enabling Ultralong Cycle Life for Sodium-Ion Batteries
journal, February 2015

  • Jiang, Yu; Yang, Zhenzhong; Li, Weihan
  • Advanced Energy Materials, Vol. 5, Issue 10
  • DOI: 10.1002/aenm.201402104

Nanoflake-Assembled Hierarchical Na 3 V 2 (PO 4 ) 3 /C Microflowers: Superior Li Storage Performance and Insertion/Extraction Mechanism
journal, February 2015

  • An, Qinyou; Xiong, Fangyu; Wei, Qiulong
  • Advanced Energy Materials, Vol. 5, Issue 10
  • DOI: 10.1002/aenm.201401963

Works referencing / citing this record:

Nonaqueous Sodium‐Ion Full Cells: Status, Strategies, and Prospects
journal, March 2019


Metal–organic framework derived 3D graphene decorated NaTi 2 (PO 4 ) 3 for fast Na-ion storage
journal, January 2019

  • Wang, Lei; Huang, Zhennan; Wang, Bo
  • Nanoscale, Vol. 11, Issue 15
  • DOI: 10.1039/c9nr00610a

Porous hydrogen substituted graphyne for high capacity and ultra-stable sodium ion storage
journal, January 2019

  • Yang, Ze; Zhang, Chunfang; Hou, Zhufeng
  • Journal of Materials Chemistry A, Vol. 7, Issue 18
  • DOI: 10.1039/c9ta02100k

Recent Progress in Iron-Based Electrode Materials for Grid-Scale Sodium-Ion Batteries
journal, January 2018


Double-layer carbon protected CoS 2 nanoparticles as an advanced anode for sodium-ion batteries
journal, January 2019

  • Yao, Xiang; Cheng, Hui; Huang, Yuping
  • RSC Advances, Vol. 9, Issue 70
  • DOI: 10.1039/c9ra08558k

Progress in supercapacitors: roles of two dimensional nanotubular materials
journal, January 2020

  • Panda, Pritam Kumar; Grigoriev, Anton; Mishra, Yogendra Kumar
  • Nanoscale Advances, Vol. 2, Issue 1
  • DOI: 10.1039/c9na00307j

The State and Challenges of Anode Materials Based on Conversion Reactions for Sodium Storage
journal, March 2018


Conductive carbon nanofiber interpenetrated graphene architecture for ultra-stable sodium ion battery
journal, September 2019


Carbon-Supported Nickel Selenide Hollow Nanowires as Advanced Anode Materials for Sodium-Ion Batteries
journal, December 2017


An Investigation of the Electrochemical Behaviors of M 0.85 Se (M=Ni, Co) Materials for Alkaline Aqueous Battery
journal, January 2018

  • Zhu, Yirong; Yun, Xiaoru; Li, Jingying
  • Journal of The Electrochemical Society, Vol. 165, Issue 16
  • DOI: 10.1149/2.0371816jes

Facile and scalable synthesis of low-cost FeS@C as long-cycle anodes for sodium-ion batteries
journal, January 2019

  • Yang, Dan; Chen, Weihua; Zhang, Xixue
  • Journal of Materials Chemistry A, Vol. 7, Issue 34
  • DOI: 10.1039/c9ta05664e

Tailoring Rod-Like FeSe 2 Coated with Nitrogen-Doped Carbon for High-Performance Sodium Storage
journal, June 2018

  • Ge, Peng; Hou, Hongshuai; Li, Sijie
  • Advanced Functional Materials, Vol. 28, Issue 30
  • DOI: 10.1002/adfm.201801765

Nanostructured Conversion-Type Negative Electrode Materials for Low-Cost and High-Performance Sodium-Ion Batteries
journal, August 2018

  • Wei, Xiujuan; Wang, Xuanpeng; Tan, Xin
  • Advanced Functional Materials, Vol. 28, Issue 46
  • DOI: 10.1002/adfm.201804458

Recent progress in flexible non-lithium based rechargeable batteries
journal, January 2019

  • Liu, Yang; Sun, Zehang; Tan, Ke
  • Journal of Materials Chemistry A, Vol. 7, Issue 9
  • DOI: 10.1039/c8ta10258a

MoSe 2 /N-Doped Carbon as Anodes for Potassium-Ion Batteries
journal, August 2018


Realizing Three-Electron Redox Reactions in NASICON-Structured Na 3 MnTi(PO 4 ) 3 for Sodium-Ion Batteries
journal, January 2019


Hollow Structured Carbon@FeSe Nanocomposite as a Promising Anode Material for Li‐Ion Batteries
journal, January 2019


One step in situ synthesis of ZnS/N and S co-doped carbon composites via salt templating for lithium-ion battery applications
journal, January 2019

  • Ikram, Sadaf; Müller, Marcus; Dsoke, Sonia
  • New Journal of Chemistry, Vol. 43, Issue 33
  • DOI: 10.1039/c9nj02488c

Synchronous synthesis of Kirkendall effect induced hollow FeSe 2 /C nanospheres as anodes for high performance sodium ion batteries
journal, January 2018

  • Lan, Yang; Zhou, Jianbin; Xu, Kangli
  • Chemical Communications, Vol. 54, Issue 45
  • DOI: 10.1039/c8cc02669f

Chemical Modification of the sp‐Hybridized Carbon Atoms of Graphdiyne by Using Organic Sulfur
journal, March 2019

  • Yang, Ze; Cui, Weiwei; Wang, Kun
  • Chemistry – A European Journal, Vol. 25, Issue 22
  • DOI: 10.1002/chem.201900477

The yolk-shell FeSe@C nanobox with novel synthesis and its high performance for the anode of lithium-ion batteries
journal, May 2019


Graphene Wrapped FeSe 2 Nano‐Microspheres with High Pseudocapacitive Contribution for Enhanced Na‐Ion Storage
journal, March 2019

  • An, Changsheng; Yuan, Yifei; Zhang, Bao
  • Advanced Energy Materials, Vol. 9, Issue 18
  • DOI: 10.1002/aenm.201900356

Dual carbon-protected metal sulfides and their application to sodium-ion battery anodes
journal, January 2018

  • Zhu, Xinxin; Liu, Dan; Zheng, Dong
  • Journal of Materials Chemistry A, Vol. 6, Issue 27
  • DOI: 10.1039/c8ta03444c

Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application
journal, March 2019


Chemical Modification of the sp‐Hybridized Carbon Atoms of Graphdiyne by Using Organic Sulfur
journal, March 2019

  • Yang, Ze; Cui, Weiwei; Wang, Kun
  • Chemistry – A European Journal, Vol. 25, Issue 22
  • DOI: 10.1002/chem.201900944

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