Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Quantitative Nanoscale 3D Imaging of Intergranular Corrosion of 304 Stainless Steel Using Hard X-Ray Nanoprobe

Abstract

Multi-modal imaging, which visualizes changes in the structure and chemistry of the same region of interest in materials by combining various techniques, is becoming attractive to material scientists. Here, we describe a multi-modal approach to investigate intergranular (IG) corrosion of sensitized stainless steels using synchrotron-based nanoscale X-ray imaging with sensitivity to microstructure and chemical composition. Three-dimensional tomography of 304 stainless steel samples deteriorated by IG corrosion, was carried out using X-ray fluorescence and differential phase contrast imaging. These findings were further supported with surface imaging and chemical analysis using scanning electron microscopy and energy dispersive X-ray spectroscopy. The combined quantitative structural and chemical analysis indicates that chromium segregates along grain boundaries, cracking is due to IG corrosion, and Cr-enrichment occurs on the cracked surfaces. Such quantitative 3D imaging of Cr23C6 nucleation at grain boundaries and Cr enriched oxides at cracked surfaces is a powerful tool to correlate IG corrosion mechanisms at nanoscale with buried grain boundary structure and alloy composition. Such understanding of IG corrosion mechanisms is critical for both the development of predictive multiscale corrosion models, and the engineering of corrosion resistant materials.

Authors:
ORCiD logo [1];  [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1]
+ Show Author Affiliations
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1529885
Report Number(s):
BNL-211817-2019-JAAM
Journal ID: ISSN 0013-4651
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 166; Journal Issue: 11; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Corrosion; 3D imaging; corrosion; synchrotron

Citation Formats

Gill, Simerjeet K., Ge, Mingyuan, Yan, Hanfei, Sasaki, Kotaro, Liang, Zhixiu, Isaacs, Hugh, Kisslinger, Kim, Ecker, Lynne, and Chu, Yong S. Quantitative Nanoscale 3D Imaging of Intergranular Corrosion of 304 Stainless Steel Using Hard X-Ray Nanoprobe. United States: N. p., 2019. Web. doi:10.1149/2.0401911jes.
Copy to clipboard
Gill, Simerjeet K., Ge, Mingyuan, Yan, Hanfei, Sasaki, Kotaro, Liang, Zhixiu, Isaacs, Hugh, Kisslinger, Kim, Ecker, Lynne, & Chu, Yong S. Quantitative Nanoscale 3D Imaging of Intergranular Corrosion of 304 Stainless Steel Using Hard X-Ray Nanoprobe. United States. https://doi.org/10.1149/2.0401911jes
Copy to clipboard
Gill, Simerjeet K., Ge, Mingyuan, Yan, Hanfei, Sasaki, Kotaro, Liang, Zhixiu, Isaacs, Hugh, Kisslinger, Kim, Ecker, Lynne, and Chu, Yong S. Tue . "Quantitative Nanoscale 3D Imaging of Intergranular Corrosion of 304 Stainless Steel Using Hard X-Ray Nanoprobe". United States. https://doi.org/10.1149/2.0401911jes. https://www.osti.gov/servlets/purl/1529885.
Copy to clipboard
@article{osti_1529885,
title = {Quantitative Nanoscale 3D Imaging of Intergranular Corrosion of 304 Stainless Steel Using Hard X-Ray Nanoprobe},
author = {Gill, Simerjeet K. and Ge, Mingyuan and Yan, Hanfei and Sasaki, Kotaro and Liang, Zhixiu and Isaacs, Hugh and Kisslinger, Kim and Ecker, Lynne and Chu, Yong S.},
abstractNote = {Multi-modal imaging, which visualizes changes in the structure and chemistry of the same region of interest in materials by combining various techniques, is becoming attractive to material scientists. Here, we describe a multi-modal approach to investigate intergranular (IG) corrosion of sensitized stainless steels using synchrotron-based nanoscale X-ray imaging with sensitivity to microstructure and chemical composition. Three-dimensional tomography of 304 stainless steel samples deteriorated by IG corrosion, was carried out using X-ray fluorescence and differential phase contrast imaging. These findings were further supported with surface imaging and chemical analysis using scanning electron microscopy and energy dispersive X-ray spectroscopy. The combined quantitative structural and chemical analysis indicates that chromium segregates along grain boundaries, cracking is due to IG corrosion, and Cr-enrichment occurs on the cracked surfaces. Such quantitative 3D imaging of Cr23C6 nucleation at grain boundaries and Cr enriched oxides at cracked surfaces is a powerful tool to correlate IG corrosion mechanisms at nanoscale with buried grain boundary structure and alloy composition. Such understanding of IG corrosion mechanisms is critical for both the development of predictive multiscale corrosion models, and the engineering of corrosion resistant materials.},
doi = {10.1149/2.0401911jes},
journal = {Journal of the Electrochemical Society},
number = 11,
volume = 166,
place = {United States},
year = {2019},
month = {1}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1149/2.0401911jes
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Phase instabilities during high temperature exposure of 316 austenitic stainless steel
journal, April 1972

  • Weiss, B.; Stickler, R.
  • Metallurgical and Materials Transactions B, Vol. 3, Issue 4
  • DOI: 10.1007/BF02647659

MATERIALS SCIENCE: Tracking Corrosion Cracking
journal, July 2008

Observations of Intergranular Stress Corrosion Cracking in a Grain-Mapped Polycrystal
journal, July 2008

Correlative Tomography
journal, April 2014

  • Burnett, T. L.; McDonald, S. A.; Gholinia, A.
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep04711

Effective Multimodal Multiscale Analytical and Imaging Correlation
journal, January 2019

Correlative multiscale tomography of biological materials
journal, July 2016

Multiscale correlative tomography: an investigation of creep cavitation in 316 stainless steel
journal, August 2017

Degradation of metallic materials studied by correlative tomography
journal, July 2017

  • Burnett, T. L.; Holroyd, N. J. H.; Lewandowski, J. J.
  • IOP Conference Series: Materials Science and Engineering, Vol. 219
  • DOI: 10.1088/1757-899X/219/1/012001

A multi-scale correlative investigation of ductile fracture
journal, May 2017

Multimodal hard x-ray imaging with resolution approaching 10 nm for studies in material science
journal, March 2018

Design and performance of an X-ray scanning microscope at the Hard X-ray Nanoprobe beamline of NSLS-II
journal, October 2017

Artifact mitigation of ptychography integrated with on-the-fly scanning probe microscopy
journal, July 2017

  • Huang, Xiaojing; Yan, Hanfei; Ge, Mingyuan
  • Applied Physics Letters, Vol. 111, Issue 2
  • DOI: 10.1063/1.4993744

PyXRF: Python-based X-ray fluorescence analysis package
conference, September 2017

  • Yan, Hanfei; Xu, Wei; Yu, Dantong
  • X-Ray Nanoimaging: Instruments and Methods III
  • DOI: 10.1117/12.2272585

Multimodality hard-x-ray imaging of a chromosome with nanoscale spatial resolution
journal, February 2016

  • Yan, Hanfei; Nazaretski, Evgeny; Lauer, Kenneth
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep20112

High-Capacity Cathode Material with High Voltage for Li-Ion Batteries
journal, January 2018

Quantitative x-ray phase imaging at the nanoscale by multilayer Laue lenses
journal, February 2013

  • Yan, Hanfei; Chu, Yong S.; Maser, Jörg
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep01307

Using the in situ lift-out technique to prepare TEM specimens on a single-beam FIB instrument
journal, August 2008

An ESCA study of the Fe2+/Fe3+ ratio in passive films on iron-chromium alloys
journal, January 1976

The coupled kinetics of film growth and dissolution of stainless steel repassivating in acid solutions
journal, January 1984

A surface study of the oxidation of type 304L stainless steel at 600 K in air
journal, June 1988

  • Allen, G. C.; Dyke, J. M.; Harris, S. J.
  • Oxidation of Metals, Vol. 29, Issue 5-6
  • DOI: 10.1007/BF00666841

An XPS study of the passivity of a series of iron—chromium alloys in sulphuric acid
journal, January 1978

Passivity breakdown and pitting corrosion of binary alloys
journal, March 1991

  • Williams, D. E.; Newman, R. C.; Song, Q.
  • Nature, Vol. 350, Issue 6315
  • DOI: 10.1038/350216a0

A Percolation Model for Passivation in Stainless Steels
journal, January 1986

  • Sieradzki, K.
  • Journal of The Electrochemical Society, Vol. 133, Issue 9
  • DOI: 10.1149/1.2109065

In Situ Synchrotron X-Ray Microprobe Studies of Passivation Thresholds in Fe-Cr Alloys
journal, January 2001

  • Davenport, Alison J.; Ryan, Mary P.; Simmonds, Michael C.
  • Journal of The Electrochemical Society, Vol. 148, Issue 6
  • DOI: 10.1149/1.1368101
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: