High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3

Zheng, Hong; Zhang, Junjie; Wang, Bixia; Phelan, Daniel; Krogstad, Matthew J.; Ren, Yang; Phelan, W. Adam; Chmaissem, Omar; Poudel, Bisham; Mitchell, J. F.

doi:10.3390/cryst9070324

Title: High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3

Abstract

Single crystals of PrNiO₃ were grown under an oxygen pressure of 295 bar using a unique high-pressure optical-image floating zone furnace. The crystals, with volume in excess of 1 mm³, were characterized structurally using single crystal and powder X-ray diffraction. Resistivity, specific heat, and magnetic susceptibility were measured, all of which evidenced an abrupt, first order metal-insulator transition (MIT) at ~130 K, in agreement with previous literature reports on polycrystalline specimens. Temperature-dependent single crystal diffraction was performed to investigate changes through the MIT. Our study demonstrates the opportunity space for high fugacity, reactive environments for single crystal growth specifically of perovskite nickelates but more generally to correlated electron oxides.

Authors:

Zheng, Hong;

; Wang, Bixia; Phelan, Daniel; Krogstad, Matthew J.; Ren, Yang; Phelan, W. Adam; Chmaissem, Omar; Poudel, Bisham; Mitchell, J. F.

Publication Date:: 2019-06-26

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

OSTI Identifier:: 1529649

Alternate Identifier(s):: OSTI ID: 1530072

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

Resource Type:: Published Article

Journal Name:: Crystals

Additional Journal Information:: Journal Name: Crystals Journal Volume: 9 Journal Issue: 7; Journal ID: ISSN 2073-4352

Publisher:: MDPI AG

Country of Publication:: Germany

Language:: English

Subject:: 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; high pressure crystal growth; floating zone method; perovskite; nickelate; metal-insulator transition

Citation Formats


                    Zheng, Hong, Zhang, Junjie, Wang, Bixia, Phelan, Daniel, Krogstad, Matthew J., Ren, Yang, Phelan, W. Adam, Chmaissem, Omar, Poudel, Bisham, and Mitchell, J. F. High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3.  Germany: N. p., 2019. 
Web.  doi:10.3390/cryst9070324.

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                    Zheng, Hong, Zhang, Junjie, Wang, Bixia, Phelan, Daniel, Krogstad, Matthew J., Ren, Yang, Phelan, W. Adam, Chmaissem, Omar, Poudel, Bisham, & Mitchell, J. F. High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3.  Germany.  https://doi.org/10.3390/cryst9070324

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                    Zheng, Hong, Zhang, Junjie, Wang, Bixia, Phelan, Daniel, Krogstad, Matthew J., Ren, Yang, Phelan, W. Adam, Chmaissem, Omar, Poudel, Bisham, and Mitchell, J. F. Wed .  
"High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3".  Germany.  https://doi.org/10.3390/cryst9070324.

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@article{osti_1529649,

  title        = {High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3},

  author       = {Zheng, Hong and Zhang, Junjie and Wang, Bixia and Phelan, Daniel and Krogstad, Matthew J. and Ren, Yang and Phelan, W. Adam and Chmaissem, Omar and Poudel, Bisham and Mitchell, J. F.},

  abstractNote = {Single crystals of PrNiO3 were grown under an oxygen pressure of 295 bar using a unique high-pressure optical-image floating zone furnace. The crystals, with volume in excess of 1 mm3, were characterized structurally using single crystal and powder X-ray diffraction. Resistivity, specific heat, and magnetic susceptibility were measured, all of which evidenced an abrupt, first order metal-insulator transition (MIT) at ~130 K, in agreement with previous literature reports on polycrystalline specimens. Temperature-dependent single crystal diffraction was performed to investigate changes through the MIT. Our study demonstrates the opportunity space for high fugacity, reactive environments for single crystal growth specifically of perovskite nickelates but more generally to correlated electron oxides.},

  doi          = {10.3390/cryst9070324},

  journal      = {Crystals},

  number       = 7,

  volume       = 9,

  place        = {Germany},

  year         = {2019},

  month        = {6}

}

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Works referencing / citing this record:

Insulating Pockets in Metallic LaNiO ₃
journal, November 2015

Li, Bing; Louca, Despina; Yano, Shinichiro
Advanced Electronic Materials, Vol. 2, Issue 2
DOI: 10.1002/aelm.201500261

Sur une série de composés oxygènes du nickel trivalent derivés de la perovskite
journal, November 1971

Demazeau, Gérard; Marbeuf, Alain; Pouchard, Michel
Journal of Solid State Chemistry, Vol. 3, Issue 4
DOI: 10.1016/0022-4596(71)90105-8

Synthesis, crystal structure, and properties of metallic PrNiO3: Comparison with metallic NdNiO3 and semiconducting SmNiO3
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Lacorre, P.; Torrance, J. B.; Pannetier, J.
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Phelan, W. Adam; Zahn, Jessica; Kennedy, Zachary
Journal of Solid State Chemistry, Vol. 270
DOI: 10.1016/j.jssc.2018.12.013

Magnetic and orbital ordering in NdNiO3
journal, May 2006

Scagnoli, V.; Staub, U.; Mulders, A. M.
Physica B: Condensed Matter, Vol. 378-380
DOI: 10.1016/j.physb.2006.01.525

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journal, May 2003

Saito, T.
Physica B: Condensed Matter, Vol. 329-333
DOI: 10.1016/s0921-4526(02)02584-x

Charge disproportionation in RNiO3 perovskites
journal, March 2000

Fernández-Dı́az, M. T.; Alonso, J. A.; Martı́nez-Lope, M. J.
Physica B: Condensed Matter, Vol. 276-278
DOI: 10.1016/s0921-4526(99)01416-7

Single crystal growth of transition metal oxides at high pressures of several GPa
journal, October 2003

Azuma, M.; Saito, T.; Ishiwata, S.
Physica C: Superconductivity, Vol. 392-396
DOI: 10.1016/s0921-4534(03)00794-9

High-Pressure Floating-Zone Growth of Perovskite Nickelate LaNiO ₃ Single Crystals
journal, April 2017

Zhang, Junjie; Zheng, Hong; Ren, Yang
Crystal Growth & Design, Vol. 17, Issue 5
DOI: 10.1021/acs.cgd.7b00205

High-Pressure Preparation, Crystal Structure, Magnetic Properties, and Phase Transitions in GdNiO ₃ and DyNiO ₃ Perovskites
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Alonso, J. A.; Martínez-Lope, M. J.; Casais, M. T.
Chemistry of Materials, Vol. 11, Issue 9
DOI: 10.1021/cm991033k

Metal−Insulator Transitions, Structural and Microstructural Evolution of RNiO ₃ (R = Sm, Eu, Gd, Dy, Ho, Y) Perovskites: Evidence for Room-Temperature Charge Disproportionation in Monoclinic HoNiO ₃ and YNiO ₃
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Alonso, José A.; Martínez-Lope, María J.; Casais, María T.
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Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates
journal, October 2016

Bisogni, Valentina; Catalano, Sara; Green, Robert J.
Nature Communications, Vol. 7, Issue 1
DOI: 10.1038/ncomms13017

Atomic-scale control of competing electronic phases in ultrathin LaNiO3
journal, April 2014

King, P. D. C.; Wei, H. I.; Nie, Y. F.
Nature Nanotechnology, Vol. 9, Issue 6
DOI: 10.1038/nnano.2014.59

Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates
journal, March 2014

Jaramillo, R.; Ha, Sieu D.; Silevitch, D. M.
Nature Physics, Vol. 10, Issue 4
DOI: 10.1038/nphys2907

Large orbital polarization in a metallic square-planar nickelate
journal, June 2017

Zhang, Junjie; Botana, A. S.; Freeland, J. W.
Nature Physics, Vol. 13, Issue 9
DOI: 10.1038/nphys4149

Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3
journal, January 2018

Guo, H.; Li, Z. W.; Zhao, L.
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-017-02524-x

Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates
journal, January 2018

Shamblin, Jacob; Heres, Maximilian; Zhou, Haidong
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-017-02561-6

Gaps and pseudogaps in perovskite rare earth nickelates
journal, June 2015

Allen, S. James; Hauser, Adam J.; Mikheev, Evgeny
APL Materials, Vol. 3, Issue 6
DOI: 10.1063/1.4907771

Progress in perovskite nickelate research
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Catalan, G.
Phase Transitions, Vol. 81, Issue 7-8
DOI: 10.1080/01411590801992463

Possible ground states of rare-earth nickelates (RNiO ₃ , R = La, Nd, Pr): a mean-field study
journal, August 2013

Misra, Debolina
Phase Transitions, Vol. 87, Issue 4
DOI: 10.1080/01411594.2013.853767

Crystal growth of NdNiO ₃ perovskite under high oxygen pressure
journal, March 2004

Alonso, J. A.; Muñoz, A.; Largeteau, A.
Journal of Physics: Condensed Matter, Vol. 16, Issue 14
DOI: 10.1088/0953-8984/16/14/040

Magnetic and electronic properties of RNiO ₃ (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction
journal, January 2011

Bodenthin, Y.; Staub, U.; Piamonteze, C.
Journal of Physics: Condensed Matter, Vol. 23, Issue 3
DOI: 10.1088/0953-8984/23/3/036002

Structural, magnetic and electronic properties of perovskites (R = rare earth)
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Medarde, María Luisa
Journal of Physics: Condensed Matter, Vol. 9, Issue 8
DOI: 10.1088/0953-8984/9/8/003

Rare-earth nickelates R NiO ₃ : thin films and heterostructures
journal, February 2018

Catalano, S.; Gibert, M.; Fowlie, J.
Reports on Progress in Physics, Vol. 81, Issue 4
DOI: 10.1088/1361-6633/aaa37a

Crystalline electric field of the rare-earth nickelates $R {NiO}_{3} (R = \Pr,$ Nd, Sm, Eu, and $\Pr_{1 - x} {La}_{x},$ $0 <~ x <~ 0.7)$ determined by inelastic neutron scattering
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Rosenkranz, S.; Medarde, M.; Fauth, F.
Physical Review B, Vol. 60, Issue 21
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Short-range charge order in $R Ni O_{3}$ perovskites ( $R = \Pr$ , Nd, Eu, Y) probed by x-ray-absorption spectroscopy
journal, January 2005

Piamonteze, Cínthia; Tolentino, Hélio C. N.; Ramos, Aline Y.
Physical Review B, Vol. 71, Issue 1
DOI: 10.1103/physrevb.71.012104

Charge disproportionation and search for orbital ordering in $Nd Ni O_{3}$ by use of resonant x-ray diffraction
journal, October 2005

Scagnoli, V.; Staub, U.; Janousch, M.
Physical Review B, Vol. 72, Issue 15
DOI: 10.1103/physrevb.72.155111

Long-range charge order in the low-temperature insulating phase of ${PrNiO}_{3}$
journal, December 2008

Medarde, M.; Fernández-Díaz, M. T.; Lacorre, Ph.
Physical Review B, Vol. 78, Issue 21
DOI: 10.1103/physrevb.78.212101

Structure and charge order in the antiferromagnetic band-insulating phase of ${NdNiO}_{3}$
journal, April 2009

García-Muñoz, J. L.; Aranda, M. A. G.; Alonso, J. A.
Physical Review B, Vol. 79, Issue 13
DOI: 10.1103/physrevb.79.134432

Charge disproportionation in $R {NiO}_{3}$ perovskites ( $R = rare$ earth) from high-resolution x-ray absorption spectroscopy
journal, December 2009

Medarde, M.; Dallera, C.; Grioni, M.
Physical Review B, Vol. 80, Issue 24
DOI: 10.1103/physrevb.80.245105

Charge disproportionation in $R$ NiO $_{3}$ ( $R =$ Tm, Yb) perovskites observed in situ by neutron diffraction and $^{57}$ Fe probe Mössbauer spectroscopy
journal, May 2013

Alonso, J. A.; Martínez-Lope, M. J.; Presniakov, I. A.
Physical Review B, Vol. 87, Issue 18
DOI: 10.1103/physrevb.87.184111

Spin-canted magnetism and decoupling of charge and spin ordering in NdNiO $_{3}$
journal, July 2013

Kumar, Devendra; Rajeev, K. P.; Alonso, J. A.
Physical Review B, Vol. 88, Issue 1
DOI: 10.1103/physrevb.88.014410

Photoinduced melting of magnetic order in the correlated electron insulator NdNiO $_{3}$
journal, December 2013

Caviglia, A. D.; Först, M.; Scherwitzl, R.
Physical Review B, Vol. 88, Issue 22
DOI: 10.1103/physrevb.88.220401

Mass enhancement versus Stoner enhancement in strongly correlated metallic perovskites: ${LaNiO}_{3}$ and ${LaCuO}_{3}$
journal, June 2014

Zhou, J. -S.; Marshall, L. G.; Goodenough, J. B.
Physical Review B, Vol. 89, Issue 24
DOI: 10.1103/physrevb.89.245138

Counter-thermal flow of holes in high-mobility ${LaNiO}_{3}$ thin films
journal, January 2019

Liu, Changjiang; Wrobel, Friederike; Hoffman, Jason D.
Physical Review B, Vol. 99, Issue 4
DOI: 10.1103/physrevb.99.041114

Multiferroicity in Rare-Earth Nickelates $R {NiO}_{3}$
journal, October 2009

Giovannetti, Gianluca; Kumar, Sanjeev; Khomskii, Daniel
Physical Review Letters, Vol. 103, Issue 15
DOI: 10.1103/physrevlett.103.156401

Landau Theory of Charge and Spin Ordering in the Nickelates
journal, January 2011

Lee, SungBin; Chen, Ru; Balents, Leon
Physical Review Letters, Vol. 106, Issue 1
DOI: 10.1103/physrevlett.106.016405

Theory of the Magnetic and Metal-Insulator Transitions in $R {NiO}_{3}$ Bulk and Layered Structures
journal, March 2013

Lau, Bayo; Millis, Andrew J.
Physical Review Letters, Vol. 110, Issue 12
DOI: 10.1103/physrevlett.110.126404

Enhanced Susceptibility in $L {NiO}_{3}$ Perovskites ( $L {= L a, P r, N d, N d}_{0.5} {Sm}_{0.5}$ )
journal, January 2000

Zhou, J. -S.; Goodenough, J. B.; Dabrowski, B.
Physical Review Letters, Vol. 84, Issue 3
DOI: 10.1103/physrevlett.84.526

Pressure-Induced Non-Fermi-Liquid Behavior of ${PrNiO}_{3}$
journal, June 2005

Zhou, J. -S.; Goodenough, J. B.; Dabrowski, B.
Physical Review Letters, Vol. 94, Issue 22
DOI: 10.1103/physrevlett.94.226602

Antiferromagnetic defect structure in $LaNi O_{3 - δ}$ single crystals
journal, June 2018

Wang, Bi-Xia; Rosenkranz, S.; Rui, X.
Physical Review Materials, Vol. 2, Issue 6
DOI: 10.1103/physrevmaterials.2.064404

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013

Toby, Brian H.; Von Dreele, Robert B.
Journal of Applied Crystallography, Vol. 46, Issue 2
DOI: 10.1107/s0021889813003531

Oxygen Deficiency and Electrical Conductivity in LnNiO3-z (Ln=La, Pr) and LaCuO3-z. [ＬｎＮｉＯ３−ｚ（Ｌｎ＝Ｌａ，Ｐｒ）及びＬａＣｕＯ３−ｚの酸素欠損と電気伝導]
journal, January 1992

Takeda, Yasuo; Hashimoto, Hiroshi; Sato, Atsushi
Journal of the Japan Society of Powder and Powder Metallurgy, Vol. 39, Issue 5
DOI: 10.2497/jjspm.39.345

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Title: High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3

Abstract

Citation Formats

Antiferromagnetic defect structure in LaNi O 3 − δ single crystals journal, June 2018

Landau Theory of Charge and Spin Ordering in the Nickelates journal, January 2011

Magnetic and electronic properties of RNiO 3 (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction journal, January 2011

Pushing boundaries: High pressure, supercritical optical floating zone materials discovery journal, February 2019

Multiferroicity in Rare-Earth Nickelates R NiO 3 journal, October 2009

Synthesis, crystal structure, and properties of metallic PrNiO3: Comparison with metallic NdNiO3 and semiconducting SmNiO3 journal, April 1991

Charge disproportionation and search for orbital ordering in Nd Ni O 3 by use of resonant x-ray diffraction journal, October 2005

Structural, magnetic and electronic properties of perovskites (R = rare earth) journal, February 1997

Gaps and pseudogaps in perovskite rare earth nickelates journal, June 2015

Charge disproportionation in RNiO3 perovskites journal, March 2000

Rare-earth nickelates R NiO 3 : thin films and heterostructures journal, February 2018

Structure and charge order in the antiferromagnetic band-insulating phase of NdNiO 3 journal, April 2009

Long-range charge order in the low-temperature insulating phase of PrNiO 3 journal, December 2008

Insulating Pockets in Metallic LaNiO 3 journal, November 2015

Pressure-Induced Non-Fermi-Liquid Behavior of PrNiO 3 journal, June 2005

Large orbital polarization in a metallic square-planar nickelate journal, June 2017

Progress in perovskite nickelate research journal, July 2008

Mass enhancement versus Stoner enhancement in strongly correlated metallic perovskites: LaNiO 3 and LaCuO 3 journal, June 2014

GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal, March 2013

Magnetic and orbital ordering in NdNiO3 journal, May 2006

Charge disproportionation in R NiO 3 ( R = Tm, Yb) perovskites observed in situ by neutron diffraction and 57 Fe probe Mössbauer spectroscopy journal, May 2013

High-Pressure Preparation, Crystal Structure, Magnetic Properties, and Phase Transitions in GdNiO 3 and DyNiO 3 Perovskites journal, September 1999

Metal−Insulator Transitions, Structural and Microstructural Evolution of RNiO 3 (R = Sm, Eu, Gd, Dy, Ho, Y) Perovskites: Evidence for Room-Temperature Charge Disproportionation in Monoclinic HoNiO 3 and YNiO 3 journal, May 1999

Monoclinic distortion in the insulating phase of PrNiO3 journal, May 2003

Enhanced Susceptibility in L NiO 3 Perovskites ( L = L a , P r , N d , N d 0.5 Sm 0.5 ) journal, January 2000

Possible ground states of rare-earth nickelates (RNiO 3 , R = La, Nd, Pr): a mean-field study journal, August 2013

Spin-canted magnetism and decoupling of charge and spin ordering in NdNiO 3 journal, July 2013

Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates journal, January 2018

Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates journal, March 2014

Sur une série de composés oxygènes du nickel trivalent derivés de la perovskite journal, November 1971

Crystal growth of NdNiO 3 perovskite under high oxygen pressure journal, March 2004

Crystalline electric field of the rare-earth nickelates R NiO 3 ( R = Pr , Nd, Sm, Eu, and Pr 1 − x La x , 0 <~ x <~ 0 . 7 ) determined by inelastic neutron scattering journal, December 1999

Atomic-scale control of competing electronic phases in ultrathin LaNiO3 journal, April 2014

Short-range charge order in R Ni O 3 perovskites ( R = Pr , Nd, Eu, Y) probed by x-ray-absorption spectroscopy journal, January 2005

Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates journal, October 2016

Oxygen Deficiency and Electrical Conductivity in LnNiO3-z (Ln=La, Pr) and LaCuO3-z. [ＬｎＮｉＯ３−ｚ（Ｌｎ＝Ｌａ，Ｐｒ）及びＬａＣｕＯ３−ｚの酸素欠損と電気伝導] journal, January 1992

Theory of the Magnetic and Metal-Insulator Transitions in R NiO 3 Bulk and Layered Structures journal, March 2013

Charge disproportionation in R NiO 3 perovskites ( R = rare earth) from high-resolution x-ray absorption spectroscopy journal, December 2009

Counter-thermal flow of holes in high-mobility LaNiO 3 thin films journal, January 2019

Photoinduced melting of magnetic order in the correlated electron insulator NdNiO 3 journal, December 2013

Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3 journal, January 2018

High-Pressure Floating-Zone Growth of Perovskite Nickelate LaNiO 3 Single Crystals journal, April 2017

Single crystal growth of transition metal oxides at high pressures of several GPa journal, October 2003

Insulating Pockets in Metallic LaNiO 3 journal, November 2015

Sur une série de composés oxygènes du nickel trivalent derivés de la perovskite journal, November 1971

Synthesis, crystal structure, and properties of metallic PrNiO3: Comparison with metallic NdNiO3 and semiconducting SmNiO3 journal, April 1991

Pushing boundaries: High pressure, supercritical optical floating zone materials discovery journal, February 2019

Magnetic and orbital ordering in NdNiO3 journal, May 2006

Monoclinic distortion in the insulating phase of PrNiO3 journal, May 2003

Charge disproportionation in RNiO3 perovskites journal, March 2000

Single crystal growth of transition metal oxides at high pressures of several GPa journal, October 2003

High-Pressure Floating-Zone Growth of Perovskite Nickelate LaNiO 3 Single Crystals journal, April 2017

High-Pressure Preparation, Crystal Structure, Magnetic Properties, and Phase Transitions in GdNiO 3 and DyNiO 3 Perovskites journal, September 1999

Metal−Insulator Transitions, Structural and Microstructural Evolution of RNiO 3 (R = Sm, Eu, Gd, Dy, Ho, Y) Perovskites: Evidence for Room-Temperature Charge Disproportionation in Monoclinic HoNiO 3 and YNiO 3 journal, May 1999

Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates journal, October 2016

Atomic-scale control of competing electronic phases in ultrathin LaNiO3 journal, April 2014

Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates journal, March 2014

Large orbital polarization in a metallic square-planar nickelate journal, June 2017

Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3 journal, January 2018

Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates journal, January 2018

Gaps and pseudogaps in perovskite rare earth nickelates journal, June 2015

Progress in perovskite nickelate research journal, July 2008

Possible ground states of rare-earth nickelates (RNiO 3 , R = La, Nd, Pr): a mean-field study journal, August 2013

Crystal growth of NdNiO 3 perovskite under high oxygen pressure journal, March 2004

Magnetic and electronic properties of RNiO 3 (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction journal, January 2011

Structural, magnetic and electronic properties of perovskites (R = rare earth) journal, February 1997

Rare-earth nickelates R NiO 3 : thin films and heterostructures journal, February 2018

Crystalline electric field of the rare-earth nickelates R NiO 3 ( R = Pr , Nd, Sm, Eu, and Pr 1 − x La x , 0 <~ x <~ 0 . 7 ) determined by inelastic neutron scattering journal, December 1999

Short-range charge order in R Ni O 3 perovskites ( R = Pr , Nd, Eu, Y) probed by x-ray-absorption spectroscopy journal, January 2005

Charge disproportionation and search for orbital ordering in Nd Ni O 3 by use of resonant x-ray diffraction journal, October 2005

Long-range charge order in the low-temperature insulating phase of PrNiO 3 journal, December 2008

Structure and charge order in the antiferromagnetic band-insulating phase of NdNiO 3 journal, April 2009

Charge disproportionation in R NiO 3 perovskites ( R = rare earth) from high-resolution x-ray absorption spectroscopy journal, December 2009

Charge disproportionation in R NiO 3 ( R = Tm, Yb) perovskites observed in situ by neutron diffraction and 57 Fe probe Mössbauer spectroscopy journal, May 2013

Spin-canted magnetism and decoupling of charge and spin ordering in NdNiO 3 journal, July 2013

Photoinduced melting of magnetic order in the correlated electron insulator NdNiO 3 journal, December 2013

Mass enhancement versus Stoner enhancement in strongly correlated metallic perovskites: LaNiO 3 and LaCuO 3 journal, June 2014

Antiferromagnetic defect structure in $LaNi O_{3 - δ}$ single crystals
journal, June 2018

Landau Theory of Charge and Spin Ordering in the Nickelates
journal, January 2011

Magnetic and electronic properties of RNiO ₃ (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction
journal, January 2011

Pushing boundaries: High pressure, supercritical optical floating zone materials discovery
journal, February 2019

Multiferroicity in Rare-Earth Nickelates $R {NiO}_{3}$
journal, October 2009

Synthesis, crystal structure, and properties of metallic PrNiO3: Comparison with metallic NdNiO3 and semiconducting SmNiO3
journal, April 1991

Charge disproportionation and search for orbital ordering in $Nd Ni O_{3}$ by use of resonant x-ray diffraction
journal, October 2005

Structural, magnetic and electronic properties of perovskites (R = rare earth)
journal, February 1997

Gaps and pseudogaps in perovskite rare earth nickelates
journal, June 2015

Charge disproportionation in RNiO3 perovskites
journal, March 2000

Rare-earth nickelates R NiO ₃ : thin films and heterostructures
journal, February 2018

Structure and charge order in the antiferromagnetic band-insulating phase of ${NdNiO}_{3}$
journal, April 2009

Long-range charge order in the low-temperature insulating phase of ${PrNiO}_{3}$
journal, December 2008

Insulating Pockets in Metallic LaNiO ₃
journal, November 2015

Pressure-Induced Non-Fermi-Liquid Behavior of ${PrNiO}_{3}$
journal, June 2005

Large orbital polarization in a metallic square-planar nickelate
journal, June 2017

Progress in perovskite nickelate research
journal, July 2008

Mass enhancement versus Stoner enhancement in strongly correlated metallic perovskites: ${LaNiO}_{3}$ and ${LaCuO}_{3}$
journal, June 2014

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013

Magnetic and orbital ordering in NdNiO3
journal, May 2006

Charge disproportionation in $R$ NiO $_{3}$ ( $R =$ Tm, Yb) perovskites observed in situ by neutron diffraction and $^{57}$ Fe probe Mössbauer spectroscopy
journal, May 2013

High-Pressure Preparation, Crystal Structure, Magnetic Properties, and Phase Transitions in GdNiO ₃ and DyNiO ₃ Perovskites
journal, September 1999

Metal−Insulator Transitions, Structural and Microstructural Evolution of RNiO ₃ (R = Sm, Eu, Gd, Dy, Ho, Y) Perovskites: Evidence for Room-Temperature Charge Disproportionation in Monoclinic HoNiO ₃ and YNiO ₃
journal, May 1999

Monoclinic distortion in the insulating phase of PrNiO3
journal, May 2003

Enhanced Susceptibility in $L {NiO}_{3}$ Perovskites ( $L {= L a, P r, N d, N d}_{0.5} {Sm}_{0.5}$ )
journal, January 2000

Possible ground states of rare-earth nickelates (RNiO ₃ , R = La, Nd, Pr): a mean-field study
journal, August 2013

Spin-canted magnetism and decoupling of charge and spin ordering in NdNiO $_{3}$
journal, July 2013

Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates
journal, January 2018

Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates
journal, March 2014

Sur une série de composés oxygènes du nickel trivalent derivés de la perovskite
journal, November 1971

Crystal growth of NdNiO ₃ perovskite under high oxygen pressure
journal, March 2004

Crystalline electric field of the rare-earth nickelates $R {NiO}_{3} (R = \Pr,$ Nd, Sm, Eu, and $\Pr_{1 - x} {La}_{x},$ $0 <~ x <~ 0.7)$ determined by inelastic neutron scattering
journal, December 1999

Atomic-scale control of competing electronic phases in ultrathin LaNiO3
journal, April 2014

Short-range charge order in $R Ni O_{3}$ perovskites ( $R = \Pr$ , Nd, Eu, Y) probed by x-ray-absorption spectroscopy
journal, January 2005

Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates
journal, October 2016

Oxygen Deficiency and Electrical Conductivity in LnNiO3-z (Ln=La, Pr) and LaCuO3-z. [ＬｎＮｉＯ３−ｚ（Ｌｎ＝Ｌａ，Ｐｒ）及びＬａＣｕＯ３−ｚの酸素欠損と電気伝導]
journal, January 1992

Theory of the Magnetic and Metal-Insulator Transitions in $R {NiO}_{3}$ Bulk and Layered Structures
journal, March 2013

Charge disproportionation in $R {NiO}_{3}$ perovskites ( $R = rare$ earth) from high-resolution x-ray absorption spectroscopy
journal, December 2009

Counter-thermal flow of holes in high-mobility ${LaNiO}_{3}$ thin films
journal, January 2019

Photoinduced melting of magnetic order in the correlated electron insulator NdNiO $_{3}$
journal, December 2013

Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3
journal, January 2018

High-Pressure Floating-Zone Growth of Perovskite Nickelate LaNiO ₃ Single Crystals
journal, April 2017

Single crystal growth of transition metal oxides at high pressures of several GPa
journal, October 2003

Insulating Pockets in Metallic LaNiO ₃
journal, November 2015

Sur une série de composés oxygènes du nickel trivalent derivés de la perovskite
journal, November 1971

Synthesis, crystal structure, and properties of metallic PrNiO3: Comparison with metallic NdNiO3 and semiconducting SmNiO3
journal, April 1991

Pushing boundaries: High pressure, supercritical optical floating zone materials discovery
journal, February 2019

Magnetic and orbital ordering in NdNiO3
journal, May 2006

Monoclinic distortion in the insulating phase of PrNiO3
journal, May 2003

Charge disproportionation in RNiO3 perovskites
journal, March 2000

Single crystal growth of transition metal oxides at high pressures of several GPa
journal, October 2003

High-Pressure Floating-Zone Growth of Perovskite Nickelate LaNiO ₃ Single Crystals
journal, April 2017

High-Pressure Preparation, Crystal Structure, Magnetic Properties, and Phase Transitions in GdNiO ₃ and DyNiO ₃ Perovskites
journal, September 1999

Metal−Insulator Transitions, Structural and Microstructural Evolution of RNiO ₃ (R = Sm, Eu, Gd, Dy, Ho, Y) Perovskites: Evidence for Room-Temperature Charge Disproportionation in Monoclinic HoNiO ₃ and YNiO ₃
journal, May 1999

Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates
journal, October 2016

Atomic-scale control of competing electronic phases in ultrathin LaNiO3
journal, April 2014

Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates
journal, March 2014

Large orbital polarization in a metallic square-planar nickelate
journal, June 2017

Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3
journal, January 2018

Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates
journal, January 2018

Gaps and pseudogaps in perovskite rare earth nickelates
journal, June 2015

Progress in perovskite nickelate research
journal, July 2008

Possible ground states of rare-earth nickelates (RNiO ₃ , R = La, Nd, Pr): a mean-field study
journal, August 2013

Crystal growth of NdNiO ₃ perovskite under high oxygen pressure
journal, March 2004

Magnetic and electronic properties of RNiO ₃ (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction
journal, January 2011

Structural, magnetic and electronic properties of perovskites (R = rare earth)
journal, February 1997

Rare-earth nickelates R NiO ₃ : thin films and heterostructures
journal, February 2018

Crystalline electric field of the rare-earth nickelates $R {NiO}_{3} (R = \Pr,$ Nd, Sm, Eu, and $\Pr_{1 - x} {La}_{x},$ $0 <~ x <~ 0.7)$ determined by inelastic neutron scattering
journal, December 1999

Short-range charge order in $R Ni O_{3}$ perovskites ( $R = \Pr$ , Nd, Eu, Y) probed by x-ray-absorption spectroscopy
journal, January 2005

Charge disproportionation and search for orbital ordering in $Nd Ni O_{3}$ by use of resonant x-ray diffraction
journal, October 2005

Long-range charge order in the low-temperature insulating phase of ${PrNiO}_{3}$
journal, December 2008

Structure and charge order in the antiferromagnetic band-insulating phase of ${NdNiO}_{3}$
journal, April 2009

Charge disproportionation in $R {NiO}_{3}$ perovskites ( $R = rare$ earth) from high-resolution x-ray absorption spectroscopy
journal, December 2009

Charge disproportionation in $R$ NiO $_{3}$ ( $R =$ Tm, Yb) perovskites observed in situ by neutron diffraction and $^{57}$ Fe probe Mössbauer spectroscopy
journal, May 2013

Spin-canted magnetism and decoupling of charge and spin ordering in NdNiO $_{3}$
journal, July 2013

Photoinduced melting of magnetic order in the correlated electron insulator NdNiO $_{3}$
journal, December 2013

Mass enhancement versus Stoner enhancement in strongly correlated metallic perovskites: ${LaNiO}_{3}$ and ${LaCuO}_{3}$
journal, June 2014

Counter-thermal flow of holes in high-mobility ${LaNiO}_{3}$ thin films
journal, January 2019

Multiferroicity in Rare-Earth Nickelates $R {NiO}_{3}$
journal, October 2009

Landau Theory of Charge and Spin Ordering in the Nickelates
journal, January 2011