Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium

Zeeshan, Faisal; Hoszowska, Joanna; Dousse, Jean-Claude; Sokaras, Dimosthenis; Weng, Tsu-Chien; Alonso-Mori, Roberto; Kavčič, Matjaz; Guerra, Mauro; Sampaio, Jorge Miguel; Parente, Fernando; Indelicato, Paul; Marques, José Pires; Santos, José Paulo

doi:10.1002/xrs.3019

Title: Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium

Journal Article · 13 February 2019 · X-Ray Spectrometry, XRS

DOI: https://doi.org/10.1002/xrs.3019 · OSTI ID:1529495

Zeeshan, Faisal ^[1];

^[1]; Dousse, Jean-Claude ^[1]; Sokaras, Dimosthenis ^[2]; Weng, Tsu-Chien ^[2]; Alonso-Mori, Roberto ^[2]; Kavčič, Matjaz ^[3]; Guerra, Mauro ^[4]; Sampaio, Jorge Miguel ^[5]; Parente, Fernando ^[6]; Indelicato, Paul ^[7];

^[8]; Santos, José Paulo ^[4]

Univ. of Fribourg (Switzerland)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Jozef Stefan Inst. (IJS), Ljubljana (Slovenia)
New Univ. of Lisbon (NOVA), Caparica (Portugal)
LIP-Laboratório de Instrumentação e Física Experimental de Partículas, Lisboa (Portugal)
New University of Lisbon (NOVA), Caparica (Portugal); Sorbonne Universités, Paris (France)
Sorbonne Universités, Paris (France)
Univ. of Lisbon (Portugal)

Here, we identify measurements of the Kβ diagram, valence-to-core (VtC), and hypersatellite X-ray spectra induced in metallic Cr by photon single and double K-shell ionization. The experiment was carried out at the Stanford Synchrotron Radiation Lightsource using the seven-crystal Johann-type hard X-ray spectrometer of the beamline 6-2. For the Kβ diagram and VtC transitions, the present study confirms the line shape features observed in previous works, whereas the K^hβ hypersatellite transition was found to exhibit a complex spectral line shape and a characteristic low-energy shoulder. The energy shift of the hypersatellite relative to the parent diagram line was deduced from the measurements and compared with the result of extensive multiconfiguration Dirac–Fock (MCDF) calculations. A signifcant agreement between experiment and theory was found. The MCDF calculations were also used to compute the theoretical line shape of the hypersatellite. A satisfactory agreement was obtained between the overall shapes of the experimental and theoretical spectra, but deviations were observed on the low- and high-energy flanks of the hypersatellite line. The discrepancies were explained by chemical effects, which were not considered in the MCDF calculations performed for isolated atoms.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: Swiss National Science Foundation; USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1529495

Journal Information:: X-Ray Spectrometry, XRS, Journal Name: X-Ray Spectrometry, XRS Journal Issue: 5 Vol. 48; ISSN 0049-8246

Country of Publication:: United States

Language:: English

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Title: Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium

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