Thermochemistry of Surfactant‐Templating of USY Zeolite

Linares, Noemi; De Oliveira Jardim, Erika; Sharma, Geetu; Serrano, Elena; Navrotsky, Alexandra; García‐Martínez, Javier

doi:10.1002/chem.201901507

Title: Thermochemistry of Surfactant‐Templating of USY Zeolite

Journal Article · 24 June 2019 · Chemistry - A European Journal

DOI: https://doi.org/10.1002/chem.201901507 · OSTI ID:1529425

^[1];

^[2];

^[1];

^[2];

^[1]

Laboratorio de Nanotecnología Molecular Departamento de Química Inorgánica Universidad de Alicante Ctra. San Vicente-Alicante s/n E-03690 Alicante Spain
Peter A. Rock Thermochemistry Laboratory and NEAT ORU Department University of California Davis Institution Davis CA 95616 USA

Abstract With the aim of understanding the thermochemistry of the introduction of mesoporosity in zeolites by using surfactants, high temperature oxide melt solution calorimetry was used to determine the change in the enthalpy of formation of USY zeolite before and after the introduction of mesoporosity. Our results confirm that this process only slightly destabilizes the zeolite by the additional surface area. However, this can be overcome by the stabilizing effect of the interactions between the surfactant and the zeolite framework.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0016573

OSTI ID:: 1529425

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 43 Vol. 25; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (22)

Quantifying the Complex Pore Architecture of Hierarchical Faujasite Zeolites and the Impact on Diffusion Kenvin, Jeffrey; Mitchell, Sharon; Sterling, Michael Advanced Functional Materials, Vol. 26, Issue 31 https://doi.org/10.1002/adfm.201601748	journal	May 2016
The Energetics of Surfactant-Templating of Zeolites Linares, Noemi; Jardim, Erika O.; Sachse, Alexander Angewandte Chemie, Vol. 130, Issue 28 https://doi.org/10.1002/ange.201803759	journal	June 2018
The Energetics of Surfactant-Templating of Zeolites Linares, Noemi; Jardim, Erika O.; Sachse, Alexander Angewandte Chemie International Edition, Vol. 57, Issue 28 https://doi.org/10.1002/anie.201803759	journal	June 2018
Realizing the Commercial Potential of Hierarchical Zeolites: New Opportunities in Catalytic Cracking Li, Kunhao; Valla, Julia; Garcia-Martinez, Javier ChemCatChem, Vol. 6, Issue 1 https://doi.org/10.1002/cctc.201300345	journal	September 2013
Evidence of Intracrystalline Mesostructured Porosity in Zeolites by Advanced Gas Sorption, Electron Tomography and Rotation Electron Diffraction Garcia-Martinez, Javier; Xiao, Changhong; Cychosz, Katie A. ChemCatChem, Vol. 6, Issue 11 https://doi.org/10.1002/cctc.201402499	journal	August 2014
Progress and new directions in high temperature calorimetry Navrotsky, Alexandra Physics and Chemistry of Minerals, Vol. 2, Issue 1-2 https://doi.org/10.1007/BF00307526	journal	January 1977
Progress and new directions in high temperature calorimetry revisited Navrotsky, Alexandra Physics and Chemistry of Minerals, Vol. 24, Issue 3 https://doi.org/10.1007/s002690050035	journal	April 1997
High-silica zeolites: a relationship between energetics and internal surface areas Moloy, Eric C.; Davila, Lilian P.; Shackelford, James F. Microporous and Mesoporous Materials, Vol. 54, Issue 1-2 https://doi.org/10.1016/S1387-1811(02)00328-1	journal	July 2002
Mesoporous silica synthesis: Energetics of interaction between framework and structure directing agent Trofymluk, Olga; Levchenko, Andrey A.; Navrotsky, Alexandra Microporous and Mesoporous Materials, Vol. 149, Issue 1 https://doi.org/10.1016/j.micromeso.2011.08.022	journal	February 2012
Development of Intracrystalline Mesoporosity in Zeolites through Surfactant-Templating Sachse, Alexander; Grau-Atienza, Aida; Jardim, Erika O. Crystal Growth & Design, Vol. 17, Issue 8 https://doi.org/10.1021/acs.cgd.7b00619	journal	June 2017
In Situ Time-Resolved Observation of the Development of Intracrystalline Mesoporosity in USY Zeolite Linares, Noemi; Sachse, Alexander; Serrano, Elena Chemistry of Materials, Vol. 28, Issue 24 https://doi.org/10.1021/acs.chemmater.6b03688	journal	December 2016
Accelerated Construction of High-Silica RHO and CHA Zeolites via Interzeolite Transformation and Their NH ₃ –SCR Performances after Copper Exchange Ke, Quanli; Sun, Tianjun; Cheng, Hao Industrial & Engineering Chemistry Research, Vol. 57, Issue 49 https://doi.org/10.1021/acs.iecr.8b03907	journal	November 2018
Energetics of Mesoporous Silica: Investigation into Pore Size and Symmetry Trofymluk, Olga; Levchenko, Andrey A.; Tolbert, Sarah H. Chemistry of Materials, Vol. 17, Issue 14 https://doi.org/10.1021/cm050366g	journal	July 2005
Thermochemistry of Microporous and Mesoporous Materials Navrotsky, Alexandra; Trofymluk, Olga; Levchenko, Andrey A. Chemical Reviews, Vol. 109, Issue 9 https://doi.org/10.1021/cr800495t	journal	September 2009
Synthesis and Crystal Structure of a Layered Silicate HUS-1 with a Halved Sodalite-Cage Topology Ikeda, Takuji; Oumi, Yasunori; Honda, Koutaro Inorganic Chemistry, Vol. 50, Issue 6 https://doi.org/10.1021/ic1020065	journal	March 2011
High yield synthesis of high-silica chabazite by combining the role of zeolite precursors and tetraethylammonium: SCR of NOx Martín, Nuria; Moliner, Manuel; Corma, Avelino Chemical Communications, Vol. 51, Issue 49 https://doi.org/10.1039/C5CC02670A	journal	January 2015
Thermally stable nanosized LEV zeolites synthesized by hydrothermal conversion of FAU zeolites in the presence of N,N-dimethylpiperidinium cations Funase, Natsumi; Tanigawa, Takuya; Yamasaki, Yoshitaka Journal of Materials Chemistry A, Vol. 5, Issue 36 https://doi.org/10.1039/C7TA04988A	journal	January 2017
Transformation synthesis of aluminosilicate SSZ-39 zeolite from ZSM-5 and beta zeolite Xu, Hao; Chen, Wei; Wu, Qinming Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/C9TA00174C	journal	January 2019
A mesostructured Y zeolite as a superior FCC catalyst – from lab to refinery García-Martínez, Javier; Li, Kunhao; Krishnaiah, Gautham Chemical Communications, Vol. 48, Issue 97 https://doi.org/10.1039/c2cc35659g	journal	January 2012
Mesostructured zeolite Y—high hydrothermal stability and superior FCC catalytic performance García-Martínez, Javier; Johnson, Marvin; Valla, Julia Catalysis Science & Technology, Vol. 2, Issue 5 https://doi.org/10.1039/c2cy00309k	journal	January 2012
One-pot structural conversion of magadiite into MFI zeolite nanosheets using mononitrogen surfactants as structure and shape-directing agents Dhainaut, Jérémy; Daou, T. Jean; Bidal, Yannick CrystEngComm, Vol. 15, Issue 15 https://doi.org/10.1039/c3ce40118a	journal	January 2013
Thermochemistry and phase equilibria in calcium zeolites Kiseleva, Irina; Navrotsky, Alexandra; Belitsky, Igor A. American Mineralogist, Vol. 81, Issue 5-6 https://doi.org/10.2138/am-1996-5-613	journal	June 1996

Similar Records

Thermochemistry of Surfactant-Templating of USY Zeolite

Journal Article · 2019 · Chemistry - A European Journal · OSTI ID:1612651

Linares, Noemi; De Oliveira Jardim, Erika; Sharma, Geetu; +3 more

Thermochemical Insights into Stability and Hydration of Ion-Exchanged Zeolite ZK-5 (KFI Framework)

Journal Article · 2020 · Journal of Physical Chemistry. C · OSTI ID:1720174

Yang, Shuhao; Guo, Xin; Verma, Ankit; +3 more

Influence of superacid sites in USY zeolites on gasoil cracking

Conference · 1990 · American Chemical Society, Division of Petroleum Chemistry, Preprints; (United States) · OSTI ID:7195458

Corma, A; Fornes, V; Mocholi, F A; +2 more

Title: Thermochemistry of Surfactant‐Templating of USY Zeolite

Citation Formats

References (22)

Similar Records

Related Subjects