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Title: Thermochemistry of Surfactant‐Templating of USY Zeolite

Abstract

Abstract With the aim of understanding the thermochemistry of the introduction of mesoporosity in zeolites by using surfactants, high temperature oxide melt solution calorimetry was used to determine the change in the enthalpy of formation of USY zeolite before and after the introduction of mesoporosity. Our results confirm that this process only slightly destabilizes the zeolite by the additional surface area. However, this can be overcome by the stabilizing effect of the interactions between the surfactant and the zeolite framework.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Laboratorio de Nanotecnología Molecular Departamento de Química Inorgánica Universidad de Alicante Ctra. San Vicente-Alicante s/n E-03690 Alicante Spain
  2. Peter A. Rock Thermochemistry Laboratory and NEAT ORU Department University of California Davis Institution Davis CA 95616 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1529425
Grant/Contract Number:  
SC0016573
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Name: Chemistry - A European Journal Journal Volume: 25 Journal Issue: 43; Journal ID: ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Linares, Noemi, De Oliveira Jardim, Erika, Sharma, Geetu, Serrano, Elena, Navrotsky, Alexandra, and García‐Martínez, Javier. Thermochemistry of Surfactant‐Templating of USY Zeolite. Germany: N. p., 2019. Web. doi:10.1002/chem.201901507.
Linares, Noemi, De Oliveira Jardim, Erika, Sharma, Geetu, Serrano, Elena, Navrotsky, Alexandra, & García‐Martínez, Javier. Thermochemistry of Surfactant‐Templating of USY Zeolite. Germany. https://doi.org/10.1002/chem.201901507
Linares, Noemi, De Oliveira Jardim, Erika, Sharma, Geetu, Serrano, Elena, Navrotsky, Alexandra, and García‐Martínez, Javier. Mon . "Thermochemistry of Surfactant‐Templating of USY Zeolite". Germany. https://doi.org/10.1002/chem.201901507.
@article{osti_1529425,
title = {Thermochemistry of Surfactant‐Templating of USY Zeolite},
author = {Linares, Noemi and De Oliveira Jardim, Erika and Sharma, Geetu and Serrano, Elena and Navrotsky, Alexandra and García‐Martínez, Javier},
abstractNote = {Abstract With the aim of understanding the thermochemistry of the introduction of mesoporosity in zeolites by using surfactants, high temperature oxide melt solution calorimetry was used to determine the change in the enthalpy of formation of USY zeolite before and after the introduction of mesoporosity. Our results confirm that this process only slightly destabilizes the zeolite by the additional surface area. However, this can be overcome by the stabilizing effect of the interactions between the surfactant and the zeolite framework.},
doi = {10.1002/chem.201901507},
journal = {Chemistry - A European Journal},
number = 43,
volume = 25,
place = {Germany},
year = {Mon Jun 24 00:00:00 EDT 2019},
month = {Mon Jun 24 00:00:00 EDT 2019}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/chem.201901507

Citation Metrics:
Cited by: 5 works
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Works referenced in this record:

Mesostructured zeolite Y—high hydrothermal stability and superior FCC catalytic performance
journal, January 2012

  • García-Martínez, Javier; Johnson, Marvin; Valla, Julia
  • Catalysis Science & Technology, Vol. 2, Issue 5
  • DOI: 10.1039/c2cy00309k

Transformation synthesis of aluminosilicate SSZ-39 zeolite from ZSM-5 and beta zeolite
journal, January 2019

  • Xu, Hao; Chen, Wei; Wu, Qinming
  • Journal of Materials Chemistry A, Vol. 7, Issue 9
  • DOI: 10.1039/C9TA00174C

The Energetics of Surfactant-Templating of Zeolites
journal, June 2018

  • Linares, Noemi; Jardim, Erika O.; Sachse, Alexander
  • Angewandte Chemie International Edition, Vol. 57, Issue 28
  • DOI: 10.1002/anie.201803759

Evidence of Intracrystalline Mesostructured Porosity in Zeolites by Advanced Gas Sorption, Electron Tomography and Rotation Electron Diffraction
journal, August 2014

  • Garcia-Martinez, Javier; Xiao, Changhong; Cychosz, Katie A.
  • ChemCatChem, Vol. 6, Issue 11
  • DOI: 10.1002/cctc.201402499

Progress and new directions in high temperature calorimetry
journal, January 1977

  • Navrotsky, Alexandra
  • Physics and Chemistry of Minerals, Vol. 2, Issue 1-2
  • DOI: 10.1007/BF00307526

High-silica zeolites: a relationship between energetics and internal surface areas
journal, July 2002

  • Moloy, Eric C.; Davila, Lilian P.; Shackelford, James F.
  • Microporous and Mesoporous Materials, Vol. 54, Issue 1-2
  • DOI: 10.1016/S1387-1811(02)00328-1

Realizing the Commercial Potential of Hierarchical Zeolites: New Opportunities in Catalytic Cracking
journal, September 2013


Thermally stable nanosized LEV zeolites synthesized by hydrothermal conversion of FAU zeolites in the presence of N,N-dimethylpiperidinium cations
journal, January 2017

  • Funase, Natsumi; Tanigawa, Takuya; Yamasaki, Yoshitaka
  • Journal of Materials Chemistry A, Vol. 5, Issue 36
  • DOI: 10.1039/C7TA04988A

Accelerated Construction of High-Silica RHO and CHA Zeolites via Interzeolite Transformation and Their NH 3 –SCR Performances after Copper Exchange
journal, November 2018

  • Ke, Quanli; Sun, Tianjun; Cheng, Hao
  • Industrial & Engineering Chemistry Research, Vol. 57, Issue 49
  • DOI: 10.1021/acs.iecr.8b03907

A mesostructured Y zeolite as a superior FCC catalyst – from lab to refinery
journal, January 2012

  • García-Martínez, Javier; Li, Kunhao; Krishnaiah, Gautham
  • Chemical Communications, Vol. 48, Issue 97
  • DOI: 10.1039/c2cc35659g

Quantifying the Complex Pore Architecture of Hierarchical Faujasite Zeolites and the Impact on Diffusion
journal, May 2016

  • Kenvin, Jeffrey; Mitchell, Sharon; Sterling, Michael
  • Advanced Functional Materials, Vol. 26, Issue 31
  • DOI: 10.1002/adfm.201601748

Progress and new directions in high temperature calorimetry revisited
journal, April 1997


Development of Intracrystalline Mesoporosity in Zeolites through Surfactant-Templating
journal, June 2017

  • Sachse, Alexander; Grau-Atienza, Aida; Jardim, Erika O.
  • Crystal Growth & Design, Vol. 17, Issue 8
  • DOI: 10.1021/acs.cgd.7b00619

Mesoporous silica synthesis: Energetics of interaction between framework and structure directing agent
journal, February 2012


Energetics of Mesoporous Silica:  Investigation into Pore Size and Symmetry
journal, July 2005

  • Trofymluk, Olga; Levchenko, Andrey A.; Tolbert, Sarah H.
  • Chemistry of Materials, Vol. 17, Issue 14
  • DOI: 10.1021/cm050366g

Thermochemistry and phase equilibria in calcium zeolites
journal, June 1996

  • Kiseleva, Irina; Navrotsky, Alexandra; Belitsky, Igor A.
  • American Mineralogist, Vol. 81, Issue 5-6
  • DOI: 10.2138/am-1996-5-613

One-pot structural conversion of magadiite into MFI zeolite nanosheets using mononitrogen surfactants as structure and shape-directing agents
journal, January 2013

  • Dhainaut, Jérémy; Daou, T. Jean; Bidal, Yannick
  • CrystEngComm, Vol. 15, Issue 15
  • DOI: 10.1039/c3ce40118a

In Situ Time-Resolved Observation of the Development of Intracrystalline Mesoporosity in USY Zeolite
journal, December 2016


High yield synthesis of high-silica chabazite by combining the role of zeolite precursors and tetraethylammonium: SCR of NOx
journal, January 2015

  • Martín, Nuria; Moliner, Manuel; Corma, Avelino
  • Chemical Communications, Vol. 51, Issue 49
  • DOI: 10.1039/C5CC02670A

The Energetics of Surfactant-Templating of Zeolites
journal, June 2018

  • Linares, Noemi; Jardim, Erika O.; Sachse, Alexander
  • Angewandte Chemie, Vol. 130, Issue 28
  • DOI: 10.1002/ange.201803759

Synthesis and Crystal Structure of a Layered Silicate HUS-1 with a Halved Sodalite-Cage Topology
journal, March 2011

  • Ikeda, Takuji; Oumi, Yasunori; Honda, Koutaro
  • Inorganic Chemistry, Vol. 50, Issue 6
  • DOI: 10.1021/ic1020065

Thermochemistry of Microporous and Mesoporous Materials
journal, September 2009

  • Navrotsky, Alexandra; Trofymluk, Olga; Levchenko, Andrey A.
  • Chemical Reviews, Vol. 109, Issue 9
  • DOI: 10.1021/cr800495t