Evolution of short- and medium-range order in the melt-quenching amorphization of Ge2Sb2Te5

Qiao, Chong; Guo, Y. R.; Dong, F.; Wang, J. J.; Shen, H.; Wang, Song You; Xu, Ming; Miao, X. S.; Zheng, Y. X.; Zhang, R. J.; Chen, L. Y.; Wang, C. Z.; Ho, K. M.

doi:10.1039/C8TC00549D

Title: Evolution of short- and medium-range order in the melt-quenching amorphization of Ge₂Sb₂Te₅

Journal Article · 11 April 2018 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/C8TC00549D · OSTI ID:1529369

^[1];

^[1]; Shen, H. ^[1];

^[2];

^[3];

^[1]; Zhang, R. J. ^[1]; Chen, L. Y. ^[1]; Wang, C. Z. ^[4]; Ho, K. M. ^[4]

Fudan Univ., Shanghai (China)
Fudan Univ., Shanghai (China); Key Lab. for Information Science of Electromagnetic Waves (MoE), Shanghai (China)
Huazhong Univ. of Science & Technology, Wuhan (China)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Phase-change memory takes advantage of the fast phase transition between amorphous and crystalline phases of phase-change materials (e.g.,Ge₂Sb₂Te₅ or GST). To date, while the “SET” process (crystallization of GST glass) has been intensively studied, studies on the “RESET” process (melt-quenching amorphization of GST) are still limited. Here, we explore the structural changes of GST upon rapid cooling by ab initio molecular dynamics simulations and atomistic cluster alignment (ACA) analysis. Different from other methods which only focus on the nearest bonding atoms, the ACA method can study both the short- and medium-range order clusters containing atoms beyond the first-neighboring shell and enables us to explore the changes of cluster structures in a larger scale. The results reveal that low-coordinated octahedral clusters tend to become high-coordinated ones, and Ge-centered octahedral structures change to tetrahedrons whereas Sb-centered tetrahedrons transform to octahedral structures during the amorphization process. Interestingly, tetrahedrons show aggregation in liquid and supercooled liquid in contrast to 6-fold octahedrons which present notable aggregation in amorphous GST. Furthermore, our study showed that wrong bonds (Ge–Ge, Sb–Sb, Ge–Sb and Te–Te bonds) can promote the formation of large rings, and irreducible rings tend to separate into smaller and larger rings as the temperature is decreased. Our conclusions provide useful insights into the formation process and the structure of amorphous GST, which is valuable for facilitating the application of phase change materials.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); National Key R&D Plan of China; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Energy Research Scientific Computing Centre (NERSC)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1529369

Report Number(s):: IS-J--9688

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 18 Vol. 6; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Evolution of short- and medium-range order in the melt-quenching amorphization of Ge2Sb2Te5

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Title: Evolution of short- and medium-range order in the melt-quenching amorphization of Ge₂Sb₂Te₅