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Title: Solvent–Adsorbate Interactions and Adsorbate-Specific Solvent Structure in Carbon Dioxide Reduction on a Stepped Cu Surface

Abstract

In this work, the structure of water and its interactions with various carbon dioxide reduction intermediates adsorbed on a Cu(211) surface is investigated using density functional theory. We find that the presence of adsorbates has a significant and adsorbate-specific effect on the local water structure and that solvation can stabilize adsorbate conformations different from those found in vacuum. We describe relationships between the hydrogen bonding capability of an adsorbate, the dipole moment of the adsorbate, the energetic strength of water–adsorbate interactions, and the change induced in the local water orientation by the adsorbate. Mechanistic implications are discussed. Here, we investigate and quantify the error associated with using arbitrary locally optimized solvent structures in calculations of relevant physical quantities, such as solvated binding energies and work functions. Possible effects of thermal motion on calculations of the work function are investigated using ab initio molecular dynamics.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [2]; ORCiD logo [2]
+ Show Author Affiliations
  1. SLAC National Accelerator Lab., Menlo Park, CA (United States); Stanford Univ., Stanford, CA (United States)
  2. Technical Univ. of Denmark, Kongens Lyngby (Denmark)
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1529086
Grant/Contract Number:  
AC02-76SF00515; SC0008685; FG02-97ER25308
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 123; Journal Issue: 10; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Ludwig, Thomas, Gauthier, Joseph A., Brown, Kristopher S., Ringe, Stefan, Nørskov, Jens K., and Chan, Karen. Solvent–Adsorbate Interactions and Adsorbate-Specific Solvent Structure in Carbon Dioxide Reduction on a Stepped Cu Surface. United States: N. p., 2019. Web. doi:10.1021/acs.jpcc.8b11571.
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Ludwig, Thomas, Gauthier, Joseph A., Brown, Kristopher S., Ringe, Stefan, Nørskov, Jens K., & Chan, Karen. Solvent–Adsorbate Interactions and Adsorbate-Specific Solvent Structure in Carbon Dioxide Reduction on a Stepped Cu Surface. United States. https://doi.org/10.1021/acs.jpcc.8b11571
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Ludwig, Thomas, Gauthier, Joseph A., Brown, Kristopher S., Ringe, Stefan, Nørskov, Jens K., and Chan, Karen. Fri . "Solvent–Adsorbate Interactions and Adsorbate-Specific Solvent Structure in Carbon Dioxide Reduction on a Stepped Cu Surface". United States. https://doi.org/10.1021/acs.jpcc.8b11571. https://www.osti.gov/servlets/purl/1529086.
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@article{osti_1529086,
title = {Solvent–Adsorbate Interactions and Adsorbate-Specific Solvent Structure in Carbon Dioxide Reduction on a Stepped Cu Surface},
author = {Ludwig, Thomas and Gauthier, Joseph A. and Brown, Kristopher S. and Ringe, Stefan and Nørskov, Jens K. and Chan, Karen},
abstractNote = {In this work, the structure of water and its interactions with various carbon dioxide reduction intermediates adsorbed on a Cu(211) surface is investigated using density functional theory. We find that the presence of adsorbates has a significant and adsorbate-specific effect on the local water structure and that solvation can stabilize adsorbate conformations different from those found in vacuum. We describe relationships between the hydrogen bonding capability of an adsorbate, the dipole moment of the adsorbate, the energetic strength of water–adsorbate interactions, and the change induced in the local water orientation by the adsorbate. Mechanistic implications are discussed. Here, we investigate and quantify the error associated with using arbitrary locally optimized solvent structures in calculations of relevant physical quantities, such as solvated binding energies and work functions. Possible effects of thermal motion on calculations of the work function are investigated using ab initio molecular dynamics.},
doi = {10.1021/acs.jpcc.8b11571},
journal = {Journal of Physical Chemistry. C},
number = 10,
volume = 123,
place = {United States},
year = {Fri Feb 15 00:00:00 EST 2019},
month = {Fri Feb 15 00:00:00 EST 2019}
}
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https://doi.org/10.1021/acs.jpcc.8b11571
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Works referenced in this record:

Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption
journal, February 2013

  • Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao
  • Nature Chemistry, Vol. 5, Issue 4
  • DOI: 10.1038/nchem.1574

Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes
journal, March 2017

  • Ledezma-Yanez, Isis; Wallace, W. David Z.; Sebastián-Pascual, Paula
  • Nature Energy, Vol. 2, Issue 4
  • DOI: 10.1038/nenergy.2017.31

Electrochemical Reduction of Carbon Dioxide at a Platinum Electrode in Acetonitrile-Water Mixtures
journal, January 2000

  • Tomita, Y.; Teruya, S.; Koga, O.
  • Journal of The Electrochemical Society, Vol. 147, Issue 11
  • DOI: 10.1149/1.1394035

Tuning of Silver Catalyst Mesostructure Promotes Selective Carbon Dioxide Conversion into Fuels
journal, November 2016

  • Yoon, Youngmin; Hall, Anthony Shoji; Surendranath, Yogesh
  • Angewandte Chemie, Vol. 128, Issue 49
  • DOI: 10.1002/ange.201607942

Inhibited proton transfer enhances Au-catalyzed CO 2 -to-fuels selectivity
journal, July 2016

  • Wuttig, Anna; Yaguchi, Momo; Motobayashi, Kenta
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 32
  • DOI: 10.1073/pnas.1602984113

Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide
journal, August 2017

  • Resasco, Joaquin; Chen, Leanne D.; Clark, Ezra
  • Journal of the American Chemical Society, Vol. 139, Issue 32
  • DOI: 10.1021/jacs.7b06765

Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes
journal, November 2017

  • Pérez-Gallent, Elena; Marcandalli, Giulia; Figueiredo, Marta Costa
  • Journal of the American Chemical Society, Vol. 139, Issue 45
  • DOI: 10.1021/jacs.7b10142

Operando chemistry of catalyst surfaces during catalysis
journal, January 2017

  • Dou, Jian; Sun, Zaicheng; Opalade, Adedamola A.
  • Chemical Society Reviews, Vol. 46, Issue 7
  • DOI: 10.1039/c6cs00931j

Operando X-Ray Photoelectron Spectroscopy Studies of Aqueous Electrocatalytic Systems
journal, January 2016

Metal- and Hydrogen-Bonding Competition during Water Adsorption on Pd(111) and Ru(0001)
journal, December 2009

  • Tatarkhanov, Mous; Ogletree, D. Frank; Rose, Franck
  • Journal of the American Chemical Society, Vol. 131, Issue 51
  • DOI: 10.1021/ja907468m

Partial Dissociation of Water on Ru(0001)
journal, January 2002

Water adsorption and the wetting of metal surfaces
journal, September 2009

A molecular perspective of water at metal interfaces
journal, July 2012

  • Carrasco, Javier; Hodgson, Andrew; Michaelides, Angelos
  • Nature Materials, Vol. 11, Issue 8
  • DOI: 10.1038/nmat3354

Cooperativity in Surface Bonding and Hydrogen Bonding of Water and Hydroxyl at Metal Surfaces
journal, May 2010

  • Schiros, T.; Ogasawara, H.; Näslund, L. -Å.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 22
  • DOI: 10.1021/jp101855v

Water and its partially dissociated fragments at metal surfaces
journal, February 2017

A unique vibrational signature of rotated water monolayers on Pt(111): Predicted and observed
journal, May 2011

  • Feibelman, Peter J.; Kimmel, Greg A.; Smith, R. Scott
  • The Journal of Chemical Physics, Vol. 134, Issue 20
  • DOI: 10.1063/1.3591966

A one-dimensional ice structure built from pentagons
journal, March 2009

  • Carrasco, Javier; Michaelides, Angelos; Forster, Matthew
  • Nature Materials, Vol. 8, Issue 5
  • DOI: 10.1038/nmat2403

Anisotropic Water Chain Growth on Cu(110) Observed with Scanning Tunneling Microscopy
journal, January 2006

Turning things downside up: Adsorbate induced water flipping on Pt(111)
journal, November 2014

  • Kimmel, Greg A.; Zubkov, Tykhon; Smith, R. Scott
  • The Journal of Chemical Physics, Vol. 141, Issue 18
  • DOI: 10.1063/1.4896226

Diversity at the Water–Metal Interface: Metal, Water Thickness, and Confinement Effects
journal, February 2016

  • Bellarosa, Luca; García-Muelas, Rodrigo; Revilla-López, Guillem
  • ACS Central Science, Vol. 2, Issue 2
  • DOI: 10.1021/acscentsci.5b00349

Properties of metal–water interfaces studied from first principles
journal, December 2009

Water Structures at Metal Electrodes Studied by Ab Initio Molecular Dynamics Simulations
journal, January 2014

  • Groß, Axel; Gossenberger, Florian; Lin, Xiaohang
  • Journal of The Electrochemical Society, Vol. 161, Issue 8
  • DOI: 10.1149/2.003408jes

The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy
journal, October 2014

The structure of water at a Pt(111) electrode and the potential of zero charge studied from first principles
journal, May 2016

  • Sakong, Sung; Forster-Tonigold, Katrin; Groß, Axel
  • The Journal of Chemical Physics, Vol. 144, Issue 19
  • DOI: 10.1063/1.4948638

The electric double layer at metal-water interfaces revisited based on a charge polarization scheme
journal, August 2018

  • Sakong, Sung; Groß, Axel
  • The Journal of Chemical Physics, Vol. 149, Issue 8
  • DOI: 10.1063/1.5040056

Solvation Effects for Oxygen Evolution Reaction Catalysis on IrO 2 (110)
journal, May 2017

  • Gauthier, Joseph A.; Dickens, Colin F.; Chen, Leanne D.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 21
  • DOI: 10.1021/acs.jpcc.7b02383

Acidity of the Aqueous Rutile TiO 2 (110) Surface from Density Functional Theory Based Molecular Dynamics
journal, February 2010

  • Cheng, Jun; Sprik, Michiel
  • Journal of Chemical Theory and Computation, Vol. 6, Issue 3
  • DOI: 10.1021/ct100013q

Hole Localization and Thermochemistry of Oxidative Dehydrogenation of Aqueous Rutile TiO2(110)
journal, March 2012

  • Cheng, Jun; Sulpizi, Marialore; VandeVondele, Joost
  • ChemCatChem, Vol. 4, Issue 5
  • DOI: 10.1002/cctc.201100498

Titania-water interactions: a review of theoretical studies
journal, January 2010

  • Sun, Chenghua; Liu, Li-Min; Selloni, Annabella
  • Journal of Materials Chemistry, Vol. 20, Issue 46
  • DOI: 10.1039/c0jm01491e

Atomic-Scale Analysis of the RuO 2 /Water Interface under Electrochemical Conditions
journal, April 2016

  • Watanabe, Eriko; Rossmeisl, Jan; Björketun, Mårten E.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 15
  • DOI: 10.1021/acs.jpcc.5b12448

Water adsorption on bimetallic PtRu/Pt(111) surface alloys
journal, October 2016

  • Fischer, Julia M.; Mahlberg, David; Roman, Tanglaw
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 472, Issue 2194
  • DOI: 10.1098/rspa.2016.0618

Two-Dimensional Wetting of a Stepped Copper Surface
journal, February 2018

Double-Stranded Water on Stepped Platinum Surfaces
journal, March 2016

Nature of Lone-Pair–Surface Bonds and Their Scaling Relations
journal, June 2018

Modelling pH and potential in dynamic structures of the water/Pt(111) interface on the atomic scale
journal, January 2017

  • Hansen, Martin Hangaard; Nilsson, Anders; Rossmeisl, Jan
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 34
  • DOI: 10.1039/c7cp03576d

pH in Grand Canonical Statistics of an Electrochemical Interface
journal, December 2016

  • Hansen, Martin Hangaard; Rossmeisl, Jan
  • The Journal of Physical Chemistry C, Vol. 120, Issue 51
  • DOI: 10.1021/acs.jpcc.6b09019

Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
journal, November 2004

  • Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 46
  • DOI: 10.1021/jp047349j

Electric Field Effects in Electrochemical CO 2 Reduction
journal, September 2016

Theoretical Insights into a CO Dimerization Mechanism in CO 2 Electroreduction
journal, May 2015

  • Montoya, Joseph H.; Shi, Chuan; Chan, Karen
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
  • DOI: 10.1021/acs.jpclett.5b00722

CO-CO coupling on Cu facets: Coverage, strain and field effects
journal, December 2016

Electrochemical Barriers Made Simple
journal, June 2015

Estimations of electric field effects on the oxygen reduction reaction based on the density functional theory
journal, January 2007

  • Karlberg, G. S.; Rossmeisl, J.; Nørskov, J. K.
  • Physical Chemistry Chemical Physics, Vol. 9, Issue 37
  • DOI: 10.1039/b705938h

Modeling the Electrochemical Hydrogen Oxidation and Evolution Reactions on the Basis of Density Functional Theory Calculations
journal, October 2010

  • Skúlason, Egill; Tripkovic, Vladimir; Björketun, Mårten E.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 42
  • DOI: 10.1021/jp1048887

Reaction Pathways for Oxygen Evolution Promoted by Cobalt Catalyst
journal, October 2013

  • Mattioli, Giuseppe; Giannozzi, Paolo; Amore Bonapasta, Aldo
  • Journal of the American Chemical Society, Vol. 135, Issue 41
  • DOI: 10.1021/ja401797v

Understanding trends in electrochemical carbon dioxide reduction rates
journal, May 2017

  • Liu, Xinyan; Xiao, Jianping; Peng, Hongjie
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15438

Calculations of Product Selectivity in Electrochemical CO 2 Reduction
journal, April 2018

Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K
journal, February 2017

  • Cheng, Tao; Xiao, Hai; Goddard, William A.
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 8
  • DOI: 10.1073/pnas.1612106114

Non-covalent interactions in electrochemical reactions and implications in clean energy applications
journal, January 2018

  • Huang, Botao; Muy, Sokseiha; Feng, Shuting
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 23
  • DOI: 10.1039/c8cp02512f

CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
journal, May 2018

Electrochemical CO Reduction Builds Solvent Water into Oxygenate Products
journal, July 2018

  • Lum, Yanwei; Cheng, Tao; Goddard, William A.
  • Journal of the American Chemical Society, Vol. 140, Issue 30
  • DOI: 10.1021/jacs.8b03986

Solvation Effects on OH Adsorbates on Stepped Pt Surfaces
journal, July 2015

  • Jinnouchi, Ryosuke; Nagoya, Akihiro; Kodama, Kensaku
  • The Journal of Physical Chemistry C, Vol. 119, Issue 29
  • DOI: 10.1021/acs.jpcc.5b04598

Electrochemical CO Reduction: A Property of the Electrochemical Interface
journal, December 2018

  • Bagger, Alexander; Arnarson, Logi; Hansen, Martin H.
  • Journal of the American Chemical Society, Vol. 141, Issue 4
  • DOI: 10.1021/jacs.8b08839

Water Exchange at a Hydrated Platinum Electrode is Rare and Collective
journal, October 2015

  • Limmer, David T.; Willard, Adam P.; Madden, Paul A.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 42
  • DOI: 10.1021/acs.jpcc.5b08137

Hydration of metal surfaces can be dynamically heterogeneous and hydrophobic
journal, February 2013

  • Limmer, David T.; Willard, Adam P.; Madden, Paul
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 11
  • DOI: 10.1073/pnas.1301596110

Influence of surface topology and electrostatic potential on water/electrode systems
journal, January 1995

  • Siepmann, J. Ilja; Sprik, Michiel
  • The Journal of Chemical Physics, Vol. 102, Issue 1
  • DOI: 10.1063/1.469429

Water at an electrochemical interface—a simulation study
journal, January 2009

  • Willard, Adam P.; Reed, Stewart K.; Madden, Paul A.
  • Faraday Discuss., Vol. 141
  • DOI: 10.1039/b805544k

Force Field for Water over Pt(111): Development, Assessment, and Comparison
journal, April 2018

  • Steinmann, Stephan N.; Ferreira De Morais, Rodrigo; Götz, Andreas W.
  • Journal of Chemical Theory and Computation, Vol. 14, Issue 6
  • DOI: 10.1021/acs.jctc.7b01177

Joint density-functional theory for electronic structure of solvated systems
journal, May 2007

Revised self-consistent continuum solvation in electronic-structure calculations
journal, February 2012

  • Andreussi, Oliviero; Dabo, Ismaila; Marzari, Nicola
  • The Journal of Chemical Physics, Vol. 136, Issue 6
  • DOI: 10.1063/1.3676407

Solvation free energies for periodic surfaces: comparison of implicit and explicit solvation models
journal, January 2016

  • Steinmann, Stephan N.; Sautet, Philippe; Michel, Carine
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 46
  • DOI: 10.1039/c6cp04094b

Challenges in Modeling Electrochemical Reaction Energetics with Polarizable Continuum Models
journal, November 2018

Insights into CC Coupling in CO 2 Electroreduction on Copper Electrodes
journal, January 2013

  • Montoya, Joseph H.; Peterson, Andrew A.; Nørskov, Jens K.
  • ChemCatChem, Vol. 5, Issue 3
  • DOI: 10.1002/cctc.201200564

Minima hopping: An efficient search method for the global minimum of the potential energy surface of complex molecular systems
journal, June 2004

  • Goedecker, Stefan
  • The Journal of Chemical Physics, Vol. 120, Issue 21
  • DOI: 10.1063/1.1724816

Global Optimization of Adsorbate–Surface Structures While Preserving Molecular Identity
journal, October 2013

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009

  • Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
  • Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
  • DOI: 10.1088/0953-8984/21/39/395502

The atomic simulation environment—a Python library for working with atoms
journal, June 2017

  • Hjorth Larsen, Ask; Jørgen Mortensen, Jens; Blomqvist, Jakob
  • Journal of Physics: Condensed Matter, Vol. 29, Issue 27
  • DOI: 10.1088/1361-648X/aa680e

Van der Waals density functional: Self-consistent potential and the nature of the van der Waals bond
journal, September 2007

Implementation of ultrasoft pseudopotentials in ab initio molecular dynamics
journal, March 1991

Car-Parrinello molecular dynamics with Vanderbilt ultrasoft pseudopotentials
journal, April 1993

Pseudopotentials for high-throughput DFT calculations
journal, January 2014

Electronic structure calculations with GPAW: a real-space implementation of the projector augmented-wave method
journal, June 2010

VMD: Visual molecular dynamics
journal, February 1996

Proton-Transfer Mechanisms at the Water–ZnO Interface: The Role of Presolvation
journal, March 2017

  • Quaranta, Vanessa; Hellström, Matti; Behler, Jörg
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 7
  • DOI: 10.1021/acs.jpclett.7b00358

Role of Presolvation and Anharmonicity in Aqueous Phase Hydrated Proton Solvation and Transport
journal, November 2015

  • Biswas, Rajib; Tse, Ying-Lung Steve; Tokmakoff, Andrei
  • The Journal of Physical Chemistry B, Vol. 120, Issue 8
  • DOI: 10.1021/acs.jpcb.5b09466

Molecular Mechanism of HCl Acid Ionization in Water:  Ab Initio Potential Energy Surfaces and Monte Carlo Simulations
journal, December 1997

  • Ando, Koji; Hynes, James T.
  • The Journal of Physical Chemistry B, Vol. 101, Issue 49
  • DOI: 10.1021/jp970173j

Chemical and Electrochemical Electron-Transfer Theory
journal, October 1964

The absolute electrode potential: an explanatory note (Recommendations 1986)
journal, January 1986

First-Principles Simulations of Liquid Water Using a Dielectric-Dependent Hybrid Functional
journal, May 2018

  • Gaiduk, Alex P.; Gustafson, Jeffrey; Gygi, François
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 11
  • DOI: 10.1021/acs.jpclett.8b01017

Electron affinity of liquid water
journal, January 2018

Perspective: How good is DFT for water?
journal, April 2016

  • Gillan, Michael J.; Alfè, Dario; Michaelides, Angelos
  • The Journal of Chemical Physics, Vol. 144, Issue 13
  • DOI: 10.1063/1.4944633

Accurate first-principles structures and energies of diversely bonded systems from an efficient density functional
journal, June 2016

  • Sun, Jianwei; Remsing, Richard C.; Zhang, Yubo
  • Nature Chemistry, Vol. 8, Issue 9
  • DOI: 10.1038/nchem.2535

Equilibration and analysis of first-principles molecular dynamics simulations of water
journal, March 2018

  • Dawson, William; Gygi, François
  • The Journal of Chemical Physics, Vol. 148, Issue 12
  • DOI: 10.1063/1.5018116
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