DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: XY antiferromagnetic ground state in the effective S = 1 2 pyrochlore Yb 2 Ge 2 O 7

Abstract

We report neutron scattering and muon spin relaxation measurements (μSR) on the pyrochlore antiferromagnet Yb2Ge2O7. Inelastic neutron scattering was used to probe the transitions between crystal electric field levels, allowing us to determine the eigenvalues and eigenvectors appropriate to the J=$$\frac{7}{2}$$ Yb3+ ion in this environment. The crystal electric field ground state doublet in Yb2Ge2O7 corresponds primarily to mJ=± $$\frac{1}{2}$$ with local XY anisotropy, consistent with an Seff = 12 description for the Yb moments. $$μ$$SR measurements reveal the presence of an ordering transition at TN=0.57 K with persistent weak dynamics in the ordered state. Finally, we present neutron diffraction measurements that reveal a clear phase transition to the $$k$$=(000)$$Γ_5$$ ground state with an ordered magnetic moment of 0.3(1)$$μ_B$$ per Yb ion. We compare and contrast this phenomenology with the low-temperature behavior of Yb2Ti2O7 and Er2Ti2O7, the prototypical Seff= $$\frac{1}{2}$$ XY pyrochlore magnets.

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [2]; ORCiD logo [2];  [3];  [4];  [4];  [5];  [6];  [7];  [7]
  1. McMaster Univ., Hamilton, ON (Canada). Dept. of Physics and Astronomy
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
  3. Univ. de São Paulo, São Paulo (Brazil). Inst. de Física
  4. Univ. of Edinburgh, Edinburgh (United Kingdom)
  5. National Inst. for Materials Science (NIMS), Tsukuba (Japan)
  6. Univ. of Winnipeg, Winnipeg, Manitoba (Canada). Dept. of Chemistry
  7. McMaster Univ., Hamilton, ON (Canada). Dept. of Physics and Astronomy; Canadian Inst. for Advanced Research, Toronto, ON (Canada)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1528742
Alternate Identifier(s):
OSTI ID: 1240478
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 93; Journal Issue: 10; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Hallas, Alannah M., Gaudet, J., Wilson, Murray N., Munsie, Timothy J., Aczel, Adam A., Stone, Matthew B., Freitas, R. S., Arevalo-Lopez, A. M., Attfield, J. P., Tachibana, Makoto, Wiebe, Christopher, Luke, Graeme M., and Gaulin, Bruce D. XY antiferromagnetic ground state in the effective S=12 pyrochlore Yb2Ge2O7. United States: N. p., 2016. Web. doi:10.1103/PhysRevB.93.104405.
Hallas, Alannah M., Gaudet, J., Wilson, Murray N., Munsie, Timothy J., Aczel, Adam A., Stone, Matthew B., Freitas, R. S., Arevalo-Lopez, A. M., Attfield, J. P., Tachibana, Makoto, Wiebe, Christopher, Luke, Graeme M., & Gaulin, Bruce D. XY antiferromagnetic ground state in the effective S=12 pyrochlore Yb2Ge2O7. United States. https://doi.org/10.1103/PhysRevB.93.104405
Hallas, Alannah M., Gaudet, J., Wilson, Murray N., Munsie, Timothy J., Aczel, Adam A., Stone, Matthew B., Freitas, R. S., Arevalo-Lopez, A. M., Attfield, J. P., Tachibana, Makoto, Wiebe, Christopher, Luke, Graeme M., and Gaulin, Bruce D. Tue . "XY antiferromagnetic ground state in the effective S=12 pyrochlore Yb2Ge2O7". United States. https://doi.org/10.1103/PhysRevB.93.104405. https://www.osti.gov/servlets/purl/1528742.
@article{osti_1528742,
title = {XY antiferromagnetic ground state in the effective S=12 pyrochlore Yb2Ge2O7},
author = {Hallas, Alannah M. and Gaudet, J. and Wilson, Murray N. and Munsie, Timothy J. and Aczel, Adam A. and Stone, Matthew B. and Freitas, R. S. and Arevalo-Lopez, A. M. and Attfield, J. P. and Tachibana, Makoto and Wiebe, Christopher and Luke, Graeme M. and Gaulin, Bruce D.},
abstractNote = {We report neutron scattering and muon spin relaxation measurements (μSR) on the pyrochlore antiferromagnet Yb2Ge2O7. Inelastic neutron scattering was used to probe the transitions between crystal electric field levels, allowing us to determine the eigenvalues and eigenvectors appropriate to the J=$\frac{7}{2}$ Yb3+ ion in this environment. The crystal electric field ground state doublet in Yb2Ge2O7 corresponds primarily to mJ=± $\frac{1}{2}$ with local XY anisotropy, consistent with an Seff = 12 description for the Yb moments. $μ$SR measurements reveal the presence of an ordering transition at TN=0.57 K with persistent weak dynamics in the ordered state. Finally, we present neutron diffraction measurements that reveal a clear phase transition to the $k$=(000)$Γ_5$ ground state with an ordered magnetic moment of 0.3(1)$μ_B$ per Yb ion. We compare and contrast this phenomenology with the low-temperature behavior of Yb2Ti2O7 and Er2Ti2O7, the prototypical Seff= $\frac{1}{2}$ XY pyrochlore magnets.},
doi = {10.1103/PhysRevB.93.104405},
journal = {Physical Review B},
number = 10,
volume = 93,
place = {United States},
year = {Tue Mar 01 00:00:00 EST 2016},
month = {Tue Mar 01 00:00:00 EST 2016}
}

Journal Article:

Citation Metrics:
Cited by: 26 works
Citation information provided by
Web of Science

Figures / Tables:

FIG. 1. FIG. 1.: (a) Inelastic neutron scattering spectrum of Yb2Ge2O7 measured at 2 K with a neutron beam of incident energy 150 meV. A background spectrum, measured on an empty can, has been subtracted from the data. Crystal eld excitations at 80.7 meV, 84.2 meV, and 123.3 meV are indicated bymore » the blue, yellow, and green arrows, respectively. (b) An integrated cut of the same data over the range Q = [5.4, 6.0] Å-1. The fit to the data is achieved using a Hamiltonian, given by Eqn. 1, which approximates the Coulomb potential generated by the crystal electric fi eld due to the neighboring oxygen atoms.« less

Save / Share:

Works referenced in this record:

Matrix Elements and Operator Equivalents Connected with the Magnetic Properties of Rare Earth Ions
journal, March 1952


Structural distortion and the spin liquid state in Tb 2 Ti 2 O 7
journal, September 2008


Order by Quantum Disorder in Er 2 Ti 2 O 7
journal, October 2012


Evidence for unidimensional low-energy excitations as the origin of persistent spin dynamics in geometrically frustrated magnets
journal, March 2015


Tetrahedral Magnetic Order and the Metal-Insulator Transition in the Pyrochlore Lattice of Cd 2 Os 2 O 7
journal, June 2012


Emergence of Magnetic Long-range Order in Frustrated Pyrochlore Nd 2 Ir 2 O 7 with Metal–Insulator Transition
journal, March 2012

  • Tomiyasu, Keisuke; Matsuhira, Kazuyuki; Iwasa, Kazuaki
  • Journal of the Physical Society of Japan, Vol. 81, Issue 3
  • DOI: 10.1143/JPSJ.81.034709

Quantum Order by Disorder and Accidental Soft Mode in Er 2 Ti 2 O 7
journal, August 2012


Er 2 Ti 2 O 7 : Evidence of quantum order by disorder in a frustrated antiferromagnet
journal, July 2003


Magnetic phase transitions and magnetic entropy in the XY antiferromagnetic pyrochlores (Er 1− x Y x ) 2 Ti 2 O 7
journal, November 2014

  • Niven, John F.; Johnson, Michel B.; Bourque, Alex
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 470, Issue 2171
  • DOI: 10.1098/rspa.2014.0387

Magnetic ordering and dynamics in the XY pyrochlore antiferromagnet: a muon-spin relaxation study of Er 2 Ti 2 O 7 and Er 2 Sn 2 O 7
journal, January 2005


Bulk magnetization of the heavy rare earth titanate pyrochlores - a series of model frustrated magnets
journal, December 1999

  • Bramwell, S. T.; Field, M. N.; Harris, M. J.
  • Journal of Physics: Condensed Matter, Vol. 12, Issue 4
  • DOI: 10.1088/0953-8984/12/4/308

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993


Antiferromagnetic order in the pyrochlores R 2 Ge 2 O 7   ( R = Er , Yb )
journal, October 2015


Energetic selection of ordered states in a model of the Er 2 Ti 2 O 7 frustrated pyrochlore XY antiferromagnet
journal, January 2009


Dynamical Splayed Ferromagnetic Ground State in the Quantum Spin Ice Yb 2 Sn 2 O 7
journal, March 2013


Gapless quantum excitations from an icelike splayed ferromagnetic ground state in stoichiometric Yb 2 Ti 2 O 7
journal, February 2016


Order induced by dipolar interactions in a geometrically frustrated antiferromagnet
journal, July 2000


Musrfit: A Free Platform-Independent Framework for μSR Data Analysis
journal, January 2012


Dimensional evolution of spin correlations in the magnetic pyrochlore Yb 2 Ti 2 O 7
journal, November 2011


Rods of Neutron Scattering Intensity in Yb 2 Ti 2 O 7 : Compelling Evidence for Significant Anisotropic Exchange in a Magnetic Pyrochlore Oxide
journal, May 2011


The crystal field and exchange interactions in Yb 2 Ti 2 O 7
journal, September 2001


Magnetic ordering in Gd 2 Sn 2 O 7 : the archetypal Heisenberg pyrochlore antiferromagnet
journal, January 2006

  • Wills, A. S.; Zhitomirsky, M. E.; Canals, B.
  • Journal of Physics: Condensed Matter, Vol. 18, Issue 3
  • DOI: 10.1088/0953-8984/18/3/L02

Spin Waves and Quantum Criticality in the Frustrated X Y Pyrochlore Antiferromagnet Er 2 Ti 2 O 7
journal, October 2008


Soft modes in the easy plane pyrochlore antiferromagnet
journal, March 2004


Unconventional magnetic ground state in Yb 2 Ti 2 O 7
journal, October 2013


Anomalous zero-field muon spin relaxation in highly disordered magnets
journal, August 1997


Optical spectroscopy of Yb 2 Ti 2 O 7 and Y 2 Ti 2 O 7 : Yb 3 + and crystal-field parameters in rare-earth titanate pyrochlores
journal, August 2004


Frustration under pressure: Exotic magnetism in new pyrochlore oxides
journal, April 2015


Magnetic pyrochlore oxides
journal, January 2010

  • Gardner, Jason S.; Gingras, Michel J. P.; Greedan, John E.
  • Reviews of Modern Physics, Vol. 82, Issue 1
  • DOI: 10.1103/RevModPhys.82.53

Chemical pressure effects on magnetism in the quantum spin liquid candidates Yb 2 X 2 O 7 ( X = Sn , Ti, Ge)
journal, February 2014


Incipient Ferromagnetism in Tb 2 Ge 2 O 7 : Application of Chemical Pressure to the Enigmatic Spin-Liquid Compound Tb 2 Ti 2 O 7
journal, December 2014


Magnetic order, magnetic correlations, and spin dynamics in the pyrochlore antiferromagnet Er 2 Ti 2 O 7
journal, September 2012


Nd 2 Sn 2 O 7 : An all-in–all-out pyrochlore magnet with no divergence-free field and anomalously slow paramagnetic spin dynamics
journal, October 2015


Order-by-disorder in the X Y pyrochlore antiferromagnet
journal, January 2014


Ferromagnetic Transition of Pyrochlore Compound Yb 2 Ti 2 O 7
journal, November 2003

  • Yasui, Yukio; Soda, Minoru; Iikubo, Satoshi
  • Journal of the Physical Society of Japan, Vol. 72, Issue 11
  • DOI: 10.1143/JPSJ.72.3014

Quantum Excitations in Quantum Spin Ice
journal, October 2011


Ising versus X Y Anisotropy in Frustrated R 2 Ti 2 O 7 Compounds as “Seen” by Polarized Neutrons
journal, July 2009


Static magnetic moments revealed by muon spin relaxation and thermodynamic measurements in the quantum spin ice Yb 2 Ti 2 O 7
journal, May 2014


Direct Evidence for a Dynamical Ground State in the Highly Frustrated Tb 2 Sn 2 O 7 Pyrochlore
journal, September 2006


Spin dynamics in the presence of competing ferromagnetic and antiferromagnetic correlations in Yb 2 Ti 2 O 7
journal, August 2015


Long-range order and spin-liquid states of polycrystalline Tb 2 + x Ti 2 x O 7 + y
journal, February 2013


Spin Dynamics and Magnetic Order in Magnetically Frustrated Tb 2 Sn 2 O 7
journal, March 2006


Quantum spin liquid and electric quadrupolar states of single crystal Tb 2+x Ti 2-x O 7+y
journal, February 2016


Oxide pyrochlores — A review
journal, January 1983

  • Subramanian, M. A.; Aravamudan, G.; Subba Rao, G. V.
  • Progress in Solid State Chemistry, Vol. 15, Issue 2
  • DOI: 10.1016/0079-6786(83)90001-8

Lightly stuffed pyrochlore structure of single-crystalline Yb 2 Ti 2 O 7 grown by the optical floating zone technique
journal, November 2012


Two-Dimensional Kagome Correlations and Field Induced Order in the Ferromagnetic X Y Pyrochlore Yb 2 Ti 2 O 7
journal, November 2009


Magnetic ordering in the XY pyrochlore antiferromagnet Er 2 Ti 2 O 7 : a spherical neutron polarimetry study
journal, October 2007


Higgs transition from a magnetic Coulomb liquid to a ferromagnet in Yb2Ti2O7
journal, January 2012

  • Chang, Lieh-Jeng; Onoda, Shigeki; Su, Yixi
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1989

Crystal field effect and geometric frustration in Er2Ti2O7 —an XY antiferromagnetic pyrochlore
journal, August 2006

  • Dasgupta, Papri; Jana, Yatramohan; Ghosh, Debjani
  • Solid State Communications, Vol. 139, Issue 8
  • DOI: 10.1016/j.ssc.2006.06.030

Order by Disorder Spin Wave Gap in the X Y Pyrochlore Magnet Er 2 Ti 2 O 7
journal, February 2014


Synthesis and atomic structure of pyrochlore-type Yb2Ge2O7 crystals
journal, January 1988

  • Dem'yanets, L. N.; Radaev, S. F.; Mamin, B. F.
  • Journal of Structural Chemistry, Vol. 29, Issue 3
  • DOI: 10.1007/BF00744012

Are Multiphase Competition and Order by Disorder the Keys to Understanding Yb 2 Ti 2 O 7 ?
journal, December 2015


Spin-spin correlations in Yb_{2}Ti_{2}O_{7} : A polarized neutron scattering study
journal, November 2004


Neutron spectroscopic study of crystalline electric field excitations in stoichiometric and lightly stuffed Yb 2 Ti 2 O 7
journal, October 2015


Single-crystal versus polycrystalline samples of magnetically frustrated Yb 2 Ti 2 O 7 : Specific heat results
journal, November 2011


Works referencing / citing this record:

Ground state selection under pressure in the quantum pyrochlore magnet Yb2Ti2O7
journal, March 2017

  • Kermarrec, E.; Gaudet, J.; Fritsch, K.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14810

Tuning the interactions in the spin-ice materials Dy 2 Ge 2 x Si x O 7 by silicon substitution
journal, August 2019


Competing orders in pyrochlore magnets from a Z 2 spin liquid perspective
journal, August 2019


High-Pressure Routes to New Pyrochlores and Novel Magnetism
journal, April 2019


Effect of Chemical Pressure on the Crystal Electric Field States of Erbium Pyrochlore Magnets
text, January 2017


Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.