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Title: Local correlated motions in aqueous solution of sodium chloride

Abstract

Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.

Authors:
ORCiD logo [1];  [1];  [2];  [3];  [4];  [1]
+ Show Author Affiliations
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  2. Oita University, Dannoharu (Japan)
  3. Japan Synchrotron Radiation Research Institute (JASRI), Sayo (Japan)
  4. RIKEN SPring-8 Center, RIKEN, Sayo (Japan)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1528708
Alternate Identifier(s):
OSTI ID: 1546411
Grant/Contract Number:  
AC05-00OR22725; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Volume: 3; Journal Issue: 6; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
59 BASIC BIOLOGICAL SCIENCES; 36 MATERIALS SCIENCE

Citation Formats

Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride. United States: N. p., 2019. Web. doi:10.1103/PhysRevMaterials.3.065604.
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Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., & Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride. United States. doi:10.1103/PhysRevMaterials.3.065604.
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Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Mon . "Local correlated motions in aqueous solution of sodium chloride". United States. doi:10.1103/PhysRevMaterials.3.065604.
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@article{osti_1528708,
title = {Local correlated motions in aqueous solution of sodium chloride},
author = {Shinohara, Yuya and Dmowski, Wojciech and Iwashita, Takuya and Ishikawa, Daisuke and Baron, Alfred Q. R. and Egami, Takeshi},
abstractNote = {Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.},
doi = {10.1103/PhysRevMaterials.3.065604},
journal = {Physical Review Materials},
number = 6,
volume = 3,
place = {United States},
year = {2019},
month = {6}
}
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DOI:  10.1103/PhysRevMaterials.3.065604
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