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Title: Local correlated motions in aqueous solution of sodium chloride

Abstract

Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.

Authors:
ORCiD logo [1];  [1];  [2];  [3];  [4];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  2. Oita University, Dannoharu (Japan)
  3. Japan Synchrotron Radiation Research Institute (JASRI), Sayo (Japan)
  4. RIKEN SPring-8 Center, RIKEN, Sayo (Japan)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1528708
Alternate Identifier(s):
OSTI ID: 1546411
Grant/Contract Number:  
AC05-00OR22725; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Volume: 3; Journal Issue: 6; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
59 BASIC BIOLOGICAL SCIENCES; 36 MATERIALS SCIENCE

Citation Formats

Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride. United States: N. p., 2019. Web. doi:10.1103/PhysRevMaterials.3.065604.
Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., & Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride. United States. doi:10.1103/PhysRevMaterials.3.065604.
Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Mon . "Local correlated motions in aqueous solution of sodium chloride". United States. doi:10.1103/PhysRevMaterials.3.065604.
@article{osti_1528708,
title = {Local correlated motions in aqueous solution of sodium chloride},
author = {Shinohara, Yuya and Dmowski, Wojciech and Iwashita, Takuya and Ishikawa, Daisuke and Baron, Alfred Q. R. and Egami, Takeshi},
abstractNote = {Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.},
doi = {10.1103/PhysRevMaterials.3.065604},
journal = {Physical Review Materials},
number = 6,
volume = 3,
place = {United States},
year = {2019},
month = {6}
}

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Works referenced in this record:

X-ray and neutron scattering studies of the hydration structure of alkali ions in concentrated aqueous solutions
journal, December 2006


Negligible Effect of Ions on the Hydrogen-Bond Structure in Liquid Water
journal, July 2003


New analytical scattering-factor functions for free atoms and ions
journal, May 1995

  • Waasmaier, D.; Kirfel, A.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 51, Issue 3
  • DOI: 10.1107/S0108767394013292

Viscosity of Aqueous Solutions and Local Microscopic Structure
journal, December 2011

  • Corridoni, T.; Mancinelli, R.; Ricci, M. A.
  • The Journal of Physical Chemistry B, Vol. 115, Issue 48
  • DOI: 10.1021/jp202755u

Salt-induced Long-to-Short Range Orientational Transition in Water
journal, June 2018


Self-Diffusion and Viscosity in Electrolyte Solutions
journal, September 2012

  • Kim, Jun Soo; Wu, Zhe; Morrow, Andrew R.
  • The Journal of Physical Chemistry B, Vol. 116, Issue 39
  • DOI: 10.1021/jp306847t

Atomic Dynamics in Simple Liquid: de Gennes Narrowing Revisited
journal, March 2018


Viscosity and real-space molecular motion of water: Observation with inelastic x-ray scattering
journal, August 2018


Coarse-Grained Model of the Dynamics of Electrolyte Solutions
journal, August 2017

  • Andreev, Marat; Chremos, Alexandros; de Pablo, Juan
  • The Journal of Physical Chemistry B, Vol. 121, Issue 34
  • DOI: 10.1021/acs.jpcb.7b04297

Anomalous water diffusion in salt solutions
journal, February 2014

  • Ding, Yun; Hassanali, Ali A.; Parrinello, Michele
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 9
  • DOI: 10.1073/pnas.1400675111

Hydration of Sodium, Potassium, and Chloride Ions in Solution and the Concept of Structure Maker/Breaker
journal, December 2007

  • Mancinelli, R.; Botti, A.; Bruni, F.
  • The Journal of Physical Chemistry B, Vol. 111, Issue 48
  • DOI: 10.1021/jp075913v

Elementary Excitations and Crossover Phenomenon in Liquids
journal, May 2013


Terahertz echoes reveal the inhomogeneity of aqueous salt solutions
journal, October 2016

  • Shalit, Andrey; Ahmed, Saima; Savolainen, Janne
  • Nature Chemistry, Vol. 9, Issue 3
  • DOI: 10.1038/nchem.2642

Structure and dynamics of hydrated ions
journal, May 1993


Sticky ions in biological systems.
journal, June 1995


Dielectric Relaxation of Aqueous NaCl Solutions
journal, January 1999

  • Buchner, Richard; Hefter, Glenn T.; May, Peter M.
  • The Journal of Physical Chemistry A, Vol. 103, Issue 1
  • DOI: 10.1021/jp982977k

The structure of water in the hydration shell of cations from x-ray Raman and small angle x-ray scattering measurements
journal, February 2011

  • Waluyo, Iradwikanari; Huang, Congcong; Nordlund, Dennis
  • The Journal of Chemical Physics, Vol. 134, Issue 6
  • DOI: 10.1063/1.3533958

Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water
journal, April 2016

  • Chen, Yixing; Okur, Halil I.; Gomopoulos, Nikolaos
  • Science Advances, Vol. 2, Issue 4
  • DOI: 10.1126/sciadv.1501891

Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy
journal, January 2017

  • Chen, Yixing; Okur, Halil I.; Liang, Chungwen
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 36
  • DOI: 10.1039/C7CP03395H

A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions
journal, August 1933

  • Bernal, J. D.; Fowler, R. H.
  • The Journal of Chemical Physics, Vol. 1, Issue 8
  • DOI: 10.1063/1.1749327

Effect of high salt concentrations on water structure
journal, November 1995


Anomaly of structural relaxation in complex liquid metal of bismuth - Dynamic correlation function of coherent quasi-elastic neutron scattering
journal, December 2018


Local and Global Effects of Dissolved Sodium Chloride on the Structure of Water
journal, March 2017


Water Dynamics in the Hydration Shells of Biomolecules
journal, March 2017


Watching the Low-Frequency Motions in Aqueous Salt Solutions: The Terahertz Vibrational Signatures of Hydrated Ions
journal, December 2011

  • Funkner, Stefan; Niehues, Gudrun; Schmidt, Diedrich A.
  • Journal of the American Chemical Society, Vol. 134, Issue 2
  • DOI: 10.1021/ja207929u

Mechanisms of Acceleration and Retardation of Water Dynamics by Ions
journal, July 2013

  • Stirnemann, Guillaume; Wernersson, Erik; Jungwirth, Pavel
  • Journal of the American Chemical Society, Vol. 135, Issue 32
  • DOI: 10.1021/ja405201s

Neutron and X–ray scattering studies of hydration in aqueous solutions
journal, August 2001

  • Neilson, G. W.; Mason, P. E.; Ramos, S.
  • Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 359, Issue 1785
  • DOI: 10.1098/rsta.2001.0866

Local Order in Aqueous NaCl Solutions and Pure Water:  X-ray Scattering and Molecular Dynamics Simulations Study
journal, November 2006

  • Bouazizi, Salah; Nasr, Salah; Jaîdane, Nejmeddine
  • The Journal of Physical Chemistry B, Vol. 110, Issue 46
  • DOI: 10.1021/jp0641583

Structural Dynamics of Aqueous Salt Solutions
journal, April 2008


Cooperativity in Ion Hydration
journal, May 2010


How Water’s Properties Are Encoded in Its Molecular Structure and Energies
journal, September 2017

  • Brini, Emiliano; Fennell, Christopher J.; Fernandez-Serra, Marivi
  • Chemical Reviews, Vol. 117, Issue 19
  • DOI: 10.1021/acs.chemrev.7b00259

Influence of Ion Solvation on the Properties of Electrolyte Solutions
journal, April 2018

  • Andreev, Marat; de Pablo, Juan J.; Chremos, Alexandros
  • The Journal of Physical Chemistry B, Vol. 122, Issue 14
  • DOI: 10.1021/acs.jpcb.8b00518

Elementary excitation and energy landscape in simple liquids
journal, June 2014


Proposal for universality in the viscosity of metallic liquids
journal, September 2015

  • Blodgett, M. E.; Egami, T.; Nussinov, Z.
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep13837

Perturbation of water structure due to monovalent ions in solution
journal, January 2007

  • Mancinelli, R.; Botti, A.; Bruni, F.
  • Physical Chemistry Chemical Physics, Vol. 9, Issue 23
  • DOI: 10.1039/b701855j

Dynamics of Water Molecules in Aqueous Solvation Shells
journal, March 2001


How Ions Affect the Structure of Water
journal, October 2002

  • Hribar, Barbara; Southall, Noel T.; Vlachy, Vojko
  • Journal of the American Chemical Society, Vol. 124, Issue 41
  • DOI: 10.1021/ja026014h

Seeing real-space dynamics of liquid water through inelastic x-ray scattering
journal, December 2017


Viscosity B-Coefficients of Ions in Solution
journal, December 1995

  • Jenkins, H. Donald B.; Marcus, Yizhak.
  • Chemical Reviews, Vol. 95, Issue 8
  • DOI: 10.1021/cr00040a004

Effect of Ions on the Structure of Water: Structure Making and Breaking
journal, March 2009


Chemical binding and electron correlation effects in x‐ray and high energy electron scattering
journal, September 1994

  • Wang, Jiahu; Tripathi, Awadh N.; Smith, Vedene H.
  • The Journal of Chemical Physics, Vol. 101, Issue 6
  • DOI: 10.1063/1.467407

Vibrational Spectroscopy and Dynamics of Water
journal, April 2016


The Viscosity of Aqueous Solutions of Strong Electrolytes with Special Reference to Barium Chloride
journal, October 1929

  • Jones, Grinnell; Dole, Malcolm
  • Journal of the American Chemical Society, Vol. 51, Issue 10
  • DOI: 10.1021/ja01385a012