Local correlated motions in aqueous solution of sodium chloride

Shinohara, Yuya; Dmowski, Wojciech; Iwashita, Takuya; Ishikawa, Daisuke; Baron, Alfred Q. R.; Egami, Takeshi

doi:10.1103/PhysRevMaterials.3.065604

Title: Local correlated motions in aqueous solution of sodium chloride

Journal Article · 17 June 2019 · Physical Review Materials

DOI: https://doi.org/10.1103/PhysRevMaterials.3.065604 · OSTI ID:1528708

^[1]; Dmowski, Wojciech ^[1]; Iwashita, Takuya ^[2]; Ishikawa, Daisuke ^[3]; Baron, Alfred Q. R. ^[4]; Egami, Takeshi ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oita University, Dannoharu (Japan)
Japan Synchrotron Radiation Research Institute (JASRI), Sayo (Japan)
RIKEN SPring-8 Center, RIKEN, Sayo (Japan)

Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1528708

Alternate ID(s):: OSTI ID: 1546411

Journal Information:: Physical Review Materials, Vol. 3, Issue 6; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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