Local correlated motions in aqueous solution of sodium chloride
Abstract
Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oita University, Dannoharu (Japan)
- Japan Synchrotron Radiation Research Institute (JASRI), Sayo (Japan)
- RIKEN SPring-8 Center, RIKEN, Sayo (Japan)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1528708
- Alternate Identifier(s):
- OSTI ID: 1546411
- Grant/Contract Number:
- AC05-00OR22725; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Materials
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 6; Journal ID: ISSN 2475-9953
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 59 BASIC BIOLOGICAL SCIENCES; 36 MATERIALS SCIENCE
Citation Formats
Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride. United States: N. p., 2019.
Web. doi:10.1103/PhysRevMaterials.3.065604.
Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., & Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride. United States. https://doi.org/10.1103/PhysRevMaterials.3.065604
Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Mon .
"Local correlated motions in aqueous solution of sodium chloride". United States. https://doi.org/10.1103/PhysRevMaterials.3.065604. https://www.osti.gov/servlets/purl/1528708.
@article{osti_1528708,
title = {Local correlated motions in aqueous solution of sodium chloride},
author = {Shinohara, Yuya and Dmowski, Wojciech and Iwashita, Takuya and Ishikawa, Daisuke and Baron, Alfred Q. R. and Egami, Takeshi},
abstractNote = {Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.},
doi = {10.1103/PhysRevMaterials.3.065604},
journal = {Physical Review Materials},
number = 6,
volume = 3,
place = {United States},
year = {2019},
month = {6}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 2 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
X-ray and neutron scattering studies of the hydration structure of alkali ions in concentrated aqueous solutions
journal, December 2006
- Ansell, S.; Barnes, A. C.; Mason, P. E.
- Biophysical Chemistry, Vol. 124, Issue 3
Negligible Effect of Ions on the Hydrogen-Bond Structure in Liquid Water
journal, July 2003
- Omta, A. W.
- Science, Vol. 301, Issue 5631
New analytical scattering-factor functions for free atoms and ions
journal, May 1995
- Waasmaier, D.; Kirfel, A.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 51, Issue 3
Viscosity of Aqueous Solutions and Local Microscopic Structure
journal, December 2011
- Corridoni, T.; Mancinelli, R.; Ricci, M. A.
- The Journal of Physical Chemistry B, Vol. 115, Issue 48
Salt-induced Long-to-Short Range Orientational Transition in Water
journal, June 2018
- Duboisset, Julien; Brevet, Pierre-François
- Physical Review Letters, Vol. 120, Issue 26
Self-Diffusion and Viscosity in Electrolyte Solutions
journal, September 2012
- Kim, Jun Soo; Wu, Zhe; Morrow, Andrew R.
- The Journal of Physical Chemistry B, Vol. 116, Issue 39
Atomic Dynamics in Simple Liquid: de Gennes Narrowing Revisited
journal, March 2018
- Wu, Bin; Iwashita, Takuya; Egami, Takeshi
- Physical Review Letters, Vol. 120, Issue 13
Viscosity and real-space molecular motion of water: Observation with inelastic x-ray scattering
journal, August 2018
- Shinohara, Yuya; Dmowski, Wojciech; Iwashita, Takuya
- Physical Review E, Vol. 98, Issue 2
Coarse-Grained Model of the Dynamics of Electrolyte Solutions
journal, August 2017
- Andreev, Marat; Chremos, Alexandros; de Pablo, Juan
- The Journal of Physical Chemistry B, Vol. 121, Issue 34
Anomalous water diffusion in salt solutions
journal, February 2014
- Ding, Yun; Hassanali, Ali A.; Parrinello, Michele
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 9
Molecular dynamics simulations of aqueous NaCl and KCl solutions: Effects of ion concentration on the single-particle, pair, and collective dynamical properties of ions and water molecules
journal, August 2001
- Chowdhuri, Snehasis; Chandra, Amalendu
- The Journal of Chemical Physics, Vol. 115, Issue 8
Hydration of Sodium, Potassium, and Chloride Ions in Solution and the Concept of Structure Maker/Breaker
journal, December 2007
- Mancinelli, R.; Botti, A.; Bruni, F.
- The Journal of Physical Chemistry B, Vol. 111, Issue 48
Elementary Excitations and Crossover Phenomenon in Liquids
journal, May 2013
- Iwashita, T.; Nicholson, D. M.; Egami, T.
- Physical Review Letters, Vol. 110, Issue 20
Terahertz echoes reveal the inhomogeneity of aqueous salt solutions
journal, October 2016
- Shalit, Andrey; Ahmed, Saima; Savolainen, Janne
- Nature Chemistry, Vol. 9, Issue 3
Structure and dynamics of hydrated ions
journal, May 1993
- Ohtaki, Hitoshi.; Radnai, Tamas.
- Chemical Reviews, Vol. 93, Issue 3
Sticky ions in biological systems.
journal, June 1995
- Collins, K. D.
- Proceedings of the National Academy of Sciences, Vol. 92, Issue 12
Dielectric Relaxation of Aqueous NaCl Solutions
journal, January 1999
- Buchner, Richard; Hefter, Glenn T.; May, Peter M.
- The Journal of Physical Chemistry A, Vol. 103, Issue 1
The structure of water in the hydration shell of cations from x-ray Raman and small angle x-ray scattering measurements
journal, February 2011
- Waluyo, Iradwikanari; Huang, Congcong; Nordlund, Dennis
- The Journal of Chemical Physics, Vol. 134, Issue 6
Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water
journal, April 2016
- Chen, Yixing; Okur, Halil I.; Gomopoulos, Nikolaos
- Science Advances, Vol. 2, Issue 4
Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy
journal, January 2017
- Chen, Yixing; Okur, Halil I.; Liang, Chungwen
- Physical Chemistry Chemical Physics, Vol. 19, Issue 36
A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions
journal, August 1933
- Bernal, J. D.; Fowler, R. H.
- The Journal of Chemical Physics, Vol. 1, Issue 8
Effect of high salt concentrations on water structure
journal, November 1995
- Leberman, R.; Soper, A. K.
- Nature, Vol. 378, Issue 6555
Anomaly of structural relaxation in complex liquid metal of bismuth - Dynamic correlation function of coherent quasi-elastic neutron scattering
journal, December 2018
- Kawakita, Yukinobu; Kikuchi, Tatsuya; Inamura, Yasuhiro
- Physica B: Condensed Matter, Vol. 551
Local and Global Effects of Dissolved Sodium Chloride on the Structure of Water
journal, March 2017
- Gaiduk, Alex P.; Galli, Giulia
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 7
Water Dynamics in the Hydration Shells of Biomolecules
journal, March 2017
- Laage, Damien; Elsaesser, Thomas; Hynes, James T.
- Chemical Reviews, Vol. 117, Issue 16
Watching the Low-Frequency Motions in Aqueous Salt Solutions: The Terahertz Vibrational Signatures of Hydrated Ions
journal, December 2011
- Funkner, Stefan; Niehues, Gudrun; Schmidt, Diedrich A.
- Journal of the American Chemical Society, Vol. 134, Issue 2
Mechanisms of Acceleration and Retardation of Water Dynamics by Ions
journal, July 2013
- Stirnemann, Guillaume; Wernersson, Erik; Jungwirth, Pavel
- Journal of the American Chemical Society, Vol. 135, Issue 32
Neutron and X–ray scattering studies of hydration in aqueous solutions
journal, August 2001
- Neilson, G. W.; Mason, P. E.; Ramos, S.
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 359, Issue 1785
Local Order in Aqueous NaCl Solutions and Pure Water: X-ray Scattering and Molecular Dynamics Simulations Study
journal, November 2006
- Bouazizi, Salah; Nasr, Salah; Jaîdane, Nejmeddine
- The Journal of Physical Chemistry B, Vol. 110, Issue 46
Structural Dynamics of Aqueous Salt Solutions
journal, April 2008
- Bakker, H. J.
- Chemical Reviews, Vol. 108, Issue 4
Cooperativity in Ion Hydration
journal, May 2010
- Tielrooij, K. J.; Garcia-Araez, N.; Bonn, M.
- Science, Vol. 328, Issue 5981
How Water’s Properties Are Encoded in Its Molecular Structure and Energies
journal, September 2017
- Brini, Emiliano; Fennell, Christopher J.; Fernandez-Serra, Marivi
- Chemical Reviews, Vol. 117, Issue 19
Influence of Ion Solvation on the Properties of Electrolyte Solutions
journal, April 2018
- Andreev, Marat; de Pablo, Juan J.; Chremos, Alexandros
- The Journal of Physical Chemistry B, Vol. 122, Issue 14
Elementary excitation and energy landscape in simple liquids
journal, June 2014
- Egami, T.
- Modern Physics Letters B, Vol. 28, Issue 14
Proposal for universality in the viscosity of metallic liquids
journal, September 2015
- Blodgett, M. E.; Egami, T.; Nussinov, Z.
- Scientific Reports, Vol. 5, Issue 1
Perturbation of water structure due to monovalent ions in solution
journal, January 2007
- Mancinelli, R.; Botti, A.; Bruni, F.
- Physical Chemistry Chemical Physics, Vol. 9, Issue 23
Dynamics of Water Molecules in Aqueous Solvation Shells
journal, March 2001
- Kropman, M. F.
- Science, Vol. 291, Issue 5511
How Ions Affect the Structure of Water
journal, October 2002
- Hribar, Barbara; Southall, Noel T.; Vlachy, Vojko
- Journal of the American Chemical Society, Vol. 124, Issue 41
Seeing real-space dynamics of liquid water through inelastic x-ray scattering
journal, December 2017
- Iwashita, Takuya; Wu, Bin; Chen, Wei-Ren
- Science Advances, Vol. 3, Issue 12
Correlations in Space and Time and Born Approximation Scattering in Systems of Interacting Particles
journal, July 1954
- Van Hove, Léon
- Physical Review, Vol. 95, Issue 1
Viscosity B-Coefficients of Ions in Solution
journal, December 1995
- Jenkins, H. Donald B.; Marcus, Yizhak.
- Chemical Reviews, Vol. 95, Issue 8
Effect of Ions on the Structure of Water: Structure Making and Breaking
journal, March 2009
- Marcus, Yizhak
- Chemical Reviews, Vol. 109, Issue 3
Chemical binding and electron correlation effects in x‐ray and high energy electron scattering
journal, September 1994
- Wang, Jiahu; Tripathi, Awadh N.; Smith, Vedene H.
- The Journal of Chemical Physics, Vol. 101, Issue 6
Vibrational Spectroscopy and Dynamics of Water
journal, April 2016
- Perakis, Fivos; De Marco, Luigi; Shalit, Andrey
- Chemical Reviews, Vol. 116, Issue 13
The Viscosity of Aqueous Solutions of Strong Electrolytes with Special Reference to Barium Chloride
journal, October 1929
- Jones, Grinnell; Dole, Malcolm
- Journal of the American Chemical Society, Vol. 51, Issue 10