Local correlated motions in aqueous solution of sodium chloride

doi:10.1103/PhysRevMaterials.3.065604

Title: Local correlated motions in aqueous solution of sodium chloride

Abstract

Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.

Authors:

^[1]; Dmowski, Wojciech ^[1]; Iwashita, Takuya ^[2]; Ishikawa, Daisuke ^[3]; Baron, Alfred Q. R. ^[4]; Egami, Takeshi ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oita University, Dannoharu (Japan)
Japan Synchrotron Radiation Research Institute (JASRI), Sayo (Japan)
RIKEN SPring-8 Center, RIKEN, Sayo (Japan)

Publication Date:: 2019-06-17

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1528708

Alternate Identifier(s):: OSTI ID: 1546411

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Materials

Additional Journal Information:: Journal Volume: 3; Journal Issue: 6; Journal ID: ISSN 2475-9953

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 59 BASIC BIOLOGICAL SCIENCES; 36 MATERIALS SCIENCE

Citation Formats


                    Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride.  United States: N. p., 2019. 
        Web.  doi:10.1103/PhysRevMaterials.3.065604.

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                    Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., & Egami, Takeshi. Local correlated motions in aqueous solution of sodium chloride.  United States.  doi:https://doi.org/10.1103/PhysRevMaterials.3.065604

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                    Shinohara, Yuya, Dmowski, Wojciech, Iwashita, Takuya, Ishikawa, Daisuke, Baron, Alfred Q. R., and Egami, Takeshi. Mon .  
        "Local correlated motions in aqueous solution of sodium chloride".  United States.  doi:https://doi.org/10.1103/PhysRevMaterials.3.065604.  https://www.osti.gov/servlets/purl/1528708.

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@article{osti_1528708,

  title        = {Local correlated motions in aqueous solution of sodium chloride},

  author       = {Shinohara, Yuya and Dmowski, Wojciech and Iwashita, Takuya and Ishikawa, Daisuke and Baron, Alfred Q. R. and Egami, Takeshi},

  abstractNote = {Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. In this study, we focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.},

  doi          = {10.1103/PhysRevMaterials.3.065604},

  journal      = {Physical Review Materials},

  number       = 6,

  volume       = 3,

  place        = {United States},

  year         = {2019},

  month        = {6}

}

Copy to clipboard

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DOI: https://doi.org/10.1103/PhysRevMaterials.3.065604

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Title: Local correlated motions in aqueous solution of sodium chloride

Abstract

Citation Formats

X-ray and neutron scattering studies of the hydration structure of alkali ions in concentrated aqueous solutions journal, December 2006

Negligible Effect of Ions on the Hydrogen-Bond Structure in Liquid Water journal, July 2003

New analytical scattering-factor functions for free atoms and ions journal, May 1995

Viscosity of Aqueous Solutions and Local Microscopic Structure journal, December 2011

Salt-induced Long-to-Short Range Orientational Transition in Water journal, June 2018

Self-Diffusion and Viscosity in Electrolyte Solutions journal, September 2012

Atomic Dynamics in Simple Liquid: de Gennes Narrowing Revisited journal, March 2018

Viscosity and real-space molecular motion of water: Observation with inelastic x-ray scattering journal, August 2018

Coarse-Grained Model of the Dynamics of Electrolyte Solutions journal, August 2017

Anomalous water diffusion in salt solutions journal, February 2014

Molecular dynamics simulations of aqueous NaCl and KCl solutions: Effects of ion concentration on the single-particle, pair, and collective dynamical properties of ions and water molecules journal, August 2001

Hydration of Sodium, Potassium, and Chloride Ions in Solution and the Concept of Structure Maker/Breaker journal, December 2007

Elementary Excitations and Crossover Phenomenon in Liquids journal, May 2013

Terahertz echoes reveal the inhomogeneity of aqueous salt solutions journal, October 2016

Structure and dynamics of hydrated ions journal, May 1993

Sticky ions in biological systems. journal, June 1995

Dielectric Relaxation of Aqueous NaCl Solutions journal, January 1999

The structure of water in the hydration shell of cations from x-ray Raman and small angle x-ray scattering measurements journal, February 2011

Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water journal, April 2016

Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy journal, January 2017

A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions journal, August 1933

Effect of high salt concentrations on water structure journal, November 1995

Anomaly of structural relaxation in complex liquid metal of bismuth - Dynamic correlation function of coherent quasi-elastic neutron scattering journal, December 2018

Local and Global Effects of Dissolved Sodium Chloride on the Structure of Water journal, March 2017

Water Dynamics in the Hydration Shells of Biomolecules journal, March 2017

Watching the Low-Frequency Motions in Aqueous Salt Solutions: The Terahertz Vibrational Signatures of Hydrated Ions journal, December 2011

Mechanisms of Acceleration and Retardation of Water Dynamics by Ions journal, July 2013

Neutron and X–ray scattering studies of hydration in aqueous solutions journal, August 2001

Local Order in Aqueous NaCl Solutions and Pure Water: X-ray Scattering and Molecular Dynamics Simulations Study journal, November 2006

Structural Dynamics of Aqueous Salt Solutions journal, April 2008

Cooperativity in Ion Hydration journal, May 2010

How Water’s Properties Are Encoded in Its Molecular Structure and Energies journal, September 2017

Influence of Ion Solvation on the Properties of Electrolyte Solutions journal, April 2018

Elementary excitation and energy landscape in simple liquids journal, June 2014

Proposal for universality in the viscosity of metallic liquids journal, September 2015

Perturbation of water structure due to monovalent ions in solution journal, January 2007

Dynamics of Water Molecules in Aqueous Solvation Shells journal, March 2001

How Ions Affect the Structure of Water journal, October 2002

Seeing real-space dynamics of liquid water through inelastic x-ray scattering journal, December 2017

Correlations in Space and Time and Born Approximation Scattering in Systems of Interacting Particles journal, July 1954

Viscosity B-Coefficients of Ions in Solution journal, December 1995

Effect of Ions on the Structure of Water: Structure Making and Breaking journal, March 2009

Chemical binding and electron correlation effects in x‐ray and high energy electron scattering journal, September 1994

Vibrational Spectroscopy and Dynamics of Water journal, April 2016

The Viscosity of Aqueous Solutions of Strong Electrolytes with Special Reference to Barium Chloride journal, October 1929

X-ray and neutron scattering studies of the hydration structure of alkali ions in concentrated aqueous solutions
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Negligible Effect of Ions on the Hydrogen-Bond Structure in Liquid Water
journal, July 2003

New analytical scattering-factor functions for free atoms and ions
journal, May 1995

Viscosity of Aqueous Solutions and Local Microscopic Structure
journal, December 2011

Salt-induced Long-to-Short Range Orientational Transition in Water
journal, June 2018

Self-Diffusion and Viscosity in Electrolyte Solutions
journal, September 2012

Atomic Dynamics in Simple Liquid: de Gennes Narrowing Revisited
journal, March 2018

Viscosity and real-space molecular motion of water: Observation with inelastic x-ray scattering
journal, August 2018

Coarse-Grained Model of the Dynamics of Electrolyte Solutions
journal, August 2017

Anomalous water diffusion in salt solutions
journal, February 2014

Molecular dynamics simulations of aqueous NaCl and KCl solutions: Effects of ion concentration on the single-particle, pair, and collective dynamical properties of ions and water molecules
journal, August 2001

Hydration of Sodium, Potassium, and Chloride Ions in Solution and the Concept of Structure Maker/Breaker
journal, December 2007

Elementary Excitations and Crossover Phenomenon in Liquids
journal, May 2013

Terahertz echoes reveal the inhomogeneity of aqueous salt solutions
journal, October 2016

Structure and dynamics of hydrated ions
journal, May 1993

Sticky ions in biological systems.
journal, June 1995

Dielectric Relaxation of Aqueous NaCl Solutions
journal, January 1999

The structure of water in the hydration shell of cations from x-ray Raman and small angle x-ray scattering measurements
journal, February 2011

Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water
journal, April 2016

Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy
journal, January 2017

A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions
journal, August 1933

Effect of high salt concentrations on water structure
journal, November 1995

Anomaly of structural relaxation in complex liquid metal of bismuth - Dynamic correlation function of coherent quasi-elastic neutron scattering
journal, December 2018

Local and Global Effects of Dissolved Sodium Chloride on the Structure of Water
journal, March 2017

Water Dynamics in the Hydration Shells of Biomolecules
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Watching the Low-Frequency Motions in Aqueous Salt Solutions: The Terahertz Vibrational Signatures of Hydrated Ions
journal, December 2011

Mechanisms of Acceleration and Retardation of Water Dynamics by Ions
journal, July 2013

Neutron and X–ray scattering studies of hydration in aqueous solutions
journal, August 2001

Local Order in Aqueous NaCl Solutions and Pure Water: X-ray Scattering and Molecular Dynamics Simulations Study
journal, November 2006

Structural Dynamics of Aqueous Salt Solutions
journal, April 2008

Cooperativity in Ion Hydration
journal, May 2010

How Water’s Properties Are Encoded in Its Molecular Structure and Energies
journal, September 2017

Influence of Ion Solvation on the Properties of Electrolyte Solutions
journal, April 2018

Elementary excitation and energy landscape in simple liquids
journal, June 2014

Proposal for universality in the viscosity of metallic liquids
journal, September 2015

Perturbation of water structure due to monovalent ions in solution
journal, January 2007

Dynamics of Water Molecules in Aqueous Solvation Shells
journal, March 2001

How Ions Affect the Structure of Water
journal, October 2002

Seeing real-space dynamics of liquid water through inelastic x-ray scattering
journal, December 2017

Correlations in Space and Time and Born Approximation Scattering in Systems of Interacting Particles
journal, July 1954

Viscosity B-Coefficients of Ions in Solution
journal, December 1995

Effect of Ions on the Structure of Water: Structure Making and Breaking
journal, March 2009

Chemical binding and electron correlation effects in x‐ray and high energy electron scattering
journal, September 1994

Vibrational Spectroscopy and Dynamics of Water
journal, April 2016

The Viscosity of Aqueous Solutions of Strong Electrolytes with Special Reference to Barium Chloride
journal, October 1929