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Title: Redox chemistry of CeO 2 nanoparticles in aquatic systems containing Cr( vi )(aq) and Fe 2+ ions

Journal Article · · Environmental Science: Nano
DOI: https://doi.org/10.1039/C9EN00201D · OSTI ID:1528656

CeO 2 nanoparticles are extensively used in industrial applications owing to their high redox-catalytic activities and, as a result, may appear in aquatic environments where they undergo significant surface chemistry transformation with other redox-active species.

Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-94ER14466
OSTI ID:
1528656
Journal Information:
Environmental Science: Nano, Journal Name: Environmental Science: Nano Vol. 6 Journal Issue: 7; ISSN 2051-8153
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

References (67)

Effects of Fe2+ concentration on biomass accumulation and energy metabolism in photosynthetic bacteria wastewater treatment journal September 2012
The High temperature oxidation of iron-chromium alloys containing 0.1 wt. % cerium or cerium oxide journal February 1987
Reactivity of Fe(II) Species Associated with Clay Minerals journal February 2003
X-ray Absorption Spectroscopy (XAS) Corroboration of the Uptake and Storage of CeO 2 Nanoparticles and Assessment of Their Differential Toxicity in Four Edible Plant Species
  • López-Moreno, Martha L.; de la Rosa, Guadalupe; Hernández-Viezcas, José A.
  • Journal of Agricultural and Food Chemistry, Vol. 58, Issue 6 https://doi.org/10.1021/jf904472e
journal March 2010
Processing of leather waste: pilot scale studies on chrome shavings. Isolation of potentially valuable protein products and chromium journal June 1998
Cerium Dioxide Nanoparticles Induce Apoptosis and Autophagy in Human Peripheral Blood Monocytes journal June 2012
Solubility of Nanocrystalline Cerium Dioxide: Experimental Data and Thermodynamic Modeling journal September 2016
Importance of H2O2/Fe2+ ratio in Fenton's treatment of a carpet dyeing wastewater journal August 2006
Metal-loaded CeO2-ZrO2 solid solutions as innovative catalysts for automotive catalytic converters journal May 1996
Preparing an active cerium oxide catalyst for the catalytic incineration of aromatic hydrocarbons journal August 2004
Chromium sorption and Cr(VI) reduction to Cr(III) by grape stalks and yohimbe bark journal July 2008
A kinetic study on the degradation of p-nitroaniline by Fenton oxidation process journal September 2007
Chromate removal from aqueous wastes by reduction with ferrous ion journal August 1988
RO membrane removal of unreacted chromium from spent tanning effluent. A pilot-scale study, Part 2 journal September 2002
Genesis of hexavalent chromium from natural sources in soil and groundwater journal April 2007
Electron inelastic mean free paths in cerium dioxide journal June 2015
The Influence of Ferrous/Ferric Ions on the Efficiency of Photocatalytic Oxidation of Pollutants in Groundwater journal June 2005
Electrochemical studies on diffusion and redox behavior of various metal ions in some molten glasses journal May 1980
Advanced oxidation of acid and reactive dyes: Effect of Fenton treatment on aerobic, anoxic and anaerobic processes journal August 2008
The potential of compost-based biobarriers for Cr(VI) removal from contaminated groundwater: Column test journal July 2009
Natural hexavalent chromium in groundwaters interacting with ophiolitic rocks journal November 2002
Fate and Effects of CeO 2 Nanoparticles in Aquatic Ecotoxicity Tests journal June 2009
The effect of oxygen fugacity, melt composition, temperature and pressure on the oxidation state of cerium in silicate melts journal February 2014
Oxidative stress of CeO2 nanoparticles via p38-Nrf-2 signaling pathway in human bronchial epithelial cell, Beas-2B journal June 2009
Application of Ce(IV) in industrial wastewater treatment journal December 2010
Reactivity of Fe(II)-Bearing Minerals toward Reductive Transformation of Organic Contaminants journal February 2004
Comparison of different treatment strategies for industrial landfill leachate journal March 2009
Cerium oxide nanoparticles: Size-selective formation and structure analysis journal January 2002
Quantitative aspects of contact allergy to chromium and exposure to chrome-tanned leather journal September 2002
Comparison of different advanced oxidation processes for phenol degradation journal February 2002
The effect of Fe2+, Fe3+, H2O2 and the photo-Fenton reagent at near neutral pH on the solar disinfection (SODIS) at low temperatures of water containing Escherichia coli K12 journal April 2010
Cerium oxide nanoparticle: a remarkably versatile rare earth nanomaterial for biological applications journal March 2014
CeO 2 nanoparticles induce DNA damage towards human dermal fibroblasts in vitro journal January 2009
Pseudo-Single-Crystal Electrochemistry on Polycrystalline Electrodes: Visualizing Activity at Grains and Grain Boundaries on Platinum for the Fe 2+ /Fe 3+ Redox Reaction journal February 2013
A consistent method for quantitative XPS peak analysis of thin oxide films on clean polycrystalline iron surfaces journal September 1997
Aqueous geochemistry of chromium: A review journal July 1991
Ion chromatography of organic-rich natural waters from peatlands V. Fe2+ and Fe3+ journal July 1995
Structural and compositional evolution of Cr/Fe solids after indirect chromate reduction by dissimilatory iron-reducing bacteria journal February 2003
The effect of pH on the kinetics of spontaneous Fe(II) oxidation by O2 in aqueous solution – basic principles and a simple heuristic description journal August 2007
Palaeo-hydrogeological control on groundwater As levels in Red River delta, Vietnam journal November 2008
Hazard and Risk Assessment of a Nanoparticulate Cerium Oxide-Based Diesel Fuel Additive—A Case Study journal January 2008
Improvement in the oxidation behavior of austenitic stainless steels by superficially applied, cerium oxide coatings journal February 1994
Enhanced Colloidal Stability of CeO 2 Nanoparticles by Ferrous Ions: Adsorption, Redox Reaction, and Surface Precipitation journal April 2015
Advanced oxidation of phenol: A comparison between Fenton, electro-Fenton, sono-electro-Fenton and photo-electro-Fenton processes journal February 2012
Continuous hydrothermal processing of nano-crystalline particulates for chemical-mechanical planarization journal October 1998
Reduction of hexavalent chromium by ferrous iron journal June 1997
Behavior of Hexavalent Chromium in a Polluted Groundwater:  Redox Processes and Immobilization in Soils journal April 2001
Soil organic matter influences cerium translocation and physiological processes in kidney bean plants exposed to cerium oxide nanoparticles journal November 2016
Effect of electron donor source on the treatment of Cr(VI)-containing textile wastewater using sulfate-reducing fluidized bed reactors (FBRs) journal April 2013
An overview for the utilization of wastes from stainless steel industries journal June 2011
The biological effects of subacute inhalation of diesel exhaust following addition of cerium oxide nanoparticles in atherosclerosis-prone mice journal May 2012
Atomic force microscopy study of the role of molecular weight of poly(acrylic acid) in chemical mechanical planarization for shallow trench isolation journal February 2006
Temperature-Dependent Reduction of Epitaxial Ce 1– x Pr x O 2−δ ( x = 0–1) Thin Films on Si(111): A Combined Temperature-Programmed Desorption, X-ray Diffraction, X-ray Photoelectron Spectroscopy, and Raman Study journal November 2013
Chromium speciation in solid matrices and regulation: a review journal January 2010
Toxicity Assessment of Cerium Oxide Nanoparticles in Cilantro ( Coriandrum sativum L.) Plants Grown in Organic Soil
  • Morales, Maria Isabel; Rico, Cyren M.; Hernandez-Viezcas, Jose Angel
  • Journal of Agricultural and Food Chemistry, Vol. 61, Issue 26 https://doi.org/10.1021/jf401628v
journal June 2013
Occurrences, Uses, and Properties of Chromium journal August 1997
Metal tolerance and sequestration of Ni(II), Zn(II) and Cr(VI) ions from simulated and electroplating wastewater in batch process: Kinetics and equilibrium study journal January 2012
Ce 3+ Ions Determine Redox-Dependent Anti-apoptotic Effect of Cerium Oxide Nanoparticles journal May 2011
The reactivity of Fe(II) associated with goethite formed during short redox cycles toward Cr(VI) reduction under oxic conditions journal August 2017
Removal of Oxide Nanoparticles in a Model Wastewater Treatment Plant: Influence of Agglomeration and Surfactants on Clearing Efficiency journal August 2008
Natural Occurrence of Hexavalent Chromium in the Aromas Red Sands Aquifer, California journal August 2005
Chromium Isotopes and the Fate of Hexavalent Chromium in the Environment journal March 2002
Treatment of iron and manganese in simulated groundwater via ozone technology journal December 2009
Spectroscopic Evidence for Fe(II)−Fe(III) Electron Transfer at the Iron Oxide−Water Interface journal September 2004
Investigation of phosphate adsorption onto ferrihydrite by X-ray Photoelectron Spectroscopy journal October 2013
Differential redox and sorption of Cr (III/VI) on natural silicate and oxide minerals: EXAFS and XANES results journal August 1997
Remediation Options for the Treatment of Electroplating and Leather Tanning Effluent Containing Chromium—A Review journal April 2006