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Title: Redox chemistry of CeO 2 nanoparticles in aquatic systems containing Cr( vi )(aq) and Fe 2+ ions

Abstract

CeO 2 nanoparticles are extensively used in industrial applications owing to their high redox-catalytic activities and, as a result, may appear in aquatic environments where they undergo significant surface chemistry transformation with other redox-active species.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
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  1. Department of Energy, Environmental & Chemical Engineering, Washington University in St. Louis, St. Louis, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1528656
Grant/Contract Number:  
FG02-94ER14466
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Environmental Science: Nano
Additional Journal Information:
Journal Name: Environmental Science: Nano Journal Volume: 6 Journal Issue: 7; Journal ID: ISSN 2051-8153
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Ray, Jessica R., Wu, Xuanhao, Neil, Chelsea W., Jung, Haesung, Li, Zhichao, and Jun, Young-Shin. Redox chemistry of CeO 2 nanoparticles in aquatic systems containing Cr( vi )(aq) and Fe 2+ ions. United Kingdom: N. p., 2019. Web. doi:10.1039/C9EN00201D.
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Ray, Jessica R., Wu, Xuanhao, Neil, Chelsea W., Jung, Haesung, Li, Zhichao, & Jun, Young-Shin. Redox chemistry of CeO 2 nanoparticles in aquatic systems containing Cr( vi )(aq) and Fe 2+ ions. United Kingdom. https://doi.org/10.1039/C9EN00201D
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Ray, Jessica R., Wu, Xuanhao, Neil, Chelsea W., Jung, Haesung, Li, Zhichao, and Jun, Young-Shin. Thu . "Redox chemistry of CeO 2 nanoparticles in aquatic systems containing Cr( vi )(aq) and Fe 2+ ions". United Kingdom. https://doi.org/10.1039/C9EN00201D.
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@article{osti_1528656,
title = {Redox chemistry of CeO 2 nanoparticles in aquatic systems containing Cr( vi )(aq) and Fe 2+ ions},
author = {Ray, Jessica R. and Wu, Xuanhao and Neil, Chelsea W. and Jung, Haesung and Li, Zhichao and Jun, Young-Shin},
abstractNote = {CeO 2 nanoparticles are extensively used in industrial applications owing to their high redox-catalytic activities and, as a result, may appear in aquatic environments where they undergo significant surface chemistry transformation with other redox-active species.},
doi = {10.1039/C9EN00201D},
journal = {Environmental Science: Nano},
number = 7,
volume = 6,
place = {United Kingdom},
year = {2019},
month = {7}
}
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Journal Article:
Free Publicly Available Full Text
Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1039/C9EN00201D
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Works referenced in this record:

Effects of Fe2+ concentration on biomass accumulation and energy metabolism in photosynthetic bacteria wastewater treatment
journal, September 2012

The High temperature oxidation of iron-chromium alloys containing 0.1 wt. % cerium or cerium oxide
journal, February 1987

  • Rhys-Jones, T. N.; Grabke, H. J.; Kudielka, H.
  • Materials and Corrosion/Werkstoffe und Korrosion, Vol. 38, Issue 2
  • DOI: 10.1002/maco.19870380203

Reactivity of Fe(II) Species Associated with Clay Minerals
journal, February 2003

  • Hofstetter, Thomas B.; Schwarzenbach, René P.; Haderlein, Stefan B.
  • Environmental Science & Technology, Vol. 37, Issue 3
  • DOI: 10.1021/es025955r

X-ray Absorption Spectroscopy (XAS) Corroboration of the Uptake and Storage of CeO 2 Nanoparticles and Assessment of Their Differential Toxicity in Four Edible Plant Species
journal, March 2010

  • López-Moreno, Martha L.; de la Rosa, Guadalupe; Hernández-Viezcas, José A.
  • Journal of Agricultural and Food Chemistry, Vol. 58, Issue 6
  • DOI: 10.1021/jf904472e

Cerium Dioxide Nanoparticles Induce Apoptosis and Autophagy in Human Peripheral Blood Monocytes
journal, June 2012

  • Hussain, Salik; Al-Nsour, Faris; Rice, Annette B.
  • ACS Nano, Vol. 6, Issue 7
  • DOI: 10.1021/nn302235u

Solubility of Nanocrystalline Cerium Dioxide: Experimental Data and Thermodynamic Modeling
journal, September 2016

  • Plakhova, Tatiana V.; Romanchuk, Anna Yu.; Yakunin, Sergey N.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 39
  • DOI: 10.1021/acs.jpcc.6b05650

Importance of H2O2/Fe2+ ratio in Fenton's treatment of a carpet dyeing wastewater
journal, August 2006

Metal-loaded CeO2-ZrO2 solid solutions as innovative catalysts for automotive catalytic converters
journal, May 1996

Preparing an active cerium oxide catalyst for the catalytic incineration of aromatic hydrocarbons
journal, August 2004

Chromium sorption and Cr(VI) reduction to Cr(III) by grape stalks and yohimbe bark
journal, July 2008

A kinetic study on the degradation of p-nitroaniline by Fenton oxidation process
journal, September 2007

Chromate removal from aqueous wastes by reduction with ferrous ion
journal, August 1988

  • Eary, L. E.; Rai, Dhanpat.
  • Environmental Science & Technology, Vol. 22, Issue 8
  • DOI: 10.1021/es00173a018

RO membrane removal of unreacted chromium from spent tanning effluent. A pilot-scale study, Part 2
journal, September 2002

Genesis of hexavalent chromium from natural sources in soil and groundwater
journal, April 2007

  • Oze, C.; Bird, D. K.; Fendorf, S.
  • Proceedings of the National Academy of Sciences, Vol. 104, Issue 16
  • DOI: 10.1073/pnas.0701085104

Electron inelastic mean free paths in cerium dioxide
journal, June 2015

The Influence of Ferrous/Ferric Ions on the Efficiency of Photocatalytic Oxidation of Pollutants in Groundwater
journal, June 2005

Electrochemical studies on diffusion and redox behavior of various metal ions in some molten glasses
journal, May 1980

Advanced oxidation of acid and reactive dyes: Effect of Fenton treatment on aerobic, anoxic and anaerobic processes
journal, August 2008

The potential of compost-based biobarriers for Cr(VI) removal from contaminated groundwater: Column test
journal, July 2009

Natural hexavalent chromium in groundwaters interacting with ophiolitic rocks
journal, November 2002

  • Fantoni, Donatella; Brozzo, Gianpiero; Canepa, Marco
  • Environmental Geology, Vol. 42, Issue 8
  • DOI: 10.1007/s00254-002-0605-0

Fate and Effects of CeO 2 Nanoparticles in Aquatic Ecotoxicity Tests
journal, June 2009

  • Hoecke, Karen Van; Quik, Joris T. K.; Mankiewicz-Boczek, Joanna
  • Environmental Science & Technology, Vol. 43, Issue 12
  • DOI: 10.1021/es9002444

Oxidative stress of CeO2 nanoparticles via p38-Nrf-2 signaling pathway in human bronchial epithelial cell, Beas-2B
journal, June 2009

Application of Ce(IV) in industrial wastewater treatment
journal, December 2010

Reactivity of Fe(II)-Bearing Minerals toward Reductive Transformation of Organic Contaminants
journal, February 2004

  • Elsner, Martin; Schwarzenbach, René P.; Haderlein, Stefan B.
  • Environmental Science & Technology, Vol. 38, Issue 3
  • DOI: 10.1021/es0345569

Comparison of different treatment strategies for industrial landfill leachate
journal, March 2009

Cerium oxide nanoparticles: Size-selective formation and structure analysis
journal, January 2002

  • Zhang, Feng; Chan, Siu-Wai; Spanier, Jonathan E.
  • Applied Physics Letters, Vol. 80, Issue 1
  • DOI: 10.1063/1.1430502

Quantitative aspects of contact allergy to chromium and exposure to chrome-tanned leather
journal, September 2002

Comparison of different advanced oxidation processes for phenol degradation
journal, February 2002

The effect of Fe2+, Fe3+, H2O2 and the photo-Fenton reagent at near neutral pH on the solar disinfection (SODIS) at low temperatures of water containing Escherichia coli K12
journal, April 2010

  • Spuhler, Dorothee; Andrés Rengifo-Herrera, Julian; Pulgarin, César
  • Applied Catalysis B: Environmental, Vol. 96, Issue 1-2
  • DOI: 10.1016/j.apcatb.2010.02.010

Cerium oxide nanoparticle: a remarkably versatile rare earth nanomaterial for biological applications
journal, March 2014

CeO 2 nanoparticles induce DNA damage towards human dermal fibroblasts in vitro
journal, January 2009

Pseudo-Single-Crystal Electrochemistry on Polycrystalline Electrodes: Visualizing Activity at Grains and Grain Boundaries on Platinum for the Fe 2+ /Fe 3+ Redox Reaction
journal, February 2013

  • Aaronson, Barak D. B.; Chen, Chang-Hui; Li, Hongjiao
  • Journal of the American Chemical Society, Vol. 135, Issue 10
  • DOI: 10.1021/ja310632k

A consistent method for quantitative XPS peak analysis of thin oxide films on clean polycrystalline iron surfaces
journal, September 1997

Aqueous geochemistry of chromium: A review
journal, July 1991

Ion chromatography of organic-rich natural waters from peatlands V. Fe2+ and Fe3+
journal, July 1995

Structural and compositional evolution of Cr/Fe solids after indirect chromate reduction by dissimilatory iron-reducing bacteria
journal, February 2003

Palaeo-hydrogeological control on groundwater As levels in Red River delta, Vietnam
journal, November 2008

Hazard and Risk Assessment of a Nanoparticulate Cerium Oxide-Based Diesel Fuel Additive—A Case Study
journal, January 2008

Improvement in the oxidation behavior of austenitic stainless steels by superficially applied, cerium oxide coatings
journal, February 1994

  • Seal, S.; Bose, S. K.; Roy, S. K.
  • Oxidation of Metals, Vol. 41, Issue 1-2
  • DOI: 10.1007/BF01196647

Enhanced Colloidal Stability of CeO 2 Nanoparticles by Ferrous Ions: Adsorption, Redox Reaction, and Surface Precipitation
journal, April 2015

  • Liu, Xuyang; Ray, Jessica R.; Neil, Chelsea W.
  • Environmental Science & Technology, Vol. 49, Issue 9
  • DOI: 10.1021/es506363x

Advanced oxidation of phenol: A comparison between Fenton, electro-Fenton, sono-electro-Fenton and photo-electro-Fenton processes
journal, February 2012

Continuous hydrothermal processing of nano-crystalline particulates for chemical-mechanical planarization
journal, October 1998

Reduction of hexavalent chromium by ferrous iron
journal, June 1997

Behavior of Hexavalent Chromium in a Polluted Groundwater:  Redox Processes and Immobilization in Soils
journal, April 2001

  • Loyaux-Lawniczak, Stéphanie; Lecomte, Paul; Ehrhardt, Jean-Jacques
  • Environmental Science & Technology, Vol. 35, Issue 7
  • DOI: 10.1021/es001073l

Soil organic matter influences cerium translocation and physiological processes in kidney bean plants exposed to cerium oxide nanoparticles
journal, November 2016

  • Majumdar, Sanghamitra; Peralta-Videa, Jose R.; Trujillo-Reyes, Jesica
  • Science of The Total Environment, Vol. 569-570
  • DOI: 10.1016/j.scitotenv.2016.06.087

An overview for the utilization of wastes from stainless steel industries
journal, June 2011

The biological effects of subacute inhalation of diesel exhaust following addition of cerium oxide nanoparticles in atherosclerosis-prone mice
journal, May 2012

Atomic force microscopy study of the role of molecular weight of poly(acrylic acid) in chemical mechanical planarization for shallow trench isolation
journal, February 2006

  • Cho, Chae-Woong; Kim, Sang-Kyun; Paik, Ungyu
  • Journal of Materials Research, Vol. 21, Issue 2
  • DOI: 10.1557/jmr.2006.0054

Chromium speciation in solid matrices and regulation: a review
journal, January 2010

  • Unceta, N.; Séby, F.; Malherbe, J.
  • Analytical and Bioanalytical Chemistry, Vol. 397, Issue 3
  • DOI: 10.1007/s00216-009-3417-1

Toxicity Assessment of Cerium Oxide Nanoparticles in Cilantro ( Coriandrum sativum L.) Plants Grown in Organic Soil
journal, June 2013

  • Morales, Maria Isabel; Rico, Cyren M.; Hernandez-Viezcas, Jose Angel
  • Journal of Agricultural and Food Chemistry, Vol. 61, Issue 26
  • DOI: 10.1021/jf401628v

Occurrences, Uses, and Properties of Chromium
journal, August 1997

Metal tolerance and sequestration of Ni(II), Zn(II) and Cr(VI) ions from simulated and electroplating wastewater in batch process: Kinetics and equilibrium study
journal, January 2012

  • Kumar, Rajender; Bhatia, Divya; Singh, Rajesh
  • International Biodeterioration & Biodegradation, Vol. 66, Issue 1
  • DOI: 10.1016/j.ibiod.2011.11.006

Ce 3+ Ions Determine Redox-Dependent Anti-apoptotic Effect of Cerium Oxide Nanoparticles
journal, May 2011

  • Celardo, Ivana; De Nicola, Milena; Mandoli, Corrado
  • ACS Nano, Vol. 5, Issue 6
  • DOI: 10.1021/nn200126a

The reactivity of Fe(II) associated with goethite formed during short redox cycles toward Cr(VI) reduction under oxic conditions
journal, August 2017

Removal of Oxide Nanoparticles in a Model Wastewater Treatment Plant: Influence of Agglomeration and Surfactants on Clearing Efficiency
journal, August 2008

  • Limbach, Ludwig K.; Bereiter, Robert; Müller, Elisabeth
  • Environmental Science & Technology, Vol. 42, Issue 15, p. 5828-5833
  • DOI: 10.1021/es800091f

Natural Occurrence of Hexavalent Chromium in the Aromas Red Sands Aquifer, California
journal, August 2005

  • Gonzalez, A. R.; Ndung'u, K.; Flegal, A. R.
  • Environmental Science & Technology, Vol. 39, Issue 15
  • DOI: 10.1021/es048835n

Chromium Isotopes and the Fate of Hexavalent Chromium in the Environment
journal, March 2002

Treatment of iron and manganese in simulated groundwater via ozone technology
journal, December 2009

Spectroscopic Evidence for Fe(II)−Fe(III) Electron Transfer at the Iron Oxide−Water Interface
journal, September 2004

  • Williams, Aaron G. B.; Scherer, Michelle M.
  • Environmental Science & Technology, Vol. 38, Issue 18
  • DOI: 10.1021/es049373g

Investigation of phosphate adsorption onto ferrihydrite by X-ray Photoelectron Spectroscopy
journal, October 2013

Differential redox and sorption of Cr (III/VI) on natural silicate and oxide minerals: EXAFS and XANES results
journal, August 1997

Remediation Options for the Treatment of Electroplating and Leather Tanning Effluent Containing Chromium—A Review
journal, April 2006

  • Agrawal, A.; Kumar, V.; Pandey, B. D.
  • Mineral Processing and Extractive Metallurgy Review, Vol. 27, Issue 2
  • DOI: 10.1080/08827500600563319
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