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Title: Terahertz field–induced ferroelectricity in quantum paraelectric SrTiO 3

Abstract

“Hidden phases” are metastable collective states of matter that are typically not accessible on equilibrium phase diagrams. These phases can host exotic properties in otherwise conventional materials and hence may enable novel functionality and applications, but their discovery and access are still in early stages. Using intense terahertz electric field excitation, we found that an ultrafast phase transition into a hidden ferroelectric phase can be dynamically induced in quantum paraelectric strontium titanate (SrTiO 3 ). The induced lowering in crystal symmetry yields substantial changes in the phonon excitation spectra. Our results demonstrate collective coherent control over material structure, in which a single-cycle field drives ions along the microscopic pathway leading directly to their locations in a new crystalline phase on an ultrafast time scale.

Authors:
ORCiD logo; ORCiD logo; ORCiD logo; ; ; ORCiD logo; ORCiD logo
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1527067
Alternate Identifier(s):
OSTI ID: 1532430
Grant/Contract Number:  
[SC0019126; AC02-76SF00515; CHE-1808202; DMR-1719353; N00014-17-1-2574; P2ELP2-172290]
Resource Type:
Published Article
Journal Name:
Science
Additional Journal Information:
[Journal Name: Science Journal Volume: 364 Journal Issue: 6445]; Journal ID: ISSN 0036-8075
Publisher:
American Association for the Advancement of Science (AAAS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Li, Xian, Qiu, Tian, Zhang, Jiahao, Baldini, Edoardo, Lu, Jian, Rappe, Andrew M., and Nelson, Keith A. Terahertz field–induced ferroelectricity in quantum paraelectric SrTiO 3. United States: N. p., 2019. Web. doi:10.1126/science.aaw4913.
Li, Xian, Qiu, Tian, Zhang, Jiahao, Baldini, Edoardo, Lu, Jian, Rappe, Andrew M., & Nelson, Keith A. Terahertz field–induced ferroelectricity in quantum paraelectric SrTiO 3. United States. doi:10.1126/science.aaw4913.
Li, Xian, Qiu, Tian, Zhang, Jiahao, Baldini, Edoardo, Lu, Jian, Rappe, Andrew M., and Nelson, Keith A. Thu . "Terahertz field–induced ferroelectricity in quantum paraelectric SrTiO 3". United States. doi:10.1126/science.aaw4913.
@article{osti_1527067,
title = {Terahertz field–induced ferroelectricity in quantum paraelectric SrTiO 3},
author = {Li, Xian and Qiu, Tian and Zhang, Jiahao and Baldini, Edoardo and Lu, Jian and Rappe, Andrew M. and Nelson, Keith A.},
abstractNote = {“Hidden phases” are metastable collective states of matter that are typically not accessible on equilibrium phase diagrams. These phases can host exotic properties in otherwise conventional materials and hence may enable novel functionality and applications, but their discovery and access are still in early stages. Using intense terahertz electric field excitation, we found that an ultrafast phase transition into a hidden ferroelectric phase can be dynamically induced in quantum paraelectric strontium titanate (SrTiO 3 ). The induced lowering in crystal symmetry yields substantial changes in the phonon excitation spectra. Our results demonstrate collective coherent control over material structure, in which a single-cycle field drives ions along the microscopic pathway leading directly to their locations in a new crystalline phase on an ultrafast time scale.},
doi = {10.1126/science.aaw4913},
journal = {Science},
number = [6445],
volume = [364],
place = {United States},
year = {2019},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1126/science.aaw4913

Citation Metrics:
Cited by: 6 works
Citation information provided by
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