Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach

Roffey, Anna; Hollingsworth, Nathan; Islam, Husn-Ubayda; Bras, Wim; Sankar, Gopinathan; de Leeuw, Nora H.; Hogarth, Graeme

doi:10.1039/C9NA00262F

Title: Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach

Journal Article · 31 December 2018 · Nanoscale Advances

DOI: https://doi.org/10.1039/C9NA00262F · OSTI ID:1527056

^[1]; Hollingsworth, Nathan ^[2]; Islam, Husn-Ubayda ^[3];

^[4]; Sankar, Gopinathan ^[2];

^[5];

^[6]

Department of Chemistry; King's College London; London SE1 1DB; UK; Department of Chemistry
Department of Chemistry; University College London; London WC1H OAJ; UK
Department of Chemistry; University College London; London WC1H OAJ; UK; Netherlands Organisation for Scientific Research DUBBLE@ESRF
Netherlands Organisation for Scientific Research DUBBLE@ESRF; 38043 Grenoble; France; Chemistry Division; Oak Ridge National Laboratory
School of Chemistry; Cardiff University; Cardiff; UK
Department of Chemistry; King's College London; London SE1 1DB; UK

Fe(ii) and Fe(iii) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides andin situstudies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.

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Sponsoring Organization:: USDOE; Netherlands Organisation for Scientific Research (NWO)

OSTI ID:: 1527056

Alternate ID(s):: OSTI ID: 1558538

Journal Information:: Nanoscale Advances, Journal Name: Nanoscale Advances Journal Issue: 8 Vol. 1; ISSN 2516-0230; ISSN NAADAI

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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