Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach
- Department of Chemistry; King's College London; London SE1 1DB; UK; Department of Chemistry
- Department of Chemistry; University College London; London WC1H OAJ; UK
- Department of Chemistry; University College London; London WC1H OAJ; UK; Netherlands Organisation for Scientific Research DUBBLE@ESRF
- Netherlands Organisation for Scientific Research DUBBLE@ESRF; 38043 Grenoble; France; Chemistry Division; Oak Ridge National Laboratory
- School of Chemistry; Cardiff University; Cardiff; UK
- Department of Chemistry; King's College London; London SE1 1DB; UK
Fe(ii) and Fe(iii) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides andin situstudies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.
- Sponsoring Organization:
- USDOE; Netherlands Organisation for Scientific Research (NWO)
- OSTI ID:
- 1527056
- Alternate ID(s):
- OSTI ID: 1558538
- Journal Information:
- Nanoscale Advances, Journal Name: Nanoscale Advances Journal Issue: 8 Vol. 1; ISSN 2516-0230; ISSN NAADAI
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United Kingdom
- Language:
- English
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