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Title: Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach

Abstract

Fe( ii ) and Fe( iii ) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.

Authors:
ORCiD logo [1];  [2];  [3]; ORCiD logo [4];  [2]; ORCiD logo [5]; ORCiD logo [6]
  1. Department of Chemistry, King's College London, London SE1 1DB, UK, Department of Chemistry
  2. Department of Chemistry, University College London, London WC1H OAJ, UK
  3. Department of Chemistry, University College London, London WC1H OAJ, UK, Netherlands Organisation for Scientific Research DUBBLE@ESRF
  4. Netherlands Organisation for Scientific Research DUBBLE@ESRF, 38043 Grenoble, France, Chemistry Division, Oak Ridge National Laboratory
  5. School of Chemistry, Cardiff University, Cardiff, UK
  6. Department of Chemistry, King's College London, London SE1 1DB, UK
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1527056
Resource Type:
Published Article
Journal Name:
Nanoscale Advances
Additional Journal Information:
Journal Name: Nanoscale Advances Journal Volume: 1 Journal Issue: 8; Journal ID: ISSN 2516-0230
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Roffey, Anna, Hollingsworth, Nathan, Islam, Husn-Ubayda, Bras, Wim, Sankar, Gopinathan, de Leeuw, Nora H., and Hogarth, Graeme. Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach. United Kingdom: N. p., 2019. Web. doi:10.1039/C9NA00262F.
Roffey, Anna, Hollingsworth, Nathan, Islam, Husn-Ubayda, Bras, Wim, Sankar, Gopinathan, de Leeuw, Nora H., & Hogarth, Graeme. Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach. United Kingdom. doi:10.1039/C9NA00262F.
Roffey, Anna, Hollingsworth, Nathan, Islam, Husn-Ubayda, Bras, Wim, Sankar, Gopinathan, de Leeuw, Nora H., and Hogarth, Graeme. Tue . "Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach". United Kingdom. doi:10.1039/C9NA00262F.
@article{osti_1527056,
title = {Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach},
author = {Roffey, Anna and Hollingsworth, Nathan and Islam, Husn-Ubayda and Bras, Wim and Sankar, Gopinathan and de Leeuw, Nora H. and Hogarth, Graeme},
abstractNote = {Fe( ii ) and Fe( iii ) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.},
doi = {10.1039/C9NA00262F},
journal = {Nanoscale Advances},
number = 8,
volume = 1,
place = {United Kingdom},
year = {2019},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9NA00262F

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Works referenced in this record:

Reversible interconversion of carbon dioxide and formate by an electroactive enzyme
journal, July 2008

  • Reda, T.; Plugge, C. M.; Abram, N. J.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 31, p. 10654-10658
  • DOI: 10.1073/pnas.0801290105