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Title: Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach

Journal Article · · Nanoscale Advances
DOI: https://doi.org/10.1039/C9NA00262F · OSTI ID:1527056
ORCiD logo [1];  [2];  [3]; ORCiD logo [4];  [2]; ORCiD logo [5]; ORCiD logo [6]
  1. Department of Chemistry; King's College London; London SE1 1DB; UK; Department of Chemistry
  2. Department of Chemistry; University College London; London WC1H OAJ; UK
  3. Department of Chemistry; University College London; London WC1H OAJ; UK; Netherlands Organisation for Scientific Research DUBBLE@ESRF
  4. Netherlands Organisation for Scientific Research DUBBLE@ESRF; 38043 Grenoble; France; Chemistry Division; Oak Ridge National Laboratory
  5. School of Chemistry; Cardiff University; Cardiff; UK
  6. Department of Chemistry; King's College London; London SE1 1DB; UK

Fe(ii) and Fe(iii) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides andin situstudies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.

Sponsoring Organization:
USDOE; Netherlands Organisation for Scientific Research (NWO)
OSTI ID:
1527056
Alternate ID(s):
OSTI ID: 1558538
Journal Information:
Nanoscale Advances, Journal Name: Nanoscale Advances Journal Issue: 8 Vol. 1; ISSN 2516-0230; ISSN NAADAI
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United Kingdom
Language:
English

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