Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach
Abstract
Fe( ii ) and Fe( iii ) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.
- Authors:
-
[1];
[4];
[5];
[6]
- Department of Chemistry, King's College London, London SE1 1DB, UK, Department of Chemistry
- Department of Chemistry, University College London, London WC1H OAJ, UK
- Department of Chemistry, University College London, London WC1H OAJ, UK, Netherlands Organisation for Scientific Research DUBBLE@ESRF
- Netherlands Organisation for Scientific Research DUBBLE@ESRF, 38043 Grenoble, France, Chemistry Division, Oak Ridge National Laboratory
- School of Chemistry, Cardiff University, Cardiff, UK
- Department of Chemistry, King's College London, London SE1 1DB, UK
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1527056
- Resource Type:
- Published Article
- Journal Name:
- Nanoscale Advances
- Additional Journal Information:
- Journal Name: Nanoscale Advances Journal Volume: 1 Journal Issue: 8; Journal ID: ISSN 2516-0230
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Roffey, Anna, Hollingsworth, Nathan, Islam, Husn-Ubayda, Bras, Wim, Sankar, Gopinathan, de Leeuw, Nora H., and Hogarth, Graeme. Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9NA00262F.
Roffey, Anna, Hollingsworth, Nathan, Islam, Husn-Ubayda, Bras, Wim, Sankar, Gopinathan, de Leeuw, Nora H., & Hogarth, Graeme. Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach. United Kingdom. doi:10.1039/C9NA00262F.
Roffey, Anna, Hollingsworth, Nathan, Islam, Husn-Ubayda, Bras, Wim, Sankar, Gopinathan, de Leeuw, Nora H., and Hogarth, Graeme. Tue .
"Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach". United Kingdom. doi:10.1039/C9NA00262F.
@article{osti_1527056,
title = {Fe( ii ) and Fe( iii ) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach},
author = {Roffey, Anna and Hollingsworth, Nathan and Islam, Husn-Ubayda and Bras, Wim and Sankar, Gopinathan and de Leeuw, Nora H. and Hogarth, Graeme},
abstractNote = {Fe( ii ) and Fe( iii ) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.},
doi = {10.1039/C9NA00262F},
journal = {Nanoscale Advances},
number = 8,
volume = 1,
place = {United Kingdom},
year = {2019},
month = {8}
}
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9NA00262F
DOI: 10.1039/C9NA00262F
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Works referenced in this record:
Reversible interconversion of carbon dioxide and formate by an electroactive enzyme
journal, July 2008
- Reda, T.; Plugge, C. M.; Abram, N. J.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 31, p. 10654-10658