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Title: Probing molecular bond-length using molecular-frame photoelectron angular distributions

Abstract

The molecular-frame photoelectron angular distributions (MFPADs) in O 1s photoemission from CO 2 molecule were measured. Patterns due to photoelectron diffractions were observed in the MFPADs. The polarization-averaged MFPADs were compared with theoretical calculation and were found to be useful in determining the molecular bond-length, which is a component to determine molecular structures.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [1];  [4];  [5];  [6];  [6]; ORCiD logo [7]; ORCiD logo [8];  [9]; ORCiD logo [10]; ORCiD logo [9]; ORCiD logo [1]
  1. Tohoku Univ., Sendai (Japan)
  2. Tohoku Univ., Sendai (Japan); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  3. Tohoku Univ., Sendai (Japan); ShanghaiTech Univ., Shanghai (China)
  4. Kyoto Univ., Kyoto (Japan); Inst. of Molecular Science, Okazaki (Japan)
  5. Kyoto Univ., Kyoto (Japan)
  6. Goeth-Univ. Frankfurt am Main, Frankfurt (Germany)
  7. Japan Synchrotron Radiation Research Inst., Hyogo (Japan); QST, Hyogo (Japan)
  8. Japan Synchrotron Radiation Research Inst., Hyogo (Japan)
  9. National Metrology Institute of Japan, Tsukuba (Japan)
  10. National Metrology Institute of Japan, Tsukuba (Japan); Inst. of Material Structure Science, Tsukuba (Japan)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division; USDOE
OSTI Identifier:
1526599
Alternate Identifier(s):
OSTI ID: 1511080
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 150; Journal Issue: 17; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats

Fukuzawa, Hironobu, Lucchese, Robert R., Liu, Xiao-Jing, Sakai, Kentaro, Iwayama, Hiroshi, Nagaya, Kiyonobu, Kreidi, Katharina, Schöffler, Markus S., Harries, James R., Tamenori, Yusuke, Morishita, Yuichiro, Suzuki, Isao H., Saito, Norio, and Ueda, Kiyoshi. Probing molecular bond-length using molecular-frame photoelectron angular distributions. United States: N. p., 2019. Web. doi:10.1063/1.5091946.
Fukuzawa, Hironobu, Lucchese, Robert R., Liu, Xiao-Jing, Sakai, Kentaro, Iwayama, Hiroshi, Nagaya, Kiyonobu, Kreidi, Katharina, Schöffler, Markus S., Harries, James R., Tamenori, Yusuke, Morishita, Yuichiro, Suzuki, Isao H., Saito, Norio, & Ueda, Kiyoshi. Probing molecular bond-length using molecular-frame photoelectron angular distributions. United States. doi:10.1063/1.5091946.
Fukuzawa, Hironobu, Lucchese, Robert R., Liu, Xiao-Jing, Sakai, Kentaro, Iwayama, Hiroshi, Nagaya, Kiyonobu, Kreidi, Katharina, Schöffler, Markus S., Harries, James R., Tamenori, Yusuke, Morishita, Yuichiro, Suzuki, Isao H., Saito, Norio, and Ueda, Kiyoshi. Tue . "Probing molecular bond-length using molecular-frame photoelectron angular distributions". United States. doi:10.1063/1.5091946.
@article{osti_1526599,
title = {Probing molecular bond-length using molecular-frame photoelectron angular distributions},
author = {Fukuzawa, Hironobu and Lucchese, Robert R. and Liu, Xiao-Jing and Sakai, Kentaro and Iwayama, Hiroshi and Nagaya, Kiyonobu and Kreidi, Katharina and Schöffler, Markus S. and Harries, James R. and Tamenori, Yusuke and Morishita, Yuichiro and Suzuki, Isao H. and Saito, Norio and Ueda, Kiyoshi},
abstractNote = {The molecular-frame photoelectron angular distributions (MFPADs) in O 1s photoemission from CO2 molecule were measured. Patterns due to photoelectron diffractions were observed in the MFPADs. The polarization-averaged MFPADs were compared with theoretical calculation and were found to be useful in determining the molecular bond-length, which is a component to determine molecular structures.},
doi = {10.1063/1.5091946},
journal = {Journal of Chemical Physics},
number = 17,
volume = 150,
place = {United States},
year = {2019},
month = {5}
}

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