Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments
Abstract
Growth of the solid electrolyte interphase (SEI) is a primary driver of capacity fade in lithium-ion batteries. Despite its importance to this device and intense research interest, the fundamental mechanisms underpinning SEI growth remain unclear. In Part I of this work, we present an electroanalytical method to measure the dependence of SEI growth on potential, current magnitude, and current direction during galvanostatic cycling of carbon black/Li half cells.We find that SEI growth strongly depends on all three parameters; most notably, we find SEI growth rates increase with nominal C rate and are significantly higher on lithiation than on delithiation. We observe this directional effect in both galvanostatic and potentiostatic experiments and discuss hypotheses that could explain this observation. This work identifies a strong coupling between SEI growth and charge storage (e.g., intercalation and capacitance) in carbon negative electrodes.
- Authors:
-
[1];
[2];
[3];
[2];
[1]
- Stanford Univ., CA (United States). Dept. of Materials Science
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Chemical Engineering
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Div.
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1526563
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 166; Journal Issue: 4; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Attia, Peter M., Das, Supratim, Harris, Stephen J., Bazant, Martin Z., and Chueh, William C. Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments. United States: N. p., 2019.
Web. doi:10.1149/2.0231904jes.
Attia, Peter M., Das, Supratim, Harris, Stephen J., Bazant, Martin Z., & Chueh, William C. Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments. United States. https://doi.org/10.1149/2.0231904jes
Attia, Peter M., Das, Supratim, Harris, Stephen J., Bazant, Martin Z., and Chueh, William C. Tue .
"Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments". United States. https://doi.org/10.1149/2.0231904jes. https://www.osti.gov/servlets/purl/1526563.
@article{osti_1526563,
title = {Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments},
author = {Attia, Peter M. and Das, Supratim and Harris, Stephen J. and Bazant, Martin Z. and Chueh, William C.},
abstractNote = {Growth of the solid electrolyte interphase (SEI) is a primary driver of capacity fade in lithium-ion batteries. Despite its importance to this device and intense research interest, the fundamental mechanisms underpinning SEI growth remain unclear. In Part I of this work, we present an electroanalytical method to measure the dependence of SEI growth on potential, current magnitude, and current direction during galvanostatic cycling of carbon black/Li half cells.We find that SEI growth strongly depends on all three parameters; most notably, we find SEI growth rates increase with nominal C rate and are significantly higher on lithiation than on delithiation. We observe this directional effect in both galvanostatic and potentiostatic experiments and discuss hypotheses that could explain this observation. This work identifies a strong coupling between SEI growth and charge storage (e.g., intercalation and capacitance) in carbon negative electrodes.},
doi = {10.1149/2.0231904jes},
journal = {Journal of the Electrochemical Society},
number = 4,
volume = 166,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 2019},
month = {Tue Jan 01 00:00:00 EST 2019}
}
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Effect of charge rate on capacity degradation of LiFePO 4 power battery at low temperature
journal, December 2019
- Wu, Xiaogang; Wang, Wenbo; Du, Jiuyu
- International Journal of Energy Research, Vol. 44, Issue 3
Probing the reversibility and kinetics of Li + during SEI formation and (de)intercalation on edge plane graphite using ion-sensitive scanning electrochemical microscopy
journal, January 2019
- Gossage, Zachary T.; Hui, Jingshu; Zeng, Yunxiong
- Chemical Science, Vol. 10, Issue 46
Electrochemical Kinetics of SEI Growth on Carbon Black: Part II. Modeling
journal, January 2019
- Das, Supratim; Attia, Peter M.; Chueh, William C.
- Journal of The Electrochemical Society, Vol. 166, Issue 4