Lead-free halide double perovskite-polymer composites for flexible X-ray imaging

Lin, Haoran; Shan, Xin; Neu, Jennifer; Geske, Thomas; Davis, Melissa; Mao, Pengsu; Xiao, Kai; Yu, Zhibin

doi:10.1039/C8TC01564C

Title: Lead-free halide double perovskite-polymer composites for flexible X-ray imaging

Journal Article · 07 August 2018 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/C8TC01564C · OSTI ID:1526389

Lin, Haoran ^[1]; Shan, Xin ^[1]; Neu, Jennifer ^[2]; Geske, Thomas ^[1]; Davis, Melissa ^[1]; Mao, Pengsu ^[1];

^[3]; Yu, Zhibin ^[1]

Florida State Univ., Tallahassee, FL (United States)
Florida State Univ., Tallahassee, FL (United States); National High Magnetic Field Lab, Tallahassee, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

X-ray detectors are demonstrated using composite films of lead-free Cs₂AgBiBr₆ halide double perovskite embedded in a polymer matrix as the X-ray photoconductors. Polymers with hydroxyl functional groups greatly improve the uniformity of the composite films, and large area dense films are obtained using a simple drop-casting process. X-ray detectors based on the composite films exhibit a sensitivity of 40 μC Gy_air^-1 cm^-2, comparable to the reported sensitivity using Cs₂AgBiBr₆ single crystals. Such detectors can also tolerate a 5% tensile/compressive strain in the composite films without performance degradation. Pixelated X-ray detectors fabricated on the same composite film can realize X-ray imaging and resolve a proof-of-concept geometric pattern.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1526389

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 44 Vol. 6; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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