Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride
- Department of Chemistry and Biochemistry, University of California, Santa Barbara, USA
- Department of Chemistry, University at Buffalo, State University of New York, Buffalo, USA
The first isolable molecular thorium nitride, [(NR 2 ) 3 Th(μ-N)Th(NR 2 ) 3 ] − , was synthesized by reaction of [Th{N(R)(SiMe 2 )CH 2 }(NR 2 ) 2 ] with NaNH 2 and characterized by X-ray crystallography, 15 N NMR spectroscopy, and DFT calculations.
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- SC0001861; SC0001136
- OSTI ID:
- 1526076
- Alternate ID(s):
- OSTI ID: 1610532
- Journal Information:
- Chemical Science, Journal Name: Chemical Science Journal Issue: 26 Vol. 10; ISSN 2041-6520; ISSN CSHCBM
- Publisher:
- Royal Society of Chemistry (RSC)Copyright Statement
- Country of Publication:
- United Kingdom
- Language:
- English
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