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Title: Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride

Abstract

The first isolable molecular thorium nitride, [(NR 2 ) 3 Th(μ-N)Th(NR 2 ) 3 ] , was synthesized by reaction of [Th{N(R)(SiMe 2 )CH 2 }(NR 2 ) 2 ] with NaNH 2 and characterized by X-ray crystallography, 15 N NMR spectroscopy, and DFT calculations.

Authors:
 [1]; ORCiD logo [2];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, University of California, Santa Barbara, USA
  2. Department of Chemistry, University at Buffalo, State University of New York, Buffalo, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1526076
Grant/Contract Number:  
[SC-0001861; SC0001136]
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
[Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 26]; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Staun, Selena L., Sergentu, Dumitru-Claudiu, Wu, Guang, Autschbach, Jochen, and Hayton, Trevor W. Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride. United Kingdom: N. p., 2019. Web. doi:10.1039/C9SC01960J.
Staun, Selena L., Sergentu, Dumitru-Claudiu, Wu, Guang, Autschbach, Jochen, & Hayton, Trevor W. Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride. United Kingdom. doi:10.1039/C9SC01960J.
Staun, Selena L., Sergentu, Dumitru-Claudiu, Wu, Guang, Autschbach, Jochen, and Hayton, Trevor W. Wed . "Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride". United Kingdom. doi:10.1039/C9SC01960J.
@article{osti_1526076,
title = {Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride},
author = {Staun, Selena L. and Sergentu, Dumitru-Claudiu and Wu, Guang and Autschbach, Jochen and Hayton, Trevor W.},
abstractNote = {The first isolable molecular thorium nitride, [(NR 2 ) 3 Th(μ-N)Th(NR 2 ) 3 ] − , was synthesized by reaction of [Th{N(R)(SiMe 2 )CH 2 }(NR 2 ) 2 ] with NaNH 2 and characterized by X-ray crystallography, 15 N NMR spectroscopy, and DFT calculations.},
doi = {10.1039/C9SC01960J},
journal = {Chemical Science},
number = [26],
volume = [10],
place = {United Kingdom},
year = {2019},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SC01960J

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Cited by: 1 work
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