Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents
Abstract
A perhydroxylated dodecaborate cluster acts as an inorganic polyol to produce cross-linked polyurethanes, which confers a porous structure and enhanced thermal stability compared to analogous polymers produced from carbon-based polyols.
- Authors:
-
- Department of Chemistry and Biochemistry, University of California, Los Angeles, USA, California NanoSystems Institute (CNSI)
- Department of Fire Protection Engineering, University of Maryland, College Park, USA
- Department of Chemistry and Biochemistry, University of California, Los Angeles, USA
- Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1525903
- Grant/Contract Number:
- SC0019381
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm Journal Volume: 55 Journal Issue: 60; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Jung, Dahee, Raffan-Montoya, Fernando, Ramachandran, Roshini, Zhang, Yuanyuan, Islamoglu, Timur, Marin, Gustavo, Qian, Elaine A., Dziedzic, Rafal M., Farha, Omar K., Stoliarov, Stanislav I., and Spokoyny, Alexander M. Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9CC03350E.
Jung, Dahee, Raffan-Montoya, Fernando, Ramachandran, Roshini, Zhang, Yuanyuan, Islamoglu, Timur, Marin, Gustavo, Qian, Elaine A., Dziedzic, Rafal M., Farha, Omar K., Stoliarov, Stanislav I., & Spokoyny, Alexander M. Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents. United Kingdom. https://doi.org/10.1039/C9CC03350E
Jung, Dahee, Raffan-Montoya, Fernando, Ramachandran, Roshini, Zhang, Yuanyuan, Islamoglu, Timur, Marin, Gustavo, Qian, Elaine A., Dziedzic, Rafal M., Farha, Omar K., Stoliarov, Stanislav I., and Spokoyny, Alexander M. Tue .
"Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents". United Kingdom. https://doi.org/10.1039/C9CC03350E.
@article{osti_1525903,
title = {Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents},
author = {Jung, Dahee and Raffan-Montoya, Fernando and Ramachandran, Roshini and Zhang, Yuanyuan and Islamoglu, Timur and Marin, Gustavo and Qian, Elaine A. and Dziedzic, Rafal M. and Farha, Omar K. and Stoliarov, Stanislav I. and Spokoyny, Alexander M.},
abstractNote = {A perhydroxylated dodecaborate cluster acts as an inorganic polyol to produce cross-linked polyurethanes, which confers a porous structure and enhanced thermal stability compared to analogous polymers produced from carbon-based polyols.},
doi = {10.1039/C9CC03350E},
journal = {ChemComm},
number = 60,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {7}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9CC03350E
https://doi.org/10.1039/C9CC03350E
Other availability
Cited by: 1 work
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
THE ISOLATION OF THE ICOSAHEDRAL B 12 H 12 -2 ION
journal, June 1960
- Pitochelli, Anthony R.; Hawthorne, Frederick M.
- Journal of the American Chemical Society, Vol. 82, Issue 12
Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane
journal, January 2008
- Bae, Youn-Sang; Farha, Omar K.; Spokoyny, Alexander M.
- Chemical Communications, Issue 35
New ligand platforms featuring boron-rich clusters as organomimetic substituents
journal, April 2013
- Spokoyny, Alexander M.
- Pure and Applied Chemistry, Vol. 85, Issue 5
Structural engineering of polyurethane coatings for high performance applications
journal, March 2007
- Chattopadhyay, D. K.; Raju, K. V. S. N.
- Progress in Polymer Science, Vol. 32, Issue 3
Dodecahydroxy- c loso -dodecaborate(2−)
journal, March 2001
- Peymann, Toralf; Knobler, Carolyn B.; Khan, Saeed I.
- Journal of the American Chemical Society, Vol. 123, Issue 10
IR-change and yellowing of polyurethane as a result of UV irradiation
journal, April 2009
- Rosu, Dan; Rosu, Liliana; Cascaval, Constantin N.
- Polymer Degradation and Stability, Vol. 94, Issue 4
Full substitution of petroleum-based polyols by phosphorus-containing soy-based polyols for fabricating highly flame-retardant polyisocyanurate foams
journal, August 2018
- Chen, Ming-Jun; Wang, Xu; Tao, Mei-Cen
- Polymer Degradation and Stability, Vol. 154
Thermal degradation of urethanes based on 4,4′-diphenylmethane diisocyanate and 1,4-butanediol (MDI/BDO)
journal, August 1986
- Yang, W. P.; Macosko, C. W.; Wellinghoff, S. T.
- Polymer, Vol. 27, Issue 8
Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)
journal, January 2016
- Wan, Wen-Ming; Baggett, Andrew W.; Cheng, Fei
- Chemical Communications, Vol. 52, Issue 93
Screening flame retardants using milligram-scale flame calorimetry
journal, May 2018
- Raffan-Montoya, Fernando; Stoliarov, Stanislav I.; Levchik, Sergei
- Polymer Degradation and Stability, Vol. 151
Crosslinked poly(vinyl alcohol) hydrogels for wound dressing applications: A review of remarkably blended polymers
journal, January 2015
- Kamoun, Elbadawy A.; Chen, Xin; Mohy Eldin, Mohamed S.
- Arabian Journal of Chemistry, Vol. 8, Issue 1
Thermal degradation and stability of HTPB-based polyurethane and polyurethaneureas
journal, June 2003
- Gupta, Tarakranjan; Adhikari, Basudam
- Thermochimica Acta, Vol. 402, Issue 1-2
Polymer science with transition metals and main group elements: Towards functional, supramolecular inorganic polymeric materials
journal, December 2001
- Manners, Ian
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 40, Issue 2
Polyhedral boron clusters in materials science
journal, January 2011
- Dash, Barada Prasanna; Satapathy, Rashmirekha; Maguire, John A.
- New Journal of Chemistry, Vol. 35, Issue 10
Nonclassical Applications of closo -Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage
journal, February 2019
- Fisher, S. P.; Tomich, A. W.; Lovera, S. O.
- Chemical Reviews, Vol. 119, Issue 14
Synthesis and Applications of Perfunctionalized Boron Clusters
journal, February 2018
- Axtell, Jonathan C.; Saleh, Liban M. A.; Qian, Elaine A.
- Inorganic Chemistry, Vol. 57, Issue 5
Model compounds and monomers for phenylene ether carboranylene ketone (PECK) polymer synthesis: preparation and characterization of boron-arylated ortho-carboranes bearing carboxyphenyl, phenoxyphenyl or benzoylphenyl substituents
journal, March 2002
- Fox, Mark A.; Wade, Kenneth
- Journal of Materials Chemistry, Vol. 12, Issue 5
Polytellurophenes
journal, April 2011
- Jahnke, Ashlee A.; Seferos, Dwight S.
- Macromolecular Rapid Communications, Vol. 32, Issue 13
Ultra low density and highly crosslinked biocompatible shape memory polyurethane foams
journal, March 2012
- Singhal, Pooja; Rodriguez, Jennifer N.; Small, Ward
- Journal of Polymer Science Part B: Polymer Physics, Vol. 50, Issue 10, p. 724-737
Reactivity of isocyanates with urethanes: Conditions for allophanate formation
journal, November 2005
- Lapprand, A.; Boisson, F.; Delolme, F.
- Polymer Degradation and Stability, Vol. 90, Issue 2
Synthesis, mechanical properties and fire behaviors of rigid polyurethane foam with a reactive flame retardant containing phosphazene and phosphate
journal, December 2015
- Yang, Rong; Hu, Wentian; Xu, Liang
- Polymer Degradation and Stability, Vol. 122
Cross-linking dots on metal oxides
journal, April 2019
- Ramachandran, Roshini; Jung, Dahee; Spokoyny, Alexander M.
- NPG Asia Materials, Vol. 11, Issue 1
Polyurethane types, synthesis and applications – a review
journal, January 2016
- Akindoyo, John O.; Beg, M. D. H.; Ghazali, Suriati
- RSC Advances, Vol. 6, Issue 115
Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants
journal, May 2016
- Messina, Marco S.; Axtell, Jonathan C.; Wang, Yiqun
- Journal of the American Chemical Society, Vol. 138, Issue 22
Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009
- Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
- Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
Polyurethanes: A class of modern versatile materials
journal, November 1992
- Seymour, Raymond B.; Kauffman, George B.
- Journal of Chemical Education, Vol. 69, Issue 11
Influence of molecular weight and degree of crosslinking on the specific volume and glass temperature of polymers
journal, February 1955
- Fox, T. G.; Loshaek, S.
- Journal of Polymer Science, Vol. 15, Issue 80
Vegetable oil-based rigid polyurethanes and phosphorylated flame-retardants derived from epoxydized soybean oil
journal, October 2014
- Heinen, Melissa; Gerbase, Annelise Engel; Petzhold, Cesar Liberato
- Polymer Degradation and Stability, Vol. 108
A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu II Dodecaborate Cluster Complex for Selective Gas Separation
journal, May 2019
- Zhang, Yuanbin; Yang, Lifeng; Wang, Lingyao
- Angewandte Chemie International Edition, Vol. 58, Issue 24
Icosahedral boron clusters: a perfect tool for the enhancement of polymer features
journal, January 2016
- Núñez, R.; Romero, I.; Teixidor, F.
- Chemical Society Reviews, Vol. 45, Issue 19
Thermal degradation of linear polyurethanes and model biscarbamates
journal, March 1973
- Matuszak, Michael L.; Frisch, K. C.
- Journal of Polymer Science: Polymer Chemistry Edition, Vol. 11, Issue 3
Luminescent m -Carborane-Based π-Conjugated Polymer
journal, April 2009
- Kokado, Kenta; Tokoro, Yuichiro; Chujo, Yoshiki
- Macromolecules, Vol. 42, Issue 8
Synthesis and Properties of Polyurethane Elastomers with Castor Oil as Crosslinker
journal, November 2009
- Oprea, Stefan
- Journal of the American Oil Chemists' Society, Vol. 87, Issue 3
A polymer precursor route to metal borides
journal, November 1993
- Su, Kai; Sneddon, Larry G.
- Chemistry of Materials, Vol. 5, Issue 11
Functional Polymeric Materials Based on Main-Group Elements
journal, February 2019
- Vidal, Fernando; Jäkle, Frieder
- Angewandte Chemie International Edition, Vol. 58, Issue 18
Rapid synthesis of redox-active dodecaborane B 12 (OR) 12 clusters under ambient conditions
journal, January 2016
- Wixtrom, Alex I.; Shao, Yanwu; Jung, Dahee
- Inorganic Chemistry Frontiers, Vol. 3, Issue 5
Hypercrosslinked porous polymer materials: design, synthesis, and applications
journal, January 2017
- Tan, Liangxiao; Tan, Bien
- Chemical Society Reviews, Vol. 46, Issue 11
Glycerol-, pentaerythritol- and trimethylolpropane-based polyurethanes and their cellulose carbonate composites prepared via the non-isocyanate route with catalytic carbon dioxide fixation
journal, January 2013
- Fleischer, Maria; Blattmann, Hannes; Mülhaupt, Rolf
- Green Chemistry, Vol. 15, Issue 4
A novel supramolecular polymer gel constructed by crosslinking pillar[5]arene-based supramolecular polymers through metal–ligand interactions
journal, January 2015
- Wang, Pi; Xing, Hao; Xia, Danyu
- Chemical Communications, Vol. 51, Issue 98
Characterization of hyperporous polyurethane-based gels by non-intrusive mercury porosimetry
journal, August 2003
- Pirard, R.; Rigacci, A.; Maréchal, J. C.
- Polymer, Vol. 44, Issue 17
A molecular cross-linking approach for hybrid metal oxides
journal, March 2018
- Jung, Dahee; Saleh, Liban M. A.; Berkson, Zachariah J.
- Nature Materials, Vol. 17, Issue 4
Linear Hybrid Polymer Building Blocks: Methacrylate-Functionalized Polyhedral Oligomeric Silsesquioxane Monomers and Polymers
journal, November 1995
- Lichtenhan, Joseph D.; Otonari, Yoshiko A.; Carr, Michael J.
- Macromolecules, Vol. 28, Issue 24
Synthesis of rigid polyurethane foams with castor oil-based flame retardant polyols
journal, January 2014
- Zhang, Liqiang; Zhang, Meng; Hu, Lihong
- Industrial Crops and Products, Vol. 52
Vulcanization and crosslinking in elastomers
journal, January 1997
- Akiba, M.
- Progress in Polymer Science, Vol. 22, Issue 3