Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents

Jung, Dahee; Raffan-Montoya, Fernando; Ramachandran, Roshini; Zhang, Yuanyuan; Islamoglu, Timur; Marin, Gustavo; Qian, Elaine A.; Dziedzic, Rafal M.; Farha, Omar K.; Stoliarov, Stanislav I.; Spokoyny, Alexander M.

doi:10.1039/C9CC03350E

Title: Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents

Abstract

A perhydroxylated dodecaborate cluster acts as an inorganic polyol to produce cross-linked polyurethanes, which confers a porous structure and enhanced thermal stability compared to analogous polymers produced from carbon-based polyols.

Authors:

^[1];

^[2];

^[3];

^[4];

^[3];

^[1];

^[3];

^[4];

^[2];

^[1]

Department of Chemistry and Biochemistry, University of California, Los Angeles, USA, California NanoSystems Institute (CNSI)
Department of Fire Protection Engineering, University of Maryland, College Park, USA
Department of Chemistry and Biochemistry, University of California, Los Angeles, USA
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USA

Publication Date:: 2019-07-23

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1525903

Grant/Contract Number:: SC0019381

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 55 Journal Issue: 60; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Jung, Dahee, Raffan-Montoya, Fernando, Ramachandran, Roshini, Zhang, Yuanyuan, Islamoglu, Timur, Marin, Gustavo, Qian, Elaine A., Dziedzic, Rafal M., Farha, Omar K., Stoliarov, Stanislav I., and Spokoyny, Alexander M. Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9CC03350E.

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                    Jung, Dahee, Raffan-Montoya, Fernando, Ramachandran, Roshini, Zhang, Yuanyuan, Islamoglu, Timur, Marin, Gustavo, Qian, Elaine A., Dziedzic, Rafal M., Farha, Omar K., Stoliarov, Stanislav I., & Spokoyny, Alexander M. Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents.  United Kingdom.  https://doi.org/10.1039/C9CC03350E

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                    Jung, Dahee, Raffan-Montoya, Fernando, Ramachandran, Roshini, Zhang, Yuanyuan, Islamoglu, Timur, Marin, Gustavo, Qian, Elaine A., Dziedzic, Rafal M., Farha, Omar K., Stoliarov, Stanislav I., and Spokoyny, Alexander M. Tue .  
"Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents".  United Kingdom.  https://doi.org/10.1039/C9CC03350E.

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@article{osti_1525903,

  title        = {Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents},

  author       = {Jung, Dahee and Raffan-Montoya, Fernando and Ramachandran, Roshini and Zhang, Yuanyuan and Islamoglu, Timur and Marin, Gustavo and Qian, Elaine A. and Dziedzic, Rafal M. and Farha, Omar K. and Stoliarov, Stanislav I. and Spokoyny, Alexander M.},

  abstractNote = {A perhydroxylated dodecaborate cluster acts as an inorganic polyol to produce cross-linked polyurethanes, which confers a porous structure and enhanced thermal stability compared to analogous polymers produced from carbon-based polyols.},

  doi          = {10.1039/C9CC03350E},

  journal      = {ChemComm},

  number       = 60,

  volume       = 55,

  place        = {United Kingdom},

  year         = {2019},

  month        = {7}

}

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Title: Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents

Abstract

Citation Formats

THE ISOLATION OF THE ICOSAHEDRAL B 12 H 12 -2 ION journal, June 1960

Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane journal, January 2008

New ligand platforms featuring boron-rich clusters as organomimetic substituents journal, April 2013

Structural engineering of polyurethane coatings for high performance applications journal, March 2007

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Thermal degradation of urethanes based on 4,4′-diphenylmethane diisocyanate and 1,4-butanediol (MDI/BDO) journal, August 1986

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Polytellurophenes journal, April 2011

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Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants journal, May 2016

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A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu II Dodecaborate Cluster Complex for Selective Gas Separation journal, May 2019

Icosahedral boron clusters: a perfect tool for the enhancement of polymer features journal, January 2016

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Luminescent m -Carborane-Based π-Conjugated Polymer journal, April 2009

Synthesis and Properties of Polyurethane Elastomers with Castor Oil as Crosslinker journal, November 2009

A polymer precursor route to metal borides journal, November 1993

Functional Polymeric Materials Based on Main-Group Elements journal, February 2019

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Hypercrosslinked porous polymer materials: design, synthesis, and applications journal, January 2017

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Linear Hybrid Polymer Building Blocks: Methacrylate-Functionalized Polyhedral Oligomeric Silsesquioxane Monomers and Polymers journal, November 1995

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Vulcanization and crosslinking in elastomers journal, January 1997

THE ISOLATION OF THE ICOSAHEDRAL B ₁₂ H ₁₂ ^-2 ION
journal, June 1960

Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane
journal, January 2008

New ligand platforms featuring boron-rich clusters as organomimetic substituents
journal, April 2013

Structural engineering of polyurethane coatings for high performance applications
journal, March 2007

Dodecahydroxy- c loso -dodecaborate(2−)
journal, March 2001

IR-change and yellowing of polyurethane as a result of UV irradiation
journal, April 2009

Full substitution of petroleum-based polyols by phosphorus-containing soy-based polyols for fabricating highly flame-retardant polyisocyanurate foams
journal, August 2018

Thermal degradation of urethanes based on 4,4′-diphenylmethane diisocyanate and 1,4-butanediol (MDI/BDO)
journal, August 1986

Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)
journal, January 2016

Screening flame retardants using milligram-scale flame calorimetry
journal, May 2018

Crosslinked poly(vinyl alcohol) hydrogels for wound dressing applications: A review of remarkably blended polymers
journal, January 2015

Thermal degradation and stability of HTPB-based polyurethane and polyurethaneureas
journal, June 2003

Polymer science with transition metals and main group elements: Towards functional, supramolecular inorganic polymeric materials
journal, December 2001

Polyhedral boron clusters in materials science
journal, January 2011

Nonclassical Applications of closo -Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage
journal, February 2019

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journal, February 2018

Model compounds and monomers for phenylene ether carboranylene ketone (PECK) polymer synthesis: preparation and characterization of boron-arylated ortho-carboranes bearing carboxyphenyl, phenoxyphenyl or benzoylphenyl substituents
journal, March 2002

Polytellurophenes
journal, April 2011

Ultra low density and highly crosslinked biocompatible shape memory polyurethane foams
journal, March 2012

Reactivity of isocyanates with urethanes: Conditions for allophanate formation
journal, November 2005

Synthesis, mechanical properties and fire behaviors of rigid polyurethane foam with a reactive flame retardant containing phosphazene and phosphate
journal, December 2015

Cross-linking dots on metal oxides
journal, April 2019

Polyurethane types, synthesis and applications – a review
journal, January 2016

Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants
journal, May 2016

Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009

Polyurethanes: A class of modern versatile materials
journal, November 1992

Influence of molecular weight and degree of crosslinking on the specific volume and glass temperature of polymers
journal, February 1955

Vegetable oil-based rigid polyurethanes and phosphorylated flame-retardants derived from epoxydized soybean oil
journal, October 2014

A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu ^II Dodecaborate Cluster Complex for Selective Gas Separation
journal, May 2019

Icosahedral boron clusters: a perfect tool for the enhancement of polymer features
journal, January 2016

Thermal degradation of linear polyurethanes and model biscarbamates
journal, March 1973

Luminescent m -Carborane-Based π-Conjugated Polymer
journal, April 2009

Synthesis and Properties of Polyurethane Elastomers with Castor Oil as Crosslinker
journal, November 2009

A polymer precursor route to metal borides
journal, November 1993

Functional Polymeric Materials Based on Main-Group Elements
journal, February 2019

Rapid synthesis of redox-active dodecaborane B ₁₂ (OR) ₁₂ clusters under ambient conditions
journal, January 2016

Hypercrosslinked porous polymer materials: design, synthesis, and applications
journal, January 2017

Glycerol-, pentaerythritol- and trimethylolpropane-based polyurethanes and their cellulose carbonate composites prepared via the non-isocyanate route with catalytic carbon dioxide fixation
journal, January 2013

A novel supramolecular polymer gel constructed by crosslinking pillar[5]arene-based supramolecular polymers through metal–ligand interactions
journal, January 2015

Characterization of hyperporous polyurethane-based gels by non-intrusive mercury porosimetry
journal, August 2003

A molecular cross-linking approach for hybrid metal oxides
journal, March 2018

Linear Hybrid Polymer Building Blocks: Methacrylate-Functionalized Polyhedral Oligomeric Silsesquioxane Monomers and Polymers
journal, November 1995

Synthesis of rigid polyurethane foams with castor oil-based flame retardant polyols
journal, January 2014

Vulcanization and crosslinking in elastomers
journal, January 1997