Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Structure and Bonding in [Sb@In 8 Sb 12 ] 3− and [Sb@In 8 Sb 12 ] 5−

Journal Article · · Angewandte Chemie
 [1];  [2];  [3];  [2];  [4];  [5];  [5];  [6]; ORCiD logo [2]; ORCiD logo [7]
  1. School of Materials Science and Engineering State Key Laboratory of Elemento-Organic Chemistry Tianjin Key Lab for Rare Earth Materials and Applications Centre for Rare earth and inorganic functional materials Nankai University Tianjin 300350 China, College of Chemistry and Chemical Engineering Central South University Changsha 410083 Hunan P. R. China
  2. Department of Chemistry and Biochemistry Utah State University 0300, Old Main Hill Logan Utah 84322-0300 USA
  3. Theoretical Division Los Alamos National Laboratory Los Alamos New Mexico 87545 USA
  4. State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin Street Changchun Jilin 130022 China
  5. Department of Chemistry and Key Laboratory of Organic Optoelectronics &, Molecular Engineering of Ministry of Education Tsinghua University Beijing 100084 China
  6. Department of Chemistry University of Oxford South Parks Road Oxford OX1 3QZ UK
  7. School of Materials Science and Engineering State Key Laboratory of Elemento-Organic Chemistry Tianjin Key Lab for Rare Earth Materials and Applications Centre for Rare earth and inorganic functional materials Nankai University Tianjin 300350 China, State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin Street Changchun Jilin 130022 China
+ Show Author Affiliations

Abstract We report the characterization of the compound [K([2.2.2]crypt)] 4 [In 8 Sb 13 ], which proves to contain a 1:1 mixture of [Sb@In 8 Sb 12 ] 3− and [Sb@In 8 Sb 12 ] 5− . The tri‐anion displays perfect T h symmetry, the first completely inorganic molecule to do so, and contains eight equivalent In 3+ centers in a cube. The gas‐phase potential energy surface of the penta‐anion has eight equivalent minima where the extra pair of electrons is localized on one In + center, and these minima are linked by low‐lying transition states where the electron pair is delocalized over two adjacent centers. The best fit to the electron density is obtained from a model where the structure of the 5− cluster lies close to the gas‐phase transition state.

Sponsoring Organization:
USDOE
Grant/Contract Number:
89233218CNA000001
OSTI ID:
1525542
Journal Information:
Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 25 Vol. 131; ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

References (64)

Materielle Organisationsformen: ein anorganisches Superfulleren und Keplerat auf Molybdänsauerstoffbasis journal December 1998
Hexasupersilyloctaindan (tBu3Si)6In8 – eine Verbindung mit einem neuartigen In8-Clustergerüst journal September 1999
Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide journal December 1998
Hexasupersilyloctaindane (tBu3Si)6In8— A Compound with a Novel In8 Cluster Framework journal September 1999
Spherical Homoaromaticity journal November 2002
[Pt@Pb12]2− journal April 2004
Al50C120H180: Eine Pseudofullerenhülle aus 60 Kohlenstoffatomen und 60 Methylgruppen schützt einen Clusterkern aus 50 Aluminiumatomen journal June 2004
Endohedral Stannaspherenes M@Sn12−: A Rich Class of Stable Molecular Cage Clusters journal January 2007
[Co@Ge 10 ] 3− : An Intermetalloid Cluster with Archimedean Pentagonal Prismatic Structure journal March 2009
Zintl-Ionen, Käfigverbindungen und intermetalloide Cluster der Elemente der 14. und 15. Gruppe journal March 2011
[Eu@Sn6Bi8]4−: Ein Mini-Fulleran-artiges Zintl-Anion mit interstitiellem Lanthanoidion journal December 2010
{[CuSn 5 Sb 3 ] 2− } 2 : Ein Dimer inhomogener Superatome journal August 2016
(Ge 4 Bi 14 ) 4− : Ein Fall von “Element-Entmischung” auf molekularer Skala journal February 2017
Zwischen Lokalisierung und Delokalisierung: Ru(cod) 2+ -Einheiten in den Zintl-Clustern [Bi 9 {Ru(cod)} 2 ] 3− und [Tl 2 Bi 6 {Ru(cod)}] 2− journal September 2017
[Co@Sn 6 Sb 6 ] 3− : Ein endohedraler 12‐Atom‐Cluster mit einem nicht‐zentrierten inneren Atom journal October 2018
Polybismutid‐Anionen als Liganden: der homoleptische Komplex [(Bi 7 )Cd(Bi 7 )] 4− und der ternäre Cluster [(Bi 6 )Zn 3 (TlBi 5 )] 4− journal January 2019
[Pt@Pb12]2− journal April 2004
Al50C120H180: A Pseudofullerene Shell of 60 Carbon Atoms and 60 Methyl Groups Protecting a Cluster Core of 50 Aluminum Atoms journal June 2004
Endohedral Stannaspherenes M@Sn12−: A Rich Class of Stable Molecular Cage Clusters journal January 2007
[Co@Ge 10 ] 3− : An Intermetalloid Cluster with Archimedean Pentagonal Prismatic Structure journal March 2009
Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements journal March 2011
[Eu@Sn6Bi8]4−: A Mini-Fullerane-Type Zintl Anion Containing a Lanthanide Ion journal December 2010
{[CuSn 5 Sb 3 ] 2− } 2 : A Dimer of Inhomogeneous Superatoms journal August 2016
(Ge 4 Bi 14 ) 4− : A Case of “Element Segregation” on the Molecular Level journal February 2017
Between Localization and Delocalization: Ru(cod) 2+ Units in the Zintl Clusters [Bi 9 {Ru(cod)} 2 ] 3− and [Tl 2 Bi 6 {Ru(cod)}] 2− journal September 2017
[Co@Sn 6 Sb 6 ] 3− : An Off-Center Endohedral 12-Vertex Cluster journal October 2018
Polybismuthide Anions as Ligands: The Homoleptic Complex [(Bi 7 )Cd(Bi 7 )] 4− and the Ternary Cluster [(Bi 6 )Zn 3 (TlBi 5 )] 4− journal January 2019
[Cu@Sn9]3− and [Cu@Pb9]3−: Intermetalloid Clusters with Endohedral Cu Atoms in Spherical Environments journal May 2008
Step-by-Step Synthesis of the Endohedral Stannaspherene [Ir@Sn 12 ] 3− via the Capped Cluster Anion [Sn 9 Ir(cod)] 3− journal February 2010
[Co 2 @Ge 16 ] 4− : Localized versus Delocalized Bonding in Two Isomeric Intermetalloid Clusters journal December 2017
Preparation of [Et2InSb(SiMe3)2]3; a trimeric single-source precursor to indium antimonide journal March 2000
High-Symmetry Coordination Cages via Self-Assembly journal November 2002
[(Pd−Pd)@Ge 18 ] 4- :  A Palladium Dimer Inside the Largest Single-Cage Deltahedron journal June 2005
The Pb 12 2 - and Pb 10 2- Zintl Ions and the M@Pb 12 2 - and M@Pb 10 2 - Cluster Series Where M = Ni, Pd, Pt journal July 2006
Sn 12 2- :  Stannaspherene journal July 2006
Pd 2 @Sn 18 4- :  Fusion of Two Endohedral Stannaspherenes journal August 2007
[Pd 3 Sn 8 Bi 6 ] 4– : A 14-Vertex Sn/Bi Cluster Embedding a Pd 3 Triangle journal September 2011
A Bronze Matryoshka: The Discrete Intermetalloid Cluster [Sn@Cu 12 @Sn 20 ] 12– in the Ternary Phases A 12 Cu 12 Sn 21 (A = Na, K) journal December 2011
Doped Semimetal Clusters: Ternary, Intermetalloid Anions [Ln@Sn 7 Bi 7 ] 4– and [Ln@Sn 4 Bi 9 ] 4– (Ln = La, Ce) with Adjustable Magnetic Properties journal December 2011
Synthesis and Characterization of [Ru@Ge 12 ] 3– : An Endohedral 3-Connected Cluster
  • Espinoza-Quintero, Gabriela; Duckworth, Jack C. A.; Myers, William K.
  • Journal of the American Chemical Society, Vol. 136, Issue 4 https://doi.org/10.1021/ja411280v
journal January 2014
Synthesis and Isolation of [Fe@Ge 10 ] 3− : A Pentagonal Prismatic Zintl Ion Cage Encapsulating an Interstitial Iron Atom journal March 2009
Fullerene-like Polyoxotitanium Cage with High Solution Stability journal February 2016
Main Group Metal–Actinide Magnetic Coupling and Structural Response Upon U 4+ Inclusion Into Bi, Tl/Bi, or Pb/Bi Cages journal July 2016
Sb@Ni 12 @Sb 20 –/+ and Sb@Pd 12 @Sb 20 n Cluster Anions, Where n = +1, −1, −3, −4: Multi-Oxidation-State Clusters of Interpenetrating Platonic Solids journal January 2017
Revealing Intuitively Assessable Chemical Bonding Patterns in Organic Aromatic Molecules via Adaptive Natural Density Partitioning journal December 2008
Pb 12 2- :  Plumbaspherene journal August 2006
The Aromatic 8-Electron Cubic Silicon Clusters Be@Si 8 , B@Si 8 + , and C@Si 8 2+ journal July 2010
Additive Covalent Radii for Single-, Double-, and Triple-Bonded Molecules and Tetrahedrally Bonded Crystals: A Summary journal September 2014
Reactions of Distibines Sb 2 R 4 and Dibismuthine Bi 2 Et 4 with Trialkyltrieles MR 3 journal July 2004
Self-assembly of nanoscale cuboctahedra by coordination chemistry journal April 1999
C60: Buckminsterfullerene journal November 1985
Understanding of multimetallic cluster growth journal January 2016
A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions journal January 2011
[(ZnSb 6 ) 2 ] 4− : a new structure type for coupled norbornadiene-like subunits journal January 2017
Counterion-induced crystallization of intermetalloid Matryoshka clusters [Sb@Pd 12 @Sb 20 ] 3−,4− journal January 2017
Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn 10 ] 3– , [Rh@Sn 12 ] 3– , [Rh 2 @Sn 17 ] 6– and the first triply-fused stannide, [Rh 3 @Sn 24 ] 5– journal January 2019
The closo-Pb102? Zintl ion in the [Ni@Pb10]2? cluster journal January 2005
”Developing paradigms of chemical bonding: adaptive natural density partitioning journal January 2008
Extremely Stable Metal-Encapsulated AlPb 10 + and AlPb 12 + Clusters: Mass-Spectrometric Discovery and Density Functional Theory Study journal April 2004
Structure Correlation and Chemistry journal November 1998
Synthesis of Inorganic Fullerene-Like Molecules journal May 2003
Interpenetrating As20 Fullerene and Ni12 Icosahedra in the Onion-Skin [As@Ni12@As20]3- Ion journal May 2003
CHEMISTRY: The Beauty of Symmetry journal May 2003
Ti8C12+-Metallo-Carbohedrenes: A New Class of Molecular Clusters? journal March 1992

Similar Records

Related Subjects