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Title: Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion

Abstract

Incorporation of Nb into the [P 8 W 48 O 184 ] 40− anionic macrocyclic cavitand leads to formation of new Nb–W POMs. Inclusion of up to five {NbO(H 2 O)} 3+ groups was observed. Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and SAXS.

Authors:
 [1]; ORCiD logo [1]; ORCiD logo [2];  [1];  [3]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [4]
  1. Nikolaev Institute of Inorganic Chemistry, Novosibirsk, Russia
  2. Novosibirsk State University, Novosibirsk, Russia, International Tomography Center, Novosibirsk
  3. Department of Chemistry Oregon State University, Oregon 97331-4003, USA
  4. Nikolaev Institute of Inorganic Chemistry, Novosibirsk, Russia, Novosibirsk State University, Novosibirsk
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1525505
Grant/Contract Number:  
DE SC0010802
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
New Journal of Chemistry
Additional Journal Information:
Journal Name: New Journal of Chemistry Journal Volume: 43 Journal Issue: 25; Journal ID: ISSN 1144-0546
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Shmakova, Alexandra A., Volchek, Victoria V., Yanshole, Vadim, Kompankov, Nikolay B., Martin, Nicolas P., Nyman, May, Abramov, Pavel A., and Sokolov, Maxim N. Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion. United Kingdom: N. p., 2019. Web. doi:10.1039/C9NJ01907C.
Shmakova, Alexandra A., Volchek, Victoria V., Yanshole, Vadim, Kompankov, Nikolay B., Martin, Nicolas P., Nyman, May, Abramov, Pavel A., & Sokolov, Maxim N. Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion. United Kingdom. doi:10.1039/C9NJ01907C.
Shmakova, Alexandra A., Volchek, Victoria V., Yanshole, Vadim, Kompankov, Nikolay B., Martin, Nicolas P., Nyman, May, Abramov, Pavel A., and Sokolov, Maxim N. Mon . "Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion". United Kingdom. doi:10.1039/C9NJ01907C.
@article{osti_1525505,
title = {Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion},
author = {Shmakova, Alexandra A. and Volchek, Victoria V. and Yanshole, Vadim and Kompankov, Nikolay B. and Martin, Nicolas P. and Nyman, May and Abramov, Pavel A. and Sokolov, Maxim N.},
abstractNote = {Incorporation of Nb into the [P 8 W 48 O 184 ] 40− anionic macrocyclic cavitand leads to formation of new Nb–W POMs. Inclusion of up to five {NbO(H 2 O)} 3+ groups was observed. Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and SAXS.},
doi = {10.1039/C9NJ01907C},
journal = {New Journal of Chemistry},
number = 25,
volume = 43,
place = {United Kingdom},
year = {2019},
month = {6}
}

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