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Title: Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion

Journal Article · · New Journal of Chemistry
DOI: https://doi.org/10.1039/C9NJ01907C · OSTI ID:1525505
 [1]; ORCiD logo [1]; ORCiD logo [2];  [1];  [3]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [4]
  1. Nikolaev Institute of Inorganic Chemistry, Novosibirsk, Russia
  2. Novosibirsk State University, Novosibirsk, Russia, International Tomography Center, Novosibirsk
  3. Department of Chemistry Oregon State University, Oregon 97331-4003, USA
  4. Nikolaev Institute of Inorganic Chemistry, Novosibirsk, Russia, Novosibirsk State University, Novosibirsk
+ Show Author Affiliations

Incorporation of Nb into the [P 8 W 48 O 184 ] 40− anionic macrocyclic cavitand leads to formation of new Nb–W POMs. Inclusion of up to five {NbO(H 2 O)} 3+ groups was observed. Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and SAXS.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0010802
OSTI ID:
1525505
Journal Information:
New Journal of Chemistry, Journal Name: New Journal of Chemistry Journal Issue: 25 Vol. 43; ISSN NJCHE5; ISSN 1144-0546
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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