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Title: Photolysis of Tp′Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C–H bonds

Abstract

The competitive activation of the various C–H bonds found in ketones and esters by a trispyrazolylborate rhodium complex are compared.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, University of Rochester, Rochester, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1525503
Grant/Contract Number:  
FG02-86ER13569
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 29; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Parsons, Astrid M., and Jones, William D. Photolysis of Tp′Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C–H bonds. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT01802F.
Parsons, Astrid M., & Jones, William D. Photolysis of Tp′Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C–H bonds. United Kingdom. doi:10.1039/C9DT01802F.
Parsons, Astrid M., and Jones, William D. Tue . "Photolysis of Tp′Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C–H bonds". United Kingdom. doi:10.1039/C9DT01802F.
@article{osti_1525503,
title = {Photolysis of Tp′Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C–H bonds},
author = {Parsons, Astrid M. and Jones, William D.},
abstractNote = {The competitive activation of the various C–H bonds found in ketones and esters by a trispyrazolylborate rhodium complex are compared.},
doi = {10.1039/C9DT01802F},
journal = {Dalton Transactions},
number = 29,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {7}
}

Journal Article:
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