DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Engineering porous organic polymers for carbon dioxide capture

Journal Article · · Science China Chemistry
 [1];  [2];  [2];  [2];  [2]
  1. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry; Texas A&M University
  2. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry

As atmospheric CO2 levels rise, the development of physical or chemical adsorbents for CO2 capture and separation is of great importance on the way towards a sustainable low-carbon future. Porous organic polymers are promising candidates for CO2 capture materials owing to their structural flexibility, high surface area, and high stability. We highlight high-performance porous organic polymers for CO2 capture and summarize the strategies to enhance CO2 uptake and selectivity, such as increasing surface area, increasing interaction between porous organic polymers and CO2, and pore surface functionalization.

Research Organization:
Texas A & M Univ., College Station, TX (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
Grant/Contract Number:
FE0026472
OSTI ID:
1525349
Journal Information:
Science China Chemistry, Journal Name: Science China Chemistry Journal Issue: 8 Vol. 60; ISSN 1674-7291
Publisher:
Science China Press and SpringerCopyright Statement
Country of Publication:
United States
Language:
English

References (54)

Charged Covalent Triazine Frameworks for CO 2 Capture and Conversion journal February 2017
Highly Selective CO 2 Capture by Triazine-Based Benzimidazole-Linked Polymers journal November 2014
Highly Selective CO2-Capturing Polymeric Organic Network Structures journal January 2012
Phloroglucinol Based Microporous Polymeric Organic Frameworks with −OH Functional Groups and High CO 2 Capture Capacity journal April 2011
High CO 2 uptake and selectivity by triptycene-derived benzimidazole-linked polymers journal January 2012
A novel metalporphyrin-based microporous organic polymer with high CO 2 uptake and efficient chemical conversion of CO 2 under ambient conditions journal January 2017
CO2 capture from atmospheric air via consecutive CaO-carbonation and CaCO3-calcination cycles in a fluidized-bed solar reactor journal February 2009
Chemical tuning of CO2 sorption in robust nanoporous organic polymers journal January 2011
Dispelling some myths about the CO 2 solubility in ionic liquids journal January 2016
Air as the renewable carbon source of the future: an overview of CO2 capture from the atmosphere journal January 2012
Efficient CO2 capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups journal January 2014
Microporous Polycarbazole with High Specific Surface Area for Gas Storage and Separation journal March 2012
Template-Free Synthesis of a Highly Porous Benzimidazole-Linked Polymer for CO 2 Capture and H 2 Storage journal April 2011
Phosphonium salt incorporated hypercrosslinked porous polymers for CO 2 capture and conversion journal January 2015
Copper(I)-Catalyzed Synthesis of Nanoporous Azo-Linked Polymers: Impact of Textural Properties on Gas Storage and Selective Carbon Dioxide Capture journal January 2014
Amine-impregnated silica monolith with a hierarchical pore structure: enhancement of CO2 capture capacity journal January 2009
An overview of activated carbons utilization for the post-combustion carbon dioxide capture journal March 2016
Conjugated Microporous Polymers journal March 2009
Introduction to Metal–Organic Frameworks journal September 2011
Sulfonate-Grafted Porous Polymer Networks for Preferential CO2 Adsorption at Low Pressure journal November 2011
Synthesis, Properties, and Gas Separation Studies of a Robust Diimide-Based Microporous Organic Polymer journal July 2009
Microporous organic polymers based on tetraethynyl building blocks with N-functionalized pore surfaces: synthesis, porosity and carbon dioxide sorption journal January 2016
Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas journal June 2012
Hypercrosslinked organic polymer networks as potential adsorbents for pre-combustion CO2 capture journal January 2011
An Ultrahigh Pore Volume Drives Up the Amine Stability and Cyclic CO 2 Capacity of a Solid-Amine@Carbon Sorbent journal July 2015
High Surface Area Networks from Tetrahedral Monomers: Metal-Catalyzed Coupling, Thermal Polymerization, and “Click” Chemistry journal October 2010
Carbon Dioxide Capture in Metal–Organic Frameworks journal September 2011
CO2 Capture by a Task-Specific Ionic Liquid journal February 2002
Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area journal November 2009
Introduction of π-Complexation into Porous Aromatic Framework for Highly Selective Adsorption of Ethylene over Ethane journal June 2014
Nitrogen-rich conjugated microporous polymers: impact of building blocks on porosity and gas adsorption journal January 2015
Tailor-Made Pore Surface Engineering in Covalent Organic Frameworks: Systematic Functionalization for Performance Screening journal June 2015
Triptycene-Based Microporous Polymers: Synthesis and Their Gas Storage Properties journal December 2011
Synthesis and Characterization of Porous Benzimidazole-Linked Polymers and Their Performance in Small Gas Storage and Selective Uptake journal April 2012
Rational design and synthesis of a porous, task-specific polycarbazole for efficient CO 2 capture journal January 2016
Indolo[3,2-b]carbazole-containing hypercrosslinked microporous polymer networks for gas storage and separation journal July 2016
Carbon Dioxide Capture from Atmospheric Air Using Sodium Hydroxide Spray journal April 2008
Conjugated microporous polymers: design, synthesis and application journal January 2013
Carbon dioxide capture in amorphous porous organic polymers journal January 2017
Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage journal January 2006
Impact of Water Coadsorption for Carbon Dioxide Capture in Microporous Polymer Sorbents journal June 2012
In Situ Doping Strategy for the Preparation of Conjugated Triazine Frameworks Displaying Efficient CO 2 Capture Performance journal September 2016
Hypercrosslinked porous polymer materials: design, synthesis, and applications journal January 2017
Tunable porosity of nanoporous organic polymers with hierarchical pores for enhanced CO 2 capture journal January 2016
Synthesis of covalent triazine-based frameworks with high CO 2 adsorption and selectivity journal January 2015
High CO 2 -Capture Ability of a Porous Organic Polymer Bifunctionalized with Carboxy and Triazole Groups journal July 2013
Nitrogen-rich diaminotriazine-based porous organic polymers for small gas storage and selective uptake journal January 2013
Synthesis of microporous polymers by Friedel–Crafts reaction of 1-bromoadamantane with aromatic compounds and their surface modification journal January 2012
Triazatriangulenium-based porous organic polymers for carbon dioxide capture journal January 2015
Beyond pristine MOFs: carbon dioxide capture by metal–organic frameworks (MOFs)-derived porous carbon materials journal January 2017
Highly Stable Porous Polymer Networks with Exceptionally High Gas-Uptake Capacities journal July 2011
Cost-Effective Synthesis of Amine-Tethered Porous Materials for Carbon Capture journal October 2014
Porous covalent electron-rich organonitridic frameworks as highly selective sorbents for methane and carbon dioxide journal July 2011
Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization journal January 2015

Cited By (5)

Design and synthesis of a multifunctional porous N-rich polymer containing s -triazine and Tröger's base for CO 2 adsorption, catalysis and sensing journal January 2018
Direct synthesis of an aliphatic amine functionalized metal–organic framework for efficient CO 2 removal and CH 4 purification journal January 2018
Improving Alkylamine Incorporation in Porous Polymer Networks through Dopant Incorporation journal October 2019
Hexamethylcucurbit[3,3]uril-Based Porous Supramolecular Assemblies and Their Adsorption Properties journal August 2018
Carbon doping of hexagonal boron nitride porous materials toward CO 2 capture journal January 2018