skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Flexible monomer-based covalent organic frameworks: design, structure and functions

Abstract

The design and synthesis of flexible monomer-based covalent organic frameworks (COFs) have been considered a challenge. We describe the design and synthesis of a new flexible monomer-based COF, termed PPN-30 (PPN meaning porous polymer network), by the use of a flexible alkyl amine, 1,4-cyclohexanediamine, combined with 1,3,5-triformylbenzene. The structure and gas adsorption properties of PPN-30 were carefully investigated.

Authors:
ORCiD logo [1];  [1];  [1]; ORCiD logo [2]
  1. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
  2. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering
Publication Date:
Research Org.:
Texas A & M Univ., College Station, TX (United States)
Sponsoring Org.:
USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1525347
Grant/Contract Number:  
FE0026472; SC0001015; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
CrystEngComm
Additional Journal Information:
Journal Volume: 19; Journal Issue: 33; Journal ID: ISSN 1466-8033
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Zou, Lanfang, Yang, Xinyu, Yuan, Shuai, and Zhou, Hong-Cai. Flexible monomer-based covalent organic frameworks: design, structure and functions. United States: N. p., 2017. Web. doi:10.1039/c7ce00593h.
Zou, Lanfang, Yang, Xinyu, Yuan, Shuai, & Zhou, Hong-Cai. Flexible monomer-based covalent organic frameworks: design, structure and functions. United States. doi:10.1039/c7ce00593h.
Zou, Lanfang, Yang, Xinyu, Yuan, Shuai, and Zhou, Hong-Cai. Wed . "Flexible monomer-based covalent organic frameworks: design, structure and functions". United States. doi:10.1039/c7ce00593h. https://www.osti.gov/servlets/purl/1525347.
@article{osti_1525347,
title = {Flexible monomer-based covalent organic frameworks: design, structure and functions},
author = {Zou, Lanfang and Yang, Xinyu and Yuan, Shuai and Zhou, Hong-Cai},
abstractNote = {The design and synthesis of flexible monomer-based covalent organic frameworks (COFs) have been considered a challenge. We describe the design and synthesis of a new flexible monomer-based COF, termed PPN-30 (PPN meaning porous polymer network), by the use of a flexible alkyl amine, 1,4-cyclohexanediamine, combined with 1,3,5-triformylbenzene. The structure and gas adsorption properties of PPN-30 were carefully investigated.},
doi = {10.1039/c7ce00593h},
journal = {CrystEngComm},
number = 33,
volume = 19,
place = {United States},
year = {2017},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: a) The synthetic procedure for PPN-30 and b) The simulated structure of PPN-30 with the detailed connection represented. Carbon and nitrogen are represented as grey and blue spheres, respectively.

Save / Share:

Works referenced in this record:

Covalent Organic Frameworks for CO 2 Capture
journal, February 2016


Chemically Stable Covalent Organic Framework (COF)-Polybenzimidazole Hybrid Membranes: Enhanced Gas Separation through Pore Modulation
journal, February 2016

  • Biswal, Bishnu P.; Chaudhari, Harshal D.; Banerjee, Rahul
  • Chemistry - A European Journal, Vol. 22, Issue 14
  • DOI: 10.1002/chem.201504836

Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization
journal, January 2015

  • Huang, Ning; Chen, Xiong; Krishna, Rajamani
  • Angewandte Chemie International Edition, Vol. 54, Issue 10
  • DOI: 10.1002/anie.201411262

Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation
journal, July 2016

  • Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12104

Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts
journal, September 2015

  • Xu, Hong; Gao, Jia; Jiang, Donglin
  • Nature Chemistry, Vol. 7, Issue 11
  • DOI: 10.1038/nchem.2352

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015


Three-Dimensional Covalent Organic Frameworks with Dual Linkages for Bifunctional Cascade Catalysis
journal, October 2016

  • Li, Hui; Pan, Qinying; Ma, Yunchao
  • Journal of the American Chemical Society, Vol. 138, Issue 44
  • DOI: 10.1021/jacs.6b09563

Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis
journal, September 2016

  • Wang, Xiuren; Han, Xing; Zhang, Jie
  • Journal of the American Chemical Society, Vol. 138, Issue 38
  • DOI: 10.1021/jacs.6b07714

A bifunctional covalent organic framework as an efficient platform for cascade catalysis
journal, January 2017

  • Sun, Qi; Aguila, Briana; Ma, Shengqian
  • Materials Chemistry Frontiers, Vol. 1, Issue 7
  • DOI: 10.1039/C6QM00363J

Chemical sensing in two dimensional porous covalent organic nanosheets
journal, January 2015

  • Das, Gobinda; Biswal, Bishnu P.; Kandambeth, Sharath
  • Chemical Science, Vol. 6, Issue 7
  • DOI: 10.1039/C5SC00512D

Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II)
journal, February 2016

  • Ding, San-Yuan; Dong, Ming; Wang, Ya-Wen
  • Journal of the American Chemical Society, Vol. 138, Issue 9
  • DOI: 10.1021/jacs.5b10754

3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery
journal, June 2015

  • Fang, Qianrong; Wang, Junhua; Gu, Shuang
  • Journal of the American Chemical Society, Vol. 137, Issue 26
  • DOI: 10.1021/jacs.5b04147

Targeted Drug Delivery in Covalent Organic Nanosheets (CONs) via Sequential Postsynthetic Modification
journal, March 2017

  • Mitra, Shouvik; Sasmal, Himadri Sekhar; Kundu, Tanay
  • Journal of the American Chemical Society, Vol. 139, Issue 12
  • DOI: 10.1021/jacs.7b00925

Two-Dimensional π -Conjugated Covalent-Organic Frameworks as Quantum Anomalous Hall Topological Insulators
journal, February 2016


Postsynthetically Modified Covalent Organic Frameworks for Efficient and Effective Mercury Removal
journal, February 2017

  • Sun, Qi; Aguila, Briana; Perman, Jason
  • Journal of the American Chemical Society, Vol. 139, Issue 7
  • DOI: 10.1021/jacs.6b12885

Flexibility Matters: Cooperative Active Sites in Covalent Organic Framework and Threaded Ionic Polymer
journal, November 2016

  • Sun, Qi; Aguila, Briana; Perman, Jason
  • Journal of the American Chemical Society, Vol. 138, Issue 48
  • DOI: 10.1021/jacs.6b10629

Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005

  • Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
  • Science, Vol. 310, Issue 5751, p. 1166-1170
  • DOI: 10.1126/science.1120411

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007

  • El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L.
  • Science, Vol. 316, Issue 5822, p. 268-272
  • DOI: 10.1126/science.1139915

Covalent organic frameworks: a materials platform for structural and functional designs
journal, September 2016


Multiple-component covalent organic frameworks
journal, July 2016

  • Huang, Ning; Zhai, Lipeng; Coupry, Damien E.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12325

Covalent organic frameworks
journal, January 2012

  • Feng, Xiao; Ding, Xuesong; Jiang, Donglin
  • Chemical Society Reviews, Vol. 41, Issue 18
  • DOI: 10.1039/c2cs35157a

Colloidal Covalent Organic Frameworks
journal, January 2017


Construction of Covalent Organic Frameworks Bearing Three Different Kinds of Pores through the Heterostructural Mixed Linker Strategy
journal, March 2016

  • Pang, Zhong-Fu; Xu, Shun-Qi; Zhou, Tian-You
  • Journal of the American Chemical Society, Vol. 138, Issue 14
  • DOI: 10.1021/jacs.6b01244

The atom, the molecule, and the covalent organic framework
journal, March 2017


Thiophene-based covalent organic frameworks
journal, March 2013

  • Bertrand, G. H. V.; Michaelis, V. K.; Ong, T. -C.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 13
  • DOI: 10.1073/pnas.1221824110

Functionalization of 3D covalent organic frameworks using monofunctional boronic acids
journal, January 2014


Lewis acid-catalysed formation of two-dimensional phthalocyanine covalent organic frameworks
journal, June 2010

  • Spitler, Eric L.; Dichtel, William R.
  • Nature Chemistry, Vol. 2, Issue 8, p. 672-677
  • DOI: 10.1038/nchem.695

Single-Crystal Structure of a Covalent Organic Framework
journal, October 2013

  • Zhang, Yue-Biao; Su, Jie; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 135, Issue 44
  • DOI: 10.1021/ja409033p

A hydrazone-based covalent organic framework for photocatalytic hydrogen production
journal, January 2014

  • Stegbauer, Linus; Schwinghammer, Katharina; Lotsch, Bettina V.
  • Chem. Sci., Vol. 5, Issue 7
  • DOI: 10.1039/C4SC00016A

Sub-micron spheres of an imine-based covalent organic framework: supramolecular functionalization and water-dispersibility
journal, January 2017

  • Rodríguez-San-Miguel, David; Corral-Pérez, Juan J.; Gil-González, Eva
  • CrystEngComm, Vol. 19, Issue 33
  • DOI: 10.1039/C6CE02200F

3D Microporous Base-Functionalized Covalent Organic Frameworks for Size-Selective Catalysis
journal, February 2014

  • Fang, Qianrong; Gu, Shuang; Zheng, Jie
  • Angewandte Chemie International Edition, Vol. 53, Issue 11
  • DOI: 10.1002/anie.201310500

Construction of Crystalline 2D Covalent Organic Frameworks with Remarkable Chemical (Acid/Base) Stability via a Combined Reversible and Irreversible Route
journal, November 2012

  • Kandambeth, Sharath; Mallick, Arijit; Lukose, Binit
  • Journal of the American Chemical Society, Vol. 134, Issue 48
  • DOI: 10.1021/ja308278w

Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks
journal, March 2013

  • Biswal, Bishnu P.; Chandra, Suman; Kandambeth, Sharath
  • Journal of the American Chemical Society, Vol. 135, Issue 14
  • DOI: 10.1021/ja4017842

Enhancement of Chemical Stability and Crystallinity in Porphyrin-Containing Covalent Organic Frameworks by Intramolecular Hydrogen Bonds
journal, October 2013

  • Kandambeth, Sharath; Shinde, Digambar Balaji; Panda, Manas K.
  • Angewandte Chemie International Edition, Vol. 52, Issue 49
  • DOI: 10.1002/anie.201306775

Adsorption of Structural and Stereoisomers of Cyclohexanediamine at the Ge(100)-2 × 1 Surface: Geometric Effects in Adsorption on a Semiconductor Surface
journal, September 2013

  • Wong, Keith T.; Bent, Stacey F.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 37
  • DOI: 10.1021/jp406423n

    Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.