Flexible monomer-based covalent organic frameworks: design, structure and functions

Zou, Lanfang; Yang, Xinyu; Yuan, Shuai; Zhou, Hong-Cai

doi:10.1039/c7ce00593h

Title: Flexible monomer-based covalent organic frameworks: design, structure and functions

Abstract

The design and synthesis of flexible monomer-based covalent organic frameworks (COFs) have been considered a challenge. We describe the design and synthesis of a new flexible monomer-based COF, termed PPN-30 (PPN meaning porous polymer network), by the use of a flexible alkyl amine, 1,4-cyclohexanediamine, combined with 1,3,5-triformylbenzene. The structure and gas adsorption properties of PPN-30 were carefully investigated.

Authors:

^[1]; Yang, Xinyu ^[1]; Yuan, Shuai ^[1];

^[2]

Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering

Publication Date:: 2017-04-12

Research Org.:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1525347

Grant/Contract Number:: FE0026472; SC0001015; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: CrystEngComm

Additional Journal Information:: Journal Volume: 19; Journal Issue: 33; Journal ID: ISSN 1466-8033

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zou, Lanfang, Yang, Xinyu, Yuan, Shuai, and Zhou, Hong-Cai. Flexible monomer-based covalent organic frameworks: design, structure and functions.  United States: N. p., 2017. 
Web.  doi:10.1039/c7ce00593h.

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                    Zou, Lanfang, Yang, Xinyu, Yuan, Shuai, & Zhou, Hong-Cai. Flexible monomer-based covalent organic frameworks: design, structure and functions.  United States.  https://doi.org/10.1039/c7ce00593h

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                    Zou, Lanfang, Yang, Xinyu, Yuan, Shuai, and Zhou, Hong-Cai. Wed .  
"Flexible monomer-based covalent organic frameworks: design, structure and functions".  United States.  https://doi.org/10.1039/c7ce00593h.  https://www.osti.gov/servlets/purl/1525347.

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@article{osti_1525347,

  title        = {Flexible monomer-based covalent organic frameworks: design, structure and functions},

  author       = {Zou, Lanfang and Yang, Xinyu and Yuan, Shuai and Zhou, Hong-Cai},

  abstractNote = {The design and synthesis of flexible monomer-based covalent organic frameworks (COFs) have been considered a challenge. We describe the design and synthesis of a new flexible monomer-based COF, termed PPN-30 (PPN meaning porous polymer network), by the use of a flexible alkyl amine, 1,4-cyclohexanediamine, combined with 1,3,5-triformylbenzene. The structure and gas adsorption properties of PPN-30 were carefully investigated.},

  doi          = {10.1039/c7ce00593h},

  journal      = {CrystEngComm},

  number       = 33,

  volume       = 19,

  place        = {United States},

  year         = {2017},

  month        = {4}

}

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https://doi.org/10.1039/c7ce00593h

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Cited by: 14 works

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Figures / Tables:

Figure 1: a) The synthetic procedure for PPN-30 and b) The simulated structure of PPN-30 with the detailed connection represented. Carbon and nitrogen are represented as grey and blue spheres, respectively.

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Title: Flexible monomer-based covalent organic frameworks: design, structure and functions

Abstract

Citation Formats

Figures / Tables:

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