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Title: Flexible monomer-based covalent organic frameworks: design, structure and functions

Journal Article · · CrystEngComm
DOI: https://doi.org/10.1039/c7ce00593h · OSTI ID:1525347
ORCiD logo [1];  [1];  [1]; ORCiD logo [2]
  1. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
  2. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering

The design and synthesis of flexible monomer-based covalent organic frameworks (COFs) have been considered a challenge. We describe the design and synthesis of a new flexible monomer-based COF, termed PPN-30 (PPN meaning porous polymer network), by the use of a flexible alkyl amine, 1,4-cyclohexanediamine, combined with 1,3,5-triformylbenzene. The structure and gas adsorption properties of PPN-30 were carefully investigated.

Research Organization:
Texas A & M Univ., College Station, TX (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
FE0026472; SC0001015; AC02-06CH11357
OSTI ID:
1525347
Journal Information:
CrystEngComm, Vol. 19, Issue 33; ISSN 1466-8033
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 16 works
Citation information provided by
Web of Science

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Cited By (4)

Covalent Organic Frameworks: Structures, Synthesis, and Applications journal July 2018
High‐Precision Size Recognition and Separation in Synthetic 1D Nanochannels journal September 2019
High‐Precision Size Recognition and Separation in Synthetic 1D Nanochannels journal September 2019
Designed synthesis of stable light-emitting two-dimensional sp2 carbon-conjugated covalent organic frameworks journal October 2018

Figures / Tables (5)