Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters

Horwitz, Noah E.; Xie, Jiaze; Filatov, Alexander S.; Papoular, Robert J.; Shepard, William E.; Zee, David Z.; Grahn, Mia P.; Gilder, Chloe; Anderson, John S.

doi:10.1021/jacs.8b12339

Title: Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters

Journal Article · 04 February 2019 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.8b12339 · OSTI ID:1524597

Horwitz, Noah E. ^[1]; Xie, Jiaze ^[1];

^[1]; Papoular, Robert J. ^[2];

^[3]; Zee, David Z. ^[4]; Grahn, Mia P. ^[1]; Gilder, Chloe ^[1];

^[1]

Univ. of Chicago, Chicago, IL (United States)
Saclay Institute for Matter and Radiation (IRAMIS), Gif-sur-Yvette (France)
Synchrotron SOLEIL, Gif-sur-Yvette (France)
Northwestern Univ., Evanston, IL (United States)

Here we describe the combination of an archetypal redox-active metal sulfide cluster, Fe₄S₄, with an organic linker, 1,4-benzenedithiolate, to prepare coordination polymers containing infinite chains of Fe₄S₄ clusters. The crystal structures of two solid materials have been solved from synchrotron X-ray powder diffraction data using simulated annealing and re-fined by a least-squares Rietveld refinement procedure. The electronic properties of these chains have also been characterized by UV-visible and Mössbauer spectroscopies. Additional experiments demonstrated that these chains can be solubilized by variation of the countercation and that the chain structure is maintained in solution. The redox-activity of the Fe₄S₄ clusters can be accessed with chemical reagents. Introduction of charge carriers by reduction of the Fe₄S₄ clusters is found to increase the electrical conductivity of the materials by up to four orders of magnitude. These results highlight the utility of Fe₄S₄ clusters as redox-active building blocks in preparing new classes of coordination polymers.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Chicago, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019215

OSTI ID:: 1524597

Journal Information:: Journal of the American Chemical Society, Vol. 141, Issue 9; Related Information: http://pubs.acs.org/doi/suppl/10.1021/jacs.8b12339/suppl_file/ja8b12339_si_001.pdf; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 39 works

Citation information provided by
Web of Science

References (107)

Selective gas adsorption and separation in metal–organic frameworks Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504 https://doi.org/10.1039/b802426j	journal	January 2009
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Enantioselective catalysis with homochiral metal–organic frameworks Ma, Liqing; Abney, Carter; Lin, Wenbin Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256 https://doi.org/10.1039/b807083k	journal	January 2009
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Challenges and recent advances in MOF–polymer composite membranes for gas separation Zhang, Yuanyuan; Feng, Xiao; Yuan, Shuai Inorganic Chemistry Frontiers, Vol. 3, Issue 7 https://doi.org/10.1039/C6QI00042H	journal	January 2016
The new age of MOFs and of their porous-related solids Maurin, Guillaume; Serre, Christian; Cooper, Andrew Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS90049J	journal	January 2017
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion Trickett, Christopher A.; Helal, Aasif; Al-Maythalony, Bassem A. Nature Reviews Materials, Vol. 2, Issue 8 https://doi.org/10.1038/natrevmats.2017.45	journal	July 2017
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Lead-free solid-state organic–inorganic halide perovskite solar cells Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh Nature Photonics, Vol. 8, Issue 6 https://doi.org/10.1038/nphoton.2014.82	journal	May 2014
Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications Zhao, Yixin; Zhu, Kai Chemical Society Reviews, Vol. 45, Issue 3 https://doi.org/10.1039/C4CS00458B	journal	January 2016
A Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications Slavney, Adam H.; Hu, Te; Lindenberg, Aaron M. Journal of the American Chemical Society, Vol. 138, Issue 7 https://doi.org/10.1021/jacs.5b13294	journal	February 2016
White-Light Emission from Layered Halide Perovskites Smith, Matthew D.; Karunadasa, Hemamala I. Accounts of Chemical Research, Vol. 51, Issue 3 https://doi.org/10.1021/acs.accounts.7b00433	journal	February 2018
Cd(ii) based metal–organic framework behaving as a Schottky barrier diode Bhattacharya, Biswajit; Layek, Animesh; Mehboob Alam, Md. Chemical Communications, Vol. 50, Issue 58 https://doi.org/10.1039/c4cc00827h	journal	January 2014
High Electrical Conductivity in Ni ₃ (2,3,6,7,10,11-hexaiminotriphenylene) ₂ , a Semiconducting Metal–Organic Graphene Analogue Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A. Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja502765n	journal	April 2014
Cu ₃ (hexaiminotriphenylene) ₂ : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F. Angewandte Chemie International Edition, Vol. 54, Issue 14 https://doi.org/10.1002/anie.201411854	journal	February 2015
Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework Darago, Lucy E.; Aubrey, Michael L.; Yu, Chung Jui Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b10385	journal	December 2015
A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T _c = 26 to 80 K Jeon, Ie-Rang; Negru, Bogdan; Van Duyne, Richard P. Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b10382	journal	December 2015
Metal–organic frameworks for energy storage: Batteries and supercapacitors Wang, Lu; Han, Yuzhen; Feng, Xiao Coordination Chemistry Reviews, Vol. 307 https://doi.org/10.1016/j.ccr.2015.09.002	journal	January 2016
Synthesis of cobalt-based layered coordination polymer nanosheets and their application in lithium-ion batteries as anode materials Shi, Changdong; Xia, Qinghong; Xue, Xin RSC Advances, Vol. 6, Issue 6 https://doi.org/10.1039/C5RA22038F	journal	January 2016
Metal–organic frameworks for electrochemical applications Liu, Wei; Yin, Xue-Bo TrAC Trends in Analytical Chemistry, Vol. 75 https://doi.org/10.1016/j.trac.2015.07.011	journal	January 2016
Solid-State Redox Switching of Magnetic Exchange and Electronic Conductivity in a Benzoquinoid-Bridged Mn ^II Chain Compound Jeon, Ie-Rang; Sun, Lei; Negru, Bogdan Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b02485	journal	May 2016
2D Conductive Iron-Quinoid Magnets Ordering up to T _c = 105 K via Heterogenous Redox Chemistry DeGayner, Jordan A.; Jeon, Ie-Rang; Sun, Lei Journal of the American Chemical Society, Vol. 139, Issue 11 https://doi.org/10.1021/jacs.7b00705	journal	March 2017
Signature of Metallic Behavior in the Metal–Organic Frameworks M ₃ (hexaiminobenzene) ₂ (M = Ni, Cu) Dou, Jin-Hu; Sun, Lei; Ge, Yicong Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b07234	journal	September 2017
Conductive MOF electrodes for stable supercapacitors with high areal capacitance Sheberla, Dennis; Bachman, John C.; Elias, Joseph S. Nature Materials, Vol. 16, Issue 2 https://doi.org/10.1038/nmat4766	journal	October 2016
A Microporous and Naturally Nanostructured Thermoelectric Metal-Organic Framework with Ultralow Thermal Conductivity Sun, Lei; Liao, Bolin; Sheberla, Dennis Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.07.018	journal	September 2017
Multielectron-Transfer-based Rechargeable Energy Storage of Two-Dimensional Coordination Frameworks with Non-Innocent Ligands Wada, Keisuke; Sakaushi, Ken; Sasaki, Sono Angewandte Chemie International Edition, Vol. 57, Issue 29 https://doi.org/10.1002/anie.201802521	journal	May 2018
Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage Park, Jihye; Lee, Minah; Feng, Dawei Journal of the American Chemical Society, Vol. 140, Issue 32 https://doi.org/10.1021/jacs.8b06020	journal	July 2018
Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance Feng, Dawei; Lei, Ting; Lukatskaya, Maria R. Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0044-5	journal	January 2018
Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium Ziebel, Michael E.; Darago, Lucy E.; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 140, Issue 8 https://doi.org/10.1021/jacs.7b13510	journal	February 2018
Electron delocalization and charge mobility as a function of reduction in a metal–organic framework Aubrey, Michael L.; Wiers, Brian M.; Andrews, Sean C. Nature Materials, Vol. 17, Issue 7 https://doi.org/10.1038/s41563-018-0098-1	journal	June 2018
Tunable Mixed-Valence Doping toward Record Electrical Conductivity in a Three-Dimensional Metal–Organic Framework Xie, Lilia S.; Sun, Lei; Wan, Ruomeng Journal of the American Chemical Society, Vol. 140, Issue 24 https://doi.org/10.1021/jacs.8b03604	journal	May 2018
Bis- and tetrakis-(diphenylphosphino) tetrathiafulvalenes as precursors of redox-active organic—inorganic polymeric networks Fourmigué, M.; Uzelmeier, C. E.; Boubekeur, K. Journal of Organometallic Chemistry, Vol. 529, Issue 1-2 https://doi.org/10.1016/S0022-328X(96)06637-5	journal	February 1997
Homoleptic complexes of Ag(I), Cu(I), Pd(II) and Pt(II) with tetrathiafulvalene-functionalized phosphine ligands † Smucker, Bradley W.; Dunbar, Kim R. Journal of the Chemical Society, Dalton Transactions, Issue 8 https://doi.org/10.1039/a908559i	journal	January 2000
Organic Thermoelectric Materials and Devices Based on p- and n-Type Poly(metal 1,1,2,2-ethenetetrathiolate)s Sun, Yimeng; Sheng, Peng; Di, Chongan Advanced Materials, Vol. 24, Issue 7 https://doi.org/10.1002/adma.201104305	journal	January 2012
Electrical conductive coordination polymers Givaja, Gonzalo; Amo-Ochoa, Pilar; Gómez-García, Carlos J. Chem. Soc. Rev., Vol. 41, Issue 1 https://doi.org/10.1039/C1CS15092H	journal	January 2012
Mn ₂ (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) _∞ Chains and High Intrinsic Charge Mobility Sun, Lei; Miyakai, Tomoyo; Seki, Shu Journal of the American Chemical Society, Vol. 135, Issue 22 https://doi.org/10.1021/ja4037516	journal	May 2013
Million-Fold Electrical Conductivity Enhancement in Fe ₂ (DEBDC) versus Mn ₂ (DEBDC) (E = S, O) Sun, Lei; Hendon, Christopher H.; Minier, Mikael A. Journal of the American Chemical Society, Vol. 137, Issue 19 https://doi.org/10.1021/jacs.5b02897	journal	May 2015
Flexible n-Type High-Performance Thermoelectric Thin Films of Poly(nickel-ethylenetetrathiolate) Prepared by an Electrochemical Method Sun, Yuanhui; Qiu, Lin; Tang, Liangpo Advanced Materials, Vol. 28, Issue 17 https://doi.org/10.1002/adma.201505922	journal	March 2016
Electrically Conductive Porous Metal-Organic Frameworks Sun, Lei; Campbell, Michael G.; Dincă, Mircea Angewandte Chemie International Edition, Vol. 55, Issue 11 https://doi.org/10.1002/anie.201506219	journal	January 2016
Synthesis and properties of tetrathiafulvalene–metal bisdithiolene macromolecules Rivera, Nilda Martinez; Engler, Edward M.; Schumaker, Robert R. J. Chem. Soc., Chem. Commun., Issue 4 https://doi.org/10.1039/C39790000184	journal	January 1979
Metal poly(benzodithiolenes) Dirk, C. W.; Bousseau, M.; Barrett, P. H. Macromolecules, Vol. 19, Issue 2 https://doi.org/10.1021/ma00156a003	journal	March 1986
Synthesis, characterization and properties of highly conducting organometallic polymers derived from the ethylene tetrathiolate anion Vicente, R.; Ribas, J.; Cassoux, P. Synthetic Metals, Vol. 13, Issue 4 https://doi.org/10.1016/0379-6779(86)90188-8	journal	February 1986
C4S62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers Szczepura, Lisa F.; Galloway, Collin P.; Zheng, Yifan Angewandte Chemie International Edition in English, Vol. 34, Issue 17 https://doi.org/10.1002/anie.199518901	journal	September 1995
New conducting co-ordination polymers containing M(dmit)2 links Cerrada, E.; Diaz, M. C.; Diaz, C. Synthetic Metals, Vol. 119, Issue 1-3 https://doi.org/10.1016/S0379-6779(00)00847-X	journal	March 2001
Metallic Behavior and Periodical Valence Ordering in a MMX Chain Compound, Pt ₂ (EtCS ₂ ) ₄ I Mitsumi, Minoru; Murase, Tomoko; Kishida, Hideyuki Journal of the American Chemical Society, Vol. 123, Issue 45 https://doi.org/10.1021/ja010900v	journal	October 2001
Novel ET-Coordinated Copper(I) Complexes: Syntheses, Structures, and Physical Properties (ET = BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene) Kanehama, Ryo; Umemiya, Masamichi; Iwahori, Fumiyasu Inorganic Chemistry, Vol. 42, Issue 22 https://doi.org/10.1021/ic0344362	journal	November 2003
π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312380b	journal	February 2013
Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro Journal of the American Chemical Society, Vol. 136, Issue 41 https://doi.org/10.1021/ja507619d	journal	October 2014
A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour Huang, Xing; Sheng, Peng; Tu, Zeyi Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8408	journal	June 2015
Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei Angewandte Chemie International Edition, Vol. 54, Issue 41 https://doi.org/10.1002/anie.201506048	journal	August 2015
Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet Pal, Tigmansu; Kambe, Tetsuya; Kusamoto, Tetsuro ChemPlusChem, Vol. 80, Issue 8 https://doi.org/10.1002/cplu.201500206	journal	July 2015
Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water Clough, Andrew J.; Yoo, Joseph W.; Mecklenburg, Matthew H. Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja5116937	journal	December 2014
Coordination Programming of Two-Dimensional Metal Complex Frameworks Maeda, Hiroaki; Sakamoto, Ryota; Nishihara, Hiroshi Langmuir, Vol. 32, Issue 11 https://doi.org/10.1021/acs.langmuir.6b00156	journal	March 2016
Conductive Copper Benzenehexathiol Coordination Polymer as a Hydrogen Evolution Catalyst Huang, Xing; Yao, Huiying; Cui, Yutao ACS Applied Materials & Interfaces, Vol. 9, Issue 46 https://doi.org/10.1021/acsami.7b14523	journal	November 2017
Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure Huang, Xing; Zhang, Shuai; Liu, Liyao Angewandte Chemie International Edition, Vol. 57, Issue 1 https://doi.org/10.1002/anie.201707568	journal	December 2017
Linking Molybdenum–Sulfur Clusters for Electrocatalytic Hydrogen Evolution Ji, Zhe; Trickett, Christopher; Pei, Xiaokun Journal of the American Chemical Society, Vol. 140, Issue 42 https://doi.org/10.1021/jacs.8b09807	journal	September 2018
Iron-Sulfur Clusters: Nature's Modular, Multipurpose Structures Beinert, H. Science, Vol. 277, Issue 5326 https://doi.org/10.1126/science.277.5326.653	journal	August 1997
Synthetic Analogues of the Active Sites of Iron−Sulfur Proteins Venkateswara Rao, P.; Holm, R. H. Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr020615+	journal	October 2003
Selective Synthesis of Site-Differentiated Fe ₄ S ₄ and Fe ₆ S ₆ Clusters McSkimming, Alex; Suess, Daniel L. M. Inorganic Chemistry, Vol. 57, Issue 23 https://doi.org/10.1021/acs.inorgchem.8b02684	journal	November 2018
Molecular Basis of Proton Motive Force Generation: Structure of Formate Dehydrogenase-N Jormakka, M. Science, Vol. 295, Issue 5561 https://doi.org/10.1126/science.1068186	journal	March 2002
Architecture of NarGH Reveals a Structural Classification of Mo-bisMGD Enzymes Jormakka, Mika; Richardson, David; Byrne, Bernadette Structure, Vol. 12, Issue 1 https://doi.org/10.1016/j.str.2003.11.020	journal	March 2004
Structure of the Hydrophilic Domain of Respiratory Complex I from Thermus thermophilus Sazanov, L. A. Science, Vol. 311, Issue 5766 https://doi.org/10.1126/science.1123809	journal	March 2006
Molecular mechanism of energy conservation in polysulfide respiration Jormakka, Mika; Yokoyama, Ken; Yano, Takahiro Nature Structural & Molecular Biology, Vol. 15, Issue 7 https://doi.org/10.1038/nsmb.1434	journal	June 2008
Electron tunneling in respiratory complex I Hayashi, T.; Stuchebrukhov, A. A. Proceedings of the National Academy of Sciences, Vol. 107, Issue 45 https://doi.org/10.1073/pnas.1009181107	journal	October 2010
Structural basis of enzymatic benzene ring reduction Weinert, Tobias; Huwiler, Simona G.; Kung, Johannes W. Nature Chemical Biology, Vol. 11, Issue 8 https://doi.org/10.1038/nchembio.1849	journal	June 2015
Perchlorate Reductase Is Distinguished by Active Site Aromatic Gate Residues Youngblut, Matthew D.; Tsai, Chi-Lin; Clark, Iain C. Journal of Biological Chemistry, Vol. 291, Issue 17 https://doi.org/10.1074/jbc.M116.714618	journal	March 2016
The methanogenic CO2 reducing-and-fixing enzyme is bifunctional and contains 46 [4Fe-4S] clusters Wagner, T.; Ermler, U.; Shima, S. Science, Vol. 354, Issue 6308 https://doi.org/10.1126/science.aaf9284	journal	October 2016
Structural and mechanistic analysis of the arsenate respiratory reductase provides insight into environmental arsenic transformations Glasser, Nathaniel R.; Oyala, Paul H.; Osborne, Thomas H. Proceedings of the National Academy of Sciences, Vol. 115, Issue 37 https://doi.org/10.1073/pnas.1807984115	journal	August 2018
Supramolecular Assembly of Hexagonal Mesostructured Germanium Sulfide and Selenide Nanocomposites Incorporating the Biologically Relevant Fe4S4 Cluster Trikalitis, Pantelis N.; Bakas, Thomas; Papaefthymiou, Vasilios Angewandte Chemie International Edition, Vol. 39, Issue 24 https://doi.org/10.1002/1521-3773(20001215)39:24<4558::AID-ANIE4558>3.0.CO;2-B	journal	December 2000
Enhanced Electrocatalytic Reduction of CO ₂ with Ternary Ni-Fe ₄ S ₄ and Co-Fe ₄ S ₄ -Based Biomimetic Chalcogels Yuhas, Benjamin D.; Prasittichai, Chaiya; Hupp, Joseph T. Journal of the American Chemical Society, Vol. 133, Issue 40 https://doi.org/10.1021/ja205981v	journal	October 2011
Tunable Biomimetic Chalcogels with Fe ₄ S ₄ Cores and [Sn _n S _{2 n +2} ] ^4– ( n = 1, 2, 4) Building Blocks for Solar Fuel Catalysis Shim, Yurina; Yuhas, Benjamin D.; Dyar, Scott M. Journal of the American Chemical Society, Vol. 135, Issue 6 https://doi.org/10.1021/ja311310k	journal	January 2013
Iron–sulphur clusters in ionic polymers on electrodes Moutet, Jean-Claude; Pickett, Christopher J. J. Chem. Soc., Chem. Commun., Issue 3 https://doi.org/10.1039/C39890000188	journal	January 1989
Synthesis and anodic polymerisation of an L-cystine derivatised pyrrole; copolymerisation with a tetraalkylammonium pyrrole allows reduction of the cystinyl film to a cysteinyl state that binds electroactive {Fe4S4}2+ centres Pickett, Christopher J.; Ryder, Karl S.; Moutet, Jean-Claude Journal of the Chemical Society, Chemical Communications, Issue 9 https://doi.org/10.1039/c39920000694	journal	January 1992
Iron–sulfur clusters in ionic polymers on electrodes Pickett, Christopher J.; Ryder, Karl S.; Moutet, Jean-claude J. Chem. Soc., Dalton Trans., Issue 24 https://doi.org/10.1039/DT9930003695	journal	January 1993
Bioinorganic reaction centres on electrodes. Modified electrodes possessing amino acid, peptide and ferredoxin-type groups on a poly(pyrrole) backbone Pickett, Christopher J.; Ryder, Karl S. Journal of the Chemical Society, Dalton Transactions, Issue 14 https://doi.org/10.1039/dt9940002181	journal	January 1994
Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mössbauer spectroscopy Rancourt, D. G.; Ping, J. Y. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 58, Issue 1 https://doi.org/10.1016/0168-583X(91)95681-3	journal	May 1991
Role of Modulators in Controlling the Colloidal Stability and Polydispersity of the UiO-66 Metal–Organic Framework Morris, William; Wang, Shunzhi; Cho, David ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b01040	journal	April 2017
Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals Schaate, Andreas; Roy, Pascal; Godt, Adelheid Chemistry - A European Journal, Vol. 17, Issue 24 https://doi.org/10.1002/chem.201003211	journal	May 2011
Soluble dynamic coordination polymers as a paradigm for materials science Friese, Viviane A.; Kurth, Dirk G. Coordination Chemistry Reviews, Vol. 252, Issue 1-2 https://doi.org/10.1016/j.ccr.2007.06.001	journal	January 2008
Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering Beaucage, G. Journal of Applied Crystallography, Vol. 28, Issue 6 https://doi.org/10.1107/S0021889895005292	journal	December 1995
Small-Angle Scattering from Polymeric Mass Fractals of Arbitrary Mass-Fractal Dimension Beaucage, G. Journal of Applied Crystallography, Vol. 29, Issue 2 https://doi.org/10.1107/S0021889895011605	journal	April 1996
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
The Denaturation Transition of DNA in Mixed Solvents Hammouda, Boualem; Worcester, David Biophysical Journal, Vol. 91, Issue 6 https://doi.org/10.1529/biophysj.106.083691	journal	September 2006
Natural engineering principles of electron tunnelling in biological oxidation–reduction Page, Christopher C.; Moser, Christopher C.; Chen, Xiaoxi Nature, Vol. 402, Issue 6757 https://doi.org/10.1038/46972	journal	November 1999
Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters [Fe4S4(SR)4]2- DePamphilis, B. V.; Averill, B. A.; Herskovitz, T. Journal of the American Chemical Society, Vol. 96, Issue 13 https://doi.org/10.1021/ja00820a017	journal	June 1974
Synthesis and study of an analog for the [Fe4S4]3+ center of oxidized high potential iron-sulfur proteins O'Sullivan, Timothy; Millar, Michelle M. Journal of the American Chemical Society, Vol. 107, Issue 13 https://doi.org/10.1021/ja00299a066	journal	June 1985
Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd ₂ (TTFTB) as a Case Study Sun, Lei; Park, Sarah S.; Sheberla, Dennis Journal of the American Chemical Society, Vol. 138, Issue 44 https://doi.org/10.1021/jacs.6b09345	journal	October 2016
Synthetic analogs of the 4-Fe active sites of reduced ferredoxins. Electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3- and the structure of [(C2H5)3(CH3)N]3[Fe4S4(SC6H5)4] Laskowski, E. J.; Frankel, R. B.; Gillum, W. O. Journal of the American Chemical Society, Vol. 100, Issue 17 https://doi.org/10.1021/ja00485a013	journal	August 1978
Synthesis, structural characterization, and electronic structures of the mixed terminal ligand iron-sulfur cubanes [Fe4S4Cl2(XPh)2]2- (X = S, O) and [Fe4S4(SPh)2(OC6H4Me-p)2]2-. The first examples of [Fe4S4]2+ cores with a noncompressed D2d idealized geometry Kanatzidis, M. G.; Baenziger, N. C.; Coucouvanis, D. Journal of the American Chemical Society, Vol. 106, Issue 16 https://doi.org/10.1021/ja00328a033	journal	August 1984
Chemical and electrochemical interrelationships of the 1-Fe, 2-Fe, and 4-Fe analogs of the active sites of iron-sulfur proteins Cambray, J.; Lane, R. W.; Wedd, A. G. Inorganic Chemistry, Vol. 16, Issue 10 https://doi.org/10.1021/ic50176a030	journal	October 1977
Über die Salze der Phosphor-hexafluorwasserstoffsäure, HPF ₆ Lange, Willy; Müller, Emil Berichte der deutschen chemischen Gesellschaft (A and B Series), Vol. 63, Issue 5 https://doi.org/10.1002/cber.19300630510	journal	May 1930
Fragmentation of aryl alkyl sulfides. A simple, one-pot synthesis of polymercaptobenzenes from polychlorobenzenes Maiolo, Filippo; Testaferri, Lorenzo; Tiecco, Marcello The Journal of Organic Chemistry, Vol. 46, Issue 15 https://doi.org/10.1021/jo00328a016	journal	July 1981
Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand substitution reactions of the tetranuclear clusters [Fe4S4(SR)2- and the structure of bis(tetramethylammonium) [tetra-.mu.-sulfide-tetrakis(benzenethiolato)tetrairon Que, L.; Bobrik, M. A.; Ibers, James A. Journal of the American Chemical Society, Vol. 96, Issue 13 https://doi.org/10.1021/ja00820a018	journal	June 1974
Best Practices for the Synthesis, Activation, and Characterization of Metal–Organic Frameworks Howarth, Ashlee J.; Peters, Aaron W.; Vermeulen, Nicolaas A. Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02626	journal	September 2016
PROXIMA 2A – A New Fully Tunable Micro-focus Beamline for Macromolecular Crystallography Duran, D.; Couster, S. Le; Desjardins, K. Journal of Physics: Conference Series, Vol. 425, Issue 1 https://doi.org/10.1088/1742-6596/425/1/012005	journal	March 2013
Some further considerations in powder diffraction pattern indexing with the dichotomy method Louër, Daniel; Boultif, Ali Powder Diffraction, Vol. 29, Issue S2 https://doi.org/10.1017/S0885715614000906	journal	November 2014
New techniques for indexing: N-TREOR in EXPO Altomare, Angela; Giacovazzo, Carmelo; Guagliardi, Antonietta Journal of Applied Crystallography, Vol. 33, Issue 4 https://doi.org/10.1107/S0021889800006427	journal	August 2000
EXPO2013 : a kit of tools for phasing crystal structures from powder data Altomare, Angela; Cuocci, Corrado; Giacovazzo, Carmelo Journal of Applied Crystallography, Vol. 46, Issue 4 https://doi.org/10.1107/S0021889813013113	journal	July 2013
FOX , `free objects for crystallography': a modular approach to ab initio structure determination from powder diffraction Favre-Nicolin, Vincent; Černý, Radovan Journal of Applied Crystallography, Vol. 35, Issue 6 https://doi.org/10.1107/S0021889802015236	journal	November 2002
Syntheses and structural characterizations of Fe4S4 cubane-like cluster compounds containing cycloalkylthiolate ligands Liu, Qiutian; Zhang, Chunxi; Chen, Changneng Science in China Series B: Chemistry, Vol. 40, Issue 6 https://doi.org/10.1007/BF02875480	journal	December 1997
X-ray crystal structures of [NHR3]2[Fe4S4X4] (X = PhS, R = Et or n Bu; X = Cl, R = n Bu): implications for sites of protonation in Fe–S clusters Al-Rammahi, Thaer M. M.; Waddell, Paul G.; Henderson, Richard A. Transition Metal Chemistry, Vol. 41, Issue 5 https://doi.org/10.1007/s11243-016-0052-5	journal	April 2016
Mercury : visualization and analysis of crystal structures Macrae, Clare F.; Edgington, Paul R.; McCabe, Patrick Journal of Applied Crystallography, Vol. 39, Issue 3 https://doi.org/10.1107/S002188980600731X	journal	May 2006
Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures Macrae, Clare F.; Bruno, Ian J.; Chisholm, James A. Journal of Applied Crystallography, Vol. 41, Issue 2 https://doi.org/10.1107/S0021889807067908	journal	March 2008
Reaction of tetraoxomolybdate(2-) and tetraoxotungstate(2-) with aqueous polysulfides: synthesis, structure, and electrochemistry of .eta.2-polysulfido complexes containing a bridging S,S {M2O2S2}2+ (M = molybdenum, tungsten) core Bhattacharyya, Ramgopal; Chakrabarty, Prasanta K.; Ghosh, Pradip N. Inorganic Chemistry, Vol. 30, Issue 20 https://doi.org/10.1021/ic00020a031	journal	October 1991
CCDC 1472848: Experimental Crystal Structure Determination Al-Rammahi, Thaer M. M.; Waddell, Paul G.; Henderson, Richard A. Cambridge Crystallographic Data Centre https://doi.org/10.5517/ccdc.csd.cc1lfm7w	dataset	January 2016
CCDC 1472848: Experimental Crystal Structure Determination Al-Rammahi, Thaer M. M.; Waddell, Paul G.; Henderson, Richard A. Cambridge Crystallographic Data Centre https://doi.org/10.5517/ccdc.csd.cc1lfm7w	dataset	January 2016

Cited By (1)

Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds Xie, Jiaze; Boyn, Jan-Niklas; Filatov, Alexander S. Chemical Science, Vol. 11, Issue 4 https://doi.org/10.1039/c9sc04381k	journal	January 2020

Linked Research (2)

Similar Records

Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**

Journal Article · 2022 · Angewandte Chemie · OSTI ID:1891566

Wang, Lei; Papoular, Robert J.; Horwitz, Noah E.; +10 more

Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**

Journal Article · 2022 · Angewandte Chemie (International Edition) · OSTI ID:1891568

Wang, Lei; Papoular, Robert J.; Horwitz, Noah E.; +10 more

Flexible porous coordination polymer of Ni(II) for developing nanoparticles through acid formation and redox activity of the framework

Journal Article · 2017 · Journal of Solid State Chemistry · OSTI ID:22742049

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
iron-sulfur clusters

CCDC 1869639: Experimental Crystal Structure Determination Horwitz, Noah E.; Xie, Jiaze; Filatov, Alexander S. https://doi.org/10.5517/ccdc.csd.cc20rhy7 The current record is supplemented by this dataset	dataset	January 2019
CCDC 1869640: Experimental Crystal Structure Determination Horwitz, Noah E.; Xie, Jiaze; Filatov, Alexander S. https://doi.org/10.5517/ccdc.csd.cc20rhz8 The current record is supplemented by this dataset	dataset	January 2019