DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters

Abstract

Here we describe the combination of an archetypal redox-active metal sulfide cluster, Fe4S4, with an organic linker, 1,4-benzenedithiolate, to prepare coordination polymers containing infinite chains of Fe4S4 clusters. The crystal structures of two solid materials have been solved from synchrotron X-ray powder diffraction data using simulated annealing and re-fined by a least-squares Rietveld refinement procedure. The electronic properties of these chains have also been characterized by UV-visible and Mössbauer spectroscopies. Additional experiments demonstrated that these chains can be solubilized by variation of the countercation and that the chain structure is maintained in solution. The redox-activity of the Fe4S4 clusters can be accessed with chemical reagents. Introduction of charge carriers by reduction of the Fe4S4 clusters is found to increase the electrical conductivity of the materials by up to four orders of magnitude. These results highlight the utility of Fe4S4 clusters as redox-active building blocks in preparing new classes of coordination polymers.

Authors:
 [1];  [1]; ORCiD logo [1];  [2]; ORCiD logo [3];  [4];  [1];  [1]; ORCiD logo [1]
  1. Univ. of Chicago, Chicago, IL (United States)
  2. Saclay Institute for Matter and Radiation (IRAMIS), Gif-sur-Yvette (France)
  3. Synchrotron SOLEIL, Gif-sur-Yvette (France)
  4. Northwestern Univ., Evanston, IL (United States)
Publication Date:
Research Org.:
Univ. of Chicago, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1524597
Grant/Contract Number:  
SC0019215
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 141; Journal Issue: 9; Related Information: http://pubs.acs.org/doi/suppl/10.1021/jacs.8b12339/suppl_file/ja8b12339_si_001.pdf; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; iron-sulfur clusters

Citation Formats

Horwitz, Noah E., Xie, Jiaze, Filatov, Alexander S., Papoular, Robert J., Shepard, William E., Zee, David Z., Grahn, Mia P., Gilder, Chloe, and Anderson, John S. Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters. United States: N. p., 2019. Web. doi:10.1021/jacs.8b12339.
Horwitz, Noah E., Xie, Jiaze, Filatov, Alexander S., Papoular, Robert J., Shepard, William E., Zee, David Z., Grahn, Mia P., Gilder, Chloe, & Anderson, John S. Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters. United States. https://doi.org/10.1021/jacs.8b12339
Horwitz, Noah E., Xie, Jiaze, Filatov, Alexander S., Papoular, Robert J., Shepard, William E., Zee, David Z., Grahn, Mia P., Gilder, Chloe, and Anderson, John S. Mon . "Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters". United States. https://doi.org/10.1021/jacs.8b12339. https://www.osti.gov/servlets/purl/1524597.
@article{osti_1524597,
title = {Redox-Active 1D Coordination Polymers of Iron–Sulfur Clusters},
author = {Horwitz, Noah E. and Xie, Jiaze and Filatov, Alexander S. and Papoular, Robert J. and Shepard, William E. and Zee, David Z. and Grahn, Mia P. and Gilder, Chloe and Anderson, John S.},
abstractNote = {Here we describe the combination of an archetypal redox-active metal sulfide cluster, Fe4S4, with an organic linker, 1,4-benzenedithiolate, to prepare coordination polymers containing infinite chains of Fe4S4 clusters. The crystal structures of two solid materials have been solved from synchrotron X-ray powder diffraction data using simulated annealing and re-fined by a least-squares Rietveld refinement procedure. The electronic properties of these chains have also been characterized by UV-visible and Mössbauer spectroscopies. Additional experiments demonstrated that these chains can be solubilized by variation of the countercation and that the chain structure is maintained in solution. The redox-activity of the Fe4S4 clusters can be accessed with chemical reagents. Introduction of charge carriers by reduction of the Fe4S4 clusters is found to increase the electrical conductivity of the materials by up to four orders of magnitude. These results highlight the utility of Fe4S4 clusters as redox-active building blocks in preparing new classes of coordination polymers.},
doi = {10.1021/jacs.8b12339},
journal = {Journal of the American Chemical Society},
number = 9,
volume = 141,
place = {United States},
year = {2019},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009

  • Ma, Liqing; Abney, Carter; Lin, Wenbin
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
  • DOI: 10.1039/b807083k

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Challenges and recent advances in MOF–polymer composite membranes for gas separation
journal, January 2016

  • Zhang, Yuanyuan; Feng, Xiao; Yuan, Shuai
  • Inorganic Chemistry Frontiers, Vol. 3, Issue 7
  • DOI: 10.1039/C6QI00042H

The new age of MOFs and of their porous-related solids
journal, January 2017

  • Maurin, Guillaume; Serre, Christian; Cooper, Andrew
  • Chemical Society Reviews, Vol. 46, Issue 11
  • DOI: 10.1039/C7CS90049J

The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
journal, July 2017

  • Trickett, Christopher A.; Helal, Aasif; Al-Maythalony, Bassem A.
  • Nature Reviews Materials, Vol. 2, Issue 8
  • DOI: 10.1038/natrevmats.2017.45

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Lead-free solid-state organic–inorganic halide perovskite solar cells
journal, May 2014

  • Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh
  • Nature Photonics, Vol. 8, Issue 6
  • DOI: 10.1038/nphoton.2014.82

Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications
journal, January 2016

  • Zhao, Yixin; Zhu, Kai
  • Chemical Society Reviews, Vol. 45, Issue 3
  • DOI: 10.1039/C4CS00458B

A Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications
journal, February 2016

  • Slavney, Adam H.; Hu, Te; Lindenberg, Aaron M.
  • Journal of the American Chemical Society, Vol. 138, Issue 7
  • DOI: 10.1021/jacs.5b13294

White-Light Emission from Layered Halide Perovskites
journal, February 2018


Cd(ii) based metal–organic framework behaving as a Schottky barrier diode
journal, January 2014

  • Bhattacharya, Biswajit; Layek, Animesh; Mehboob Alam, Md.
  • Chemical Communications, Vol. 50, Issue 58
  • DOI: 10.1039/c4cc00827h

High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

  • Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 25
  • DOI: 10.1021/ja502765n

Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015

  • Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F.
  • Angewandte Chemie International Edition, Vol. 54, Issue 14
  • DOI: 10.1002/anie.201411854

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework
journal, December 2015

  • Darago, Lucy E.; Aubrey, Michael L.; Yu, Chung Jui
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b10385

A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T c = 26 to 80 K
journal, December 2015

  • Jeon, Ie-Rang; Negru, Bogdan; Van Duyne, Richard P.
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b10382

Metal–organic frameworks for energy storage: Batteries and supercapacitors
journal, January 2016


Synthesis of cobalt-based layered coordination polymer nanosheets and their application in lithium-ion batteries as anode materials
journal, January 2016

  • Shi, Changdong; Xia, Qinghong; Xue, Xin
  • RSC Advances, Vol. 6, Issue 6
  • DOI: 10.1039/C5RA22038F

Metal–organic frameworks for electrochemical applications
journal, January 2016


Solid-State Redox Switching of Magnetic Exchange and Electronic Conductivity in a Benzoquinoid-Bridged Mn II Chain Compound
journal, May 2016

  • Jeon, Ie-Rang; Sun, Lei; Negru, Bogdan
  • Journal of the American Chemical Society, Vol. 138, Issue 20
  • DOI: 10.1021/jacs.6b02485

2D Conductive Iron-Quinoid Magnets Ordering up to T c = 105 K via Heterogenous Redox Chemistry
journal, March 2017

  • DeGayner, Jordan A.; Jeon, Ie-Rang; Sun, Lei
  • Journal of the American Chemical Society, Vol. 139, Issue 11
  • DOI: 10.1021/jacs.7b00705

Signature of Metallic Behavior in the Metal–Organic Frameworks M 3 (hexaiminobenzene) 2 (M = Ni, Cu)
journal, September 2017

  • Dou, Jin-Hu; Sun, Lei; Ge, Yicong
  • Journal of the American Chemical Society, Vol. 139, Issue 39
  • DOI: 10.1021/jacs.7b07234

Conductive MOF electrodes for stable supercapacitors with high areal capacitance
journal, October 2016

  • Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.
  • Nature Materials, Vol. 16, Issue 2
  • DOI: 10.1038/nmat4766

A Microporous and Naturally Nanostructured Thermoelectric Metal-Organic Framework with Ultralow Thermal Conductivity
journal, September 2017


Multielectron-Transfer-based Rechargeable Energy Storage of Two-Dimensional Coordination Frameworks with Non-Innocent Ligands
journal, May 2018

  • Wada, Keisuke; Sakaushi, Ken; Sasaki, Sono
  • Angewandte Chemie International Edition, Vol. 57, Issue 29
  • DOI: 10.1002/anie.201802521

Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage
journal, July 2018

  • Park, Jihye; Lee, Minah; Feng, Dawei
  • Journal of the American Chemical Society, Vol. 140, Issue 32
  • DOI: 10.1021/jacs.8b06020

Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance
journal, January 2018


Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium
journal, February 2018

  • Ziebel, Michael E.; Darago, Lucy E.; Long, Jeffrey R.
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b13510

Electron delocalization and charge mobility as a function of reduction in a metal–organic framework
journal, June 2018


Tunable Mixed-Valence Doping toward Record Electrical Conductivity in a Three-Dimensional Metal–Organic Framework
journal, May 2018

  • Xie, Lilia S.; Sun, Lei; Wan, Ruomeng
  • Journal of the American Chemical Society, Vol. 140, Issue 24
  • DOI: 10.1021/jacs.8b03604

Bis- and tetrakis-(diphenylphosphino) tetrathiafulvalenes as precursors of redox-active organic—inorganic polymeric networks
journal, February 1997


Homoleptic complexes of Ag(I), Cu(I), Pd(II) and Pt(II) with tetrathiafulvalene-functionalized phosphine ligands †
journal, January 2000

  • Smucker, Bradley W.; Dunbar, Kim R.
  • Journal of the Chemical Society, Dalton Transactions, Issue 8
  • DOI: 10.1039/a908559i

Organic Thermoelectric Materials and Devices Based on p- and n-Type Poly(metal 1,1,2,2-ethenetetrathiolate)s
journal, January 2012


Electrical conductive coordination polymers
journal, January 2012

  • Givaja, Gonzalo; Amo-Ochoa, Pilar; Gómez-García, Carlos J.
  • Chem. Soc. Rev., Vol. 41, Issue 1
  • DOI: 10.1039/C1CS15092H

Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) Chains and High Intrinsic Charge Mobility
journal, May 2013

  • Sun, Lei; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 135, Issue 22
  • DOI: 10.1021/ja4037516

Million-Fold Electrical Conductivity Enhancement in Fe 2 (DEBDC) versus Mn 2 (DEBDC) (E = S, O)
journal, May 2015

  • Sun, Lei; Hendon, Christopher H.; Minier, Mikael A.
  • Journal of the American Chemical Society, Vol. 137, Issue 19
  • DOI: 10.1021/jacs.5b02897

Flexible n-Type High-Performance Thermoelectric Thin Films of Poly(nickel-ethylenetetrathiolate) Prepared by an Electrochemical Method
journal, March 2016


Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016

  • Sun, Lei; Campbell, Michael G.; Dincă, Mircea
  • Angewandte Chemie International Edition, Vol. 55, Issue 11
  • DOI: 10.1002/anie.201506219

Synthesis and properties of tetrathiafulvalene–metal bisdithiolene macromolecules
journal, January 1979

  • Rivera, Nilda Martinez; Engler, Edward M.; Schumaker, Robert R.
  • J. Chem. Soc., Chem. Commun., Issue 4
  • DOI: 10.1039/C39790000184

Metal poly(benzodithiolenes)
journal, March 1986

  • Dirk, C. W.; Bousseau, M.; Barrett, P. H.
  • Macromolecules, Vol. 19, Issue 2
  • DOI: 10.1021/ma00156a003

C4S62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers
journal, September 1995

  • Szczepura, Lisa F.; Galloway, Collin P.; Zheng, Yifan
  • Angewandte Chemie International Edition in English, Vol. 34, Issue 17
  • DOI: 10.1002/anie.199518901

New conducting co-ordination polymers containing M(dmit)2 links
journal, March 2001


Metallic Behavior and Periodical Valence Ordering in a MMX Chain Compound, Pt 2 (EtCS 2 ) 4 I
journal, October 2001

  • Mitsumi, Minoru; Murase, Tomoko; Kishida, Hideyuki
  • Journal of the American Chemical Society, Vol. 123, Issue 45
  • DOI: 10.1021/ja010900v

Novel ET-Coordinated Copper(I) Complexes:  Syntheses, Structures, and Physical Properties (ET = BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene)
journal, November 2003

  • Kanehama, Ryo; Umemiya, Masamichi; Iwahori, Fumiyasu
  • Inorganic Chemistry, Vol. 42, Issue 22
  • DOI: 10.1021/ic0344362

π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet
journal, February 2013

  • Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken
  • Journal of the American Chemical Society, Vol. 135, Issue 7
  • DOI: 10.1021/ja312380b

Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator
journal, October 2014

  • Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro
  • Journal of the American Chemical Society, Vol. 136, Issue 41
  • DOI: 10.1021/ja507619d

A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
journal, June 2015

  • Huang, Xing; Sheng, Peng; Tu, Zeyi
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8408

Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution
journal, August 2015

  • Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei
  • Angewandte Chemie International Edition, Vol. 54, Issue 41
  • DOI: 10.1002/anie.201506048

Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet
journal, July 2015


Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water
journal, December 2014

  • Clough, Andrew J.; Yoo, Joseph W.; Mecklenburg, Matthew H.
  • Journal of the American Chemical Society, Vol. 137, Issue 1
  • DOI: 10.1021/ja5116937

Coordination Programming of Two-Dimensional Metal Complex Frameworks
journal, March 2016


Conductive Copper Benzenehexathiol Coordination Polymer as a Hydrogen Evolution Catalyst
journal, November 2017

  • Huang, Xing; Yao, Huiying; Cui, Yutao
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 46
  • DOI: 10.1021/acsami.7b14523

Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure
journal, December 2017

  • Huang, Xing; Zhang, Shuai; Liu, Liyao
  • Angewandte Chemie International Edition, Vol. 57, Issue 1
  • DOI: 10.1002/anie.201707568

Linking Molybdenum–Sulfur Clusters for Electrocatalytic Hydrogen Evolution
journal, September 2018

  • Ji, Zhe; Trickett, Christopher; Pei, Xiaokun
  • Journal of the American Chemical Society, Vol. 140, Issue 42
  • DOI: 10.1021/jacs.8b09807

Iron-Sulfur Clusters: Nature's Modular, Multipurpose Structures
journal, August 1997


Selective Synthesis of Site-Differentiated Fe 4 S 4 and Fe 6 S 6 Clusters
journal, November 2018


Architecture of NarGH Reveals a Structural Classification of Mo-bisMGD Enzymes
journal, March 2004


Structure of the Hydrophilic Domain of Respiratory Complex I from Thermus thermophilus
journal, March 2006


Molecular mechanism of energy conservation in polysulfide respiration
journal, June 2008

  • Jormakka, Mika; Yokoyama, Ken; Yano, Takahiro
  • Nature Structural & Molecular Biology, Vol. 15, Issue 7
  • DOI: 10.1038/nsmb.1434

Electron tunneling in respiratory complex I
journal, October 2010

  • Hayashi, T.; Stuchebrukhov, A. A.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 45
  • DOI: 10.1073/pnas.1009181107

Structural basis of enzymatic benzene ring reduction
journal, June 2015

  • Weinert, Tobias; Huwiler, Simona G.; Kung, Johannes W.
  • Nature Chemical Biology, Vol. 11, Issue 8
  • DOI: 10.1038/nchembio.1849

Perchlorate Reductase Is Distinguished by Active Site Aromatic Gate Residues
journal, March 2016

  • Youngblut, Matthew D.; Tsai, Chi-Lin; Clark, Iain C.
  • Journal of Biological Chemistry, Vol. 291, Issue 17
  • DOI: 10.1074/jbc.M116.714618

The methanogenic CO2 reducing-and-fixing enzyme is bifunctional and contains 46 [4Fe-4S] clusters
journal, October 2016


Structural and mechanistic analysis of the arsenate respiratory reductase provides insight into environmental arsenic transformations
journal, August 2018

  • Glasser, Nathaniel R.; Oyala, Paul H.; Osborne, Thomas H.
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 37
  • DOI: 10.1073/pnas.1807984115

Supramolecular Assembly of Hexagonal Mesostructured Germanium Sulfide and Selenide Nanocomposites Incorporating the Biologically Relevant Fe4S4 Cluster
journal, December 2000


Enhanced Electrocatalytic Reduction of CO 2 with Ternary Ni-Fe 4 S 4 and Co-Fe 4 S 4 -Based Biomimetic Chalcogels
journal, October 2011

  • Yuhas, Benjamin D.; Prasittichai, Chaiya; Hupp, Joseph T.
  • Journal of the American Chemical Society, Vol. 133, Issue 40
  • DOI: 10.1021/ja205981v

Tunable Biomimetic Chalcogels with Fe 4 S 4 Cores and [Sn n S 2 n +2 ] 4– ( n = 1, 2, 4) Building Blocks for Solar Fuel Catalysis
journal, January 2013

  • Shim, Yurina; Yuhas, Benjamin D.; Dyar, Scott M.
  • Journal of the American Chemical Society, Vol. 135, Issue 6
  • DOI: 10.1021/ja311310k

Iron–sulphur clusters in ionic polymers on electrodes
journal, January 1989

  • Moutet, Jean-Claude; Pickett, Christopher J.
  • J. Chem. Soc., Chem. Commun., Issue 3
  • DOI: 10.1039/C39890000188

Iron–sulfur clusters in ionic polymers on electrodes
journal, January 1993

  • Pickett, Christopher J.; Ryder, Karl S.; Moutet, Jean-claude
  • J. Chem. Soc., Dalton Trans., Issue 24
  • DOI: 10.1039/DT9930003695

Bioinorganic reaction centres on electrodes. Modified electrodes possessing amino acid, peptide and ferredoxin-type groups on a poly(pyrrole) backbone
journal, January 1994

  • Pickett, Christopher J.; Ryder, Karl S.
  • Journal of the Chemical Society, Dalton Transactions, Issue 14
  • DOI: 10.1039/dt9940002181

Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mössbauer spectroscopy
journal, May 1991

  • Rancourt, D. G.; Ping, J. Y.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 58, Issue 1
  • DOI: 10.1016/0168-583X(91)95681-3

Role of Modulators in Controlling the Colloidal Stability and Polydispersity of the UiO-66 Metal–Organic Framework
journal, April 2017

  • Morris, William; Wang, Shunzhi; Cho, David
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 39
  • DOI: 10.1021/acsami.7b01040

Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals
journal, May 2011

  • Schaate, Andreas; Roy, Pascal; Godt, Adelheid
  • Chemistry - A European Journal, Vol. 17, Issue 24
  • DOI: 10.1002/chem.201003211

Soluble dynamic coordination polymers as a paradigm for materials science
journal, January 2008


Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering
journal, December 1995


Small-Angle Scattering from Polymeric Mass Fractals of Arbitrary Mass-Fractal Dimension
journal, April 1996


Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009


The Denaturation Transition of DNA in Mixed Solvents
journal, September 2006


Natural engineering principles of electron tunnelling in biological oxidation–reduction
journal, November 1999

  • Page, Christopher C.; Moser, Christopher C.; Chen, Xiaoxi
  • Nature, Vol. 402, Issue 6757
  • DOI: 10.1038/46972

Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters [Fe4S4(SR)4]2-
journal, June 1974

  • DePamphilis, B. V.; Averill, B. A.; Herskovitz, T.
  • Journal of the American Chemical Society, Vol. 96, Issue 13
  • DOI: 10.1021/ja00820a017

Synthesis and study of an analog for the [Fe4S4]3+ center of oxidized high potential iron-sulfur proteins
journal, June 1985

  • O'Sullivan, Timothy; Millar, Michelle M.
  • Journal of the American Chemical Society, Vol. 107, Issue 13
  • DOI: 10.1021/ja00299a066

Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study
journal, October 2016

  • Sun, Lei; Park, Sarah S.; Sheberla, Dennis
  • Journal of the American Chemical Society, Vol. 138, Issue 44
  • DOI: 10.1021/jacs.6b09345

Synthetic analogs of the 4-Fe active sites of reduced ferredoxins. Electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3- and the structure of [(C2H5)3(CH3)N]3[Fe4S4(SC6H5)4]
journal, August 1978

  • Laskowski, E. J.; Frankel, R. B.; Gillum, W. O.
  • Journal of the American Chemical Society, Vol. 100, Issue 17
  • DOI: 10.1021/ja00485a013

Chemical and electrochemical interrelationships of the 1-Fe, 2-Fe, and 4-Fe analogs of the active sites of iron-sulfur proteins
journal, October 1977

  • Cambray, J.; Lane, R. W.; Wedd, A. G.
  • Inorganic Chemistry, Vol. 16, Issue 10
  • DOI: 10.1021/ic50176a030

Über die Salze der Phosphor-hexafluorwasserstoffsäure, HPF 6
journal, May 1930

  • Lange, Willy; Müller, Emil
  • Berichte der deutschen chemischen Gesellschaft (A and B Series), Vol. 63, Issue 5
  • DOI: 10.1002/cber.19300630510

Fragmentation of aryl alkyl sulfides. A simple, one-pot synthesis of polymercaptobenzenes from polychlorobenzenes
journal, July 1981

  • Maiolo, Filippo; Testaferri, Lorenzo; Tiecco, Marcello
  • The Journal of Organic Chemistry, Vol. 46, Issue 15
  • DOI: 10.1021/jo00328a016

Best Practices for the Synthesis, Activation, and Characterization of Metal–Organic Frameworks
journal, September 2016


PROXIMA 2A – A New Fully Tunable Micro-focus Beamline for Macromolecular Crystallography
journal, March 2013


Some further considerations in powder diffraction pattern indexing with the dichotomy method
journal, November 2014


New techniques for indexing: N-TREOR in EXPO
journal, August 2000

  • Altomare, Angela; Giacovazzo, Carmelo; Guagliardi, Antonietta
  • Journal of Applied Crystallography, Vol. 33, Issue 4
  • DOI: 10.1107/S0021889800006427

EXPO2013 : a kit of tools for phasing crystal structures from powder data
journal, July 2013

  • Altomare, Angela; Cuocci, Corrado; Giacovazzo, Carmelo
  • Journal of Applied Crystallography, Vol. 46, Issue 4
  • DOI: 10.1107/S0021889813013113

FOX , `free objects for crystallography': a modular approach to ab initio structure determination from powder diffraction
journal, November 2002

  • Favre-Nicolin, Vincent; Černý, Radovan
  • Journal of Applied Crystallography, Vol. 35, Issue 6
  • DOI: 10.1107/S0021889802015236

Syntheses and structural characterizations of Fe4S4 cubane-like cluster compounds containing cycloalkylthiolate ligands
journal, December 1997

  • Liu, Qiutian; Zhang, Chunxi; Chen, Changneng
  • Science in China Series B: Chemistry, Vol. 40, Issue 6
  • DOI: 10.1007/BF02875480

X-ray crystal structures of [NHR3]2[Fe4S4X4] (X = PhS, R = Et or n Bu; X = Cl, R =  n Bu): implications for sites of protonation in Fe–S clusters
journal, April 2016

  • Al-Rammahi, Thaer M. M.; Waddell, Paul G.; Henderson, Richard A.
  • Transition Metal Chemistry, Vol. 41, Issue 5
  • DOI: 10.1007/s11243-016-0052-5

Mercury : visualization and analysis of crystal structures
journal, May 2006

  • Macrae, Clare F.; Edgington, Paul R.; McCabe, Patrick
  • Journal of Applied Crystallography, Vol. 39, Issue 3
  • DOI: 10.1107/S002188980600731X

Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures
journal, March 2008

  • Macrae, Clare F.; Bruno, Ian J.; Chisholm, James A.
  • Journal of Applied Crystallography, Vol. 41, Issue 2
  • DOI: 10.1107/S0021889807067908

Works referencing / citing this record:

Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds
journal, January 2020

  • Xie, Jiaze; Boyn, Jan-Niklas; Filatov, Alexander S.
  • Chemical Science, Vol. 11, Issue 4
  • DOI: 10.1039/c9sc04381k

PreDICT: a graphical user interface to the DICVOL14 indexing software program for powder diffraction data
journal, August 2019

  • Blanton, Justin R.; Papoular, Robert J.; Louër, Daniel
  • Powder Diffraction, Vol. 34, Issue 3
  • DOI: 10.1017/s0885715619000514