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Title: Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy) 2(bpz) 2+ complex: implications for photoinduced electron–proton transfer

Abstract

The equilibrium constants of hydrogen bonding (HB) between hydroxylic donors, ROH, and MLCT-excited Ru(bpy) 2(bpz) 2+ complex, 1(T) correlate with ROH empirical HB acidities, which is used for evaluating the unimolecular rate constants of concerted electron-proton transfer within the H-bonded Phenol-1(T) exciplexes.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1524551
Alternate Identifier(s):
OSTI ID: 1510139
Report Number(s):
BNL-211708-2019-JAAM
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 55; Journal Issue: 42; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Lymar, Sergei V., Manbeck, Gerald F., and Polyansky, Dmitry E. Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer. United States: N. p., 2019. Web. doi:10.1039/C9CC01896D.
Lymar, Sergei V., Manbeck, Gerald F., & Polyansky, Dmitry E. Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer. United States. doi:10.1039/C9CC01896D.
Lymar, Sergei V., Manbeck, Gerald F., and Polyansky, Dmitry E. Tue . "Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer". United States. doi:10.1039/C9CC01896D.
@article{osti_1524551,
title = {Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer},
author = {Lymar, Sergei V. and Manbeck, Gerald F. and Polyansky, Dmitry E.},
abstractNote = {The equilibrium constants of hydrogen bonding (HB) between hydroxylic donors, ROH, and MLCT-excited Ru(bpy)2(bpz)2+ complex, 1(T) correlate with ROH empirical HB acidities, which is used for evaluating the unimolecular rate constants of concerted electron-proton transfer within the H-bonded Phenol-1(T) exciplexes.},
doi = {10.1039/C9CC01896D},
journal = {ChemComm},
number = 42,
volume = 55,
place = {United States},
year = {2019},
month = {4}
}

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This content will become publicly available on April 16, 2020
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