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Title: Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films

Abstract

The beneficial and detrimental effects of amido Pb impurities incorporated in methylammonium lead triiodide thin films are characterized by photoemission spectroscopy.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [4];  [1]; ORCiD logo [5]; ORCiD logo [1]
  1. Princeton Univ., NJ (United States)
  2. Colorado School of Mines, Golden, CO (United States)
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States); Centre National de la Recherche Scientifique (CNRS), Palaiseau (France). Institut Photovoltaïque d’Ile de France (IPVF)
  4. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  5. Colorado School of Mines, Golden, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
OSTI Identifier:
1524328
Alternate Identifier(s):
OSTI ID: 1483337
Report Number(s):
NREL/JA-5K00-74035
Journal ID: ISSN 2050-7526; JMCCCX
Grant/Contract Number:  
AC36-08GO28308
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 7; Journal Issue: 18; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; additives; amines; crystal impurities; inclusions; layered semiconductors; metal halides; molecules; morphology; optoelectronic devices; passivation; perovskites

Citation Formats

Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, and Rand, Barry P. Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films. United States: N. p., 2019. Web. doi:10.1039/C8TC04872J.
Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, & Rand, Barry P. Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films. United States. https://doi.org/10.1039/C8TC04872J
Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, and Rand, Barry P. Fri . "Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films". United States. https://doi.org/10.1039/C8TC04872J. https://www.osti.gov/servlets/purl/1524328.
@article{osti_1524328,
title = {Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films},
author = {Kerner, Ross A. and Schloemer, Tracy H. and Schulz, Philip and Berry, Joseph J. and Schwartz, Jeffrey and Sellinger, Alan and Rand, Barry P.},
abstractNote = {The beneficial and detrimental effects of amido Pb impurities incorporated in methylammonium lead triiodide thin films are characterized by photoemission spectroscopy.},
doi = {10.1039/C8TC04872J},
journal = {Journal of Materials Chemistry C},
number = 18,
volume = 7,
place = {United States},
year = {Fri Nov 15 00:00:00 EST 2019},
month = {Fri Nov 15 00:00:00 EST 2019}
}

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Free Publicly Available Full Text
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Cited by: 22 works
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Works referencing / citing this record:

Role of Capped Oleyl Amine in the Moisture‐Induced Structural Transformation of CsPbBr 3 Perovskite Nanocrystals
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