Porosity Dependence of Compression and Lattice Rigidity in Metal–Organic Framework Series

Redfern, Louis R.; Robison, Lee; Wasson, Megan C.; Goswami, Subhadip; Lyu, Jiafei; Islamoglu, Timur; Chapman, Karena W.; Farha, Omar K.

doi:10.1021/jacs.8b13009

Title: Porosity Dependence of Compression and Lattice Rigidity in Metal–Organic Framework Series

Journal Article · 18 February 2019 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.8b13009 · OSTI ID:1524084

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Northwestern Univ., Evanston, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States)
Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Stony Brook Univ., Stony Brook, NY (United States)

Porous materials, including metal-organic frameworks (MOFs), are known to undergo structural changes when subjected to applied hydrostatic pressures that are both fundamentally interesting and practically relevant. With the rich structural diversity of MOFs, the development of design rules to better understand and enhance the mechanical stability of MOFs is of paramount importance. In this work, the compressibilities of seven MOFs belonging to two topological families (representing the most comprehensive study of this type to date) were evaluated using in situ synchrotron X-ray powder diffraction of samples within a diamond anvil cell. The judicious selection of these materials, representing widely studied classes of MOFs, provides broadly applicable insight into the rigidity and compression of hybrid materials. An analysis of these data reveals that the bulk modulus depends on several structural parameters (e.g., void fraction and linker length). Furthermore, we find that lattice distortions play a major role in the compression of MOFs. As a result, this study is an important step toward developing a predictive model of the structural variables that dictate the compressibility of porous materials.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Graduate Student Research (SCGSR) Program; U.S. Department of Defense (DOD), Defense Threat Reduction Agency (DTRA); USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS) (SC-27)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1524084

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 10 Vol. 141; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Mechanical properties of metal–organic frameworks Redfern, Louis R.; Farha, Omar K. Chemical Science, Vol. 10, Issue 46 https://doi.org/10.1039/c9sc04249k	journal	January 2019
Mechanical properties of metal–organic frameworks Redfern, Louis R.; Farha, Omar K. Chemical Science, Vol. 10, Issue 46 https://doi.org/10.1039/c9sc04249k	journal	January 2019
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