DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Determining Gas Composition for Growth of BNNTs Using Thermodynamic Approach

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI: https://doi.org/10.1039/C9CP01342C · OSTI ID:1523580
 [1];  [1];  [1];  [1];  [2];  [3];  [1]
  1. Princeton Plasma Physics Lab. (PPPL), Princeton, NJ (United States)
  2. Univ. of Belgrade, Belgrade (Serbia)
  3. Princeton Plasma Physics Lab. (PPPL), Princeton, NJ (United States); Univ. of Syracuse, NY (United States)

A high-yield production of high-quality boron-nitride nanotubes (BNNTs) was reported recently in several publications. A boron-rich material is evaporated by a laser or plasma in a nitrogen-rich atmosphere to supply...

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Fusion Energy Sciences (FES)
Grant/Contract Number:
AC52-07NA27344
OSTI ID:
1523580
Alternate ID(s):
OSTI ID: 1525547
Report Number(s):
LLNL-JRNL-759618; PPCPFQ; 948016
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Vol. 21, Issue 24; ISSN 1463-9076
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 7 works
Citation information provided by
Web of Science

References (75)

Superhydrophobicity of Boron Nitride Nanotubes Grown on Silicon Substrates journal May 2009
Comprehensive Handbook of Chemical Bond Energies book March 2007
Induction plasma synthesis of fullerenes and nanotubes using carbon black–nickel particles journal December 2005
A b i n i t i o study of boron, nitrogen, and boron–nitrogen clusters. I. Isomers and thermochemistry of B 3 , B 2 N, BN 2 , and N 3 journal June 1989
Thermophysical properties of carbon–argon and carbon–helium plasmas journal August 2011
Scaled Synthesis of Boron Nitride Nanotubes, Nanoribbons, and Nanococoons Using Direct Feedstock Injection into an Extended-Pressure, Inductively-Coupled Thermal Plasma journal July 2014
Root-growth of boron nitride nanotubes: experiments and ab initio simulations journal January 2018
Hard‐Sphere Model for the Dissociation of Diatomic Molecules journal August 1964
Reactions of pulsed laser produced boron and nitrogen atoms in a condensing argon stream journal January 1993
Ab initio multireference study of the BN molecule journal November 1992
Hydrogen-Catalyzed, Pilot-Scale Production of Small-Diameter Boron Nitride Nanotubes and Their Macroscopic Assemblies journal May 2014
Isotope Effect on the Thermal Conductivity of Boron Nitride Nanotubes journal August 2006
Boron clusters (Bn, n = 2–52) produced by laser ablation of hexagonal boron nitride journal March 1992
Accurate multireference configuration interaction calculations on the lowest 1 Σ + and 3 Π electronic states of C 2 , CN + , BN, and BO + journal January 1995
Detection of boron nitride radicals by emission spectroscopy in a laser-induced plasma journal June 2001
Detection of nanoparticles in carbon arc discharge with laser-induced incandescence journal June 2017
Root-Growth Mechanism for Single-Walled Boron Nitride Nanotubes in Laser Vaporization Technique journal December 2007
Ab initio spectroscopy and thermochemistry of the BN molecule journal March 1991
Scalable manufacturing of boron nitride nanotubes and their assemblies: a review journal December 2016
Desorption characteristics of mechanically and chemically modified LiNH2 and (LiNH2+LiH) journal April 2007
Ionization layer at the edge of a fully ionized plasma journal February 1998
Quantitative imaging of carbon dimer precursor for nanomaterial synthesis in the carbon arc journal February 2018
Modeling of particulate coagulation in low pressure plasmas journal July 1999
Synthesis of nanoparticles in carbon arc: measurements and modeling journal May 2018
Theory of graphitic boron nitride nanotubes journal February 1994
Very long single- and few-walled boron nitride nanotubes via the pressurized vapor/condenser method journal November 2009
Modeling the synthesis of aluminum particles by evaporation-condensation in an aerosol flow reactor journal September 1995
Fast reverse osmosis using boron nitride and carbon nanotubes journal March 2008
A path for synthesis of boron-nitride nanostructures in volume of arc plasma journal January 2017
Chemical vapor deposition of MoS 2 layers from Mo–S–C–O–H system: thermodynamic modeling and validation journal January 2016
BNNT-Mediated Irreversible Electroporation: Its Potential on Cancer Cells journal October 2012
Comparison between Gibbs free energy minimization and mass action law for a multitemperature plasma with application to nitrogen journal June 1997
Young modulus, mechanical and electrical properties of isolated individual and bundled single-walled boron nitride nanotubes journal May 2011
Free Energies of Formation of Metal Clusters and Nanoparticles from Molecular Simulations:  Al n with n = 2−60 journal November 2007
Current understanding of the growth of carbon nanotubes in catalytic chemical vapour deposition journal July 2013
Mass-production of boron nitride double-wall nanotubes and nanococoons journal January 2000
Post-Synthesis Carbon Doping of Individual Multiwalled Boron Nitride Nanotubes via Electron-Beam Irradiation journal October 2010
Nonthermal Plasma Synthesis of Nanocrystals: Fundamental Principles, Materials, and Applications journal August 2016
Gas phase detection of cyclic B3: 2 2E′←X 2A1′ electronic origin band journal October 2004
Mechanisms of Postsynthesis Doping of Boron Nitride Nanostructures with Carbon from First-Principles Simulations journal July 2011
Plasma nanoscience: from nano-solids in plasmas to nano-plasmas in solids journal April 2013
Kinetic Monte Carlo simulation for homogeneous nucleation of metal nanoparticles during vapor phase synthesis journal August 2017
Anion photoelectron spectroscopy of small boron nitride clusters: adiabatic detachment energies and vibrational frequencies of low-lying electronic states in B2N and B3N journal December 1999
Plasma Nanoscience: From Nature's Mastery to Deterministic Plasma-Aided Nanofabrication journal April 2007
Selective synthesis of boron nitride nanotubes by self-propagation high-temperature synthesis and annealing process journal September 2011
Encapsulation capacity and natural payload delivery of an anticancer drug from boron nitride nanotube journal January 2016
Boron Nitride Nanotubes: Recent Advances in Their Synthesis, Functionalization, and Applications journal July 2016
Boron nitride nanotube: synthesis and applications
  • Tiano, Amanda L.; Park, Cheol; Lee, Joseph W.
  • SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring, SPIE Proceedings https://doi.org/10.1117/12.2045396
conference April 2014
A Simple Numerical Algorithm and Software for Solution of Nucleation, Surface Growth, and Coagulation Problems journal November 2003
N atom measurements in high-temperature N2 dissociation kinetics journal July 1986
Predicting impurity gases and phases during hydrogen evolution from complex metal hydrides using free energy minimization enabled by first-principles calculations journal January 2010
Reactions of nitrogen atoms Communication 4. Rate constant and mechanism of the elementary reaction of nitrogen atoms with molecular hydrogen journal March 1966
Thermodynamic Modelling of Boron Nitride Formation in Thermal Plasma journal July 2006
Fine carbon particle formation by carbon‐vapor condensation journal January 1979
Measurement of the elastic modulus of a multi-wall boron nitride nanotube journal February 1998
Effective growth of boron nitride nanotubes by thermal chemical vapor deposition journal October 2008
Radial Mechanical Properties of Single-Walled Boron Nitride Nanotubes journal November 2011
The Thermal Decomposition of NH 2 and NH Radicals journal October 1998
Stable synthesis of few-layered boron nitride nanotubes by anodic arc discharge journal June 2017
Thermodynamics and Kinetics of Nanoclusters Controlling Gas-to-Particle Nucleation journal April 2009
Mechanism for Low Temperature Growth of Boron Nitride Nanotubes journal September 2010
Simulations of the synthesis of boron-nitride nanostructures in a hot, high pressure gas volume journal January 2018
Molecular Spectra and Molecular Structure book January 1979
Electronic conduction in liquid boron journal October 2001
Computer simulation of water desalination through boron nitride nanotubes journal January 2017
Bimetallic catalytic growth of boron nitride nanotubes journal January 2017
Coagulation in a low-temperature plasma journal March 1996
Role of Hydrogen in High-Yield Growth of Boron Nitride Nanotubes at Atmospheric Pressure by Induction Thermal Plasma journal January 2018
Ammonium-tungstate-promoted growth of boron nitride nanotubes journal March 2018
Haber process for ammonia synthesis journal September 2002
Vibronic analysis of the band system of BNB journal May 2007
Haber process for ammonia synthesis journal December 2011
Plasma nanoscience: from nature's mastery to deterministic plasma-aided nanofabrication conference January 2006
Molecular Spectra and Molecular Structure journal November 1929
Molecular Spectra and Molecular Structure journal October 1929