Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO 3 ) 2 (pyz) 3

Huddart, Benjamin M.; Brambleby, Jamie; Lancaster, Tom; Goddard, Paul A.; Xiao, Fan; Blundell, Stephen J.; Pratt, Francis L.; Singleton, John; Macchi, Piero; Scatena, Rebecca; Barton, Alyssa M.; Manson, Jamie L.

doi:10.1039/C8CP07160H

Title: Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO ₃ ) ₂ (pyz) ₃

Abstract

The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO₃)₂(pyz)₃ has an intrachain coupling J = 13.7(1) K ($$\hat{H}$$ = J$$^{Σ}_{i}S_{i}$$• S_i+1) and exhibits a state of long-range magnetic order below T_N = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J'/J| = 3.3 × 10^–3, demonstrating a high degree of isolation for the Cu chains.

Authors:

^[1]; Brambleby, Jamie ^[2];

^[1];

^[2]; Xiao, Fan ^[3];

^[4];

^[5]; Singleton, John ^[6];

^[7];

^[8]; Barton, Alyssa M. ^[9];

^[9]

Centre for Materials Physics, Durham University, Durham DH1 3LE, UK
Department of Physics, University of Warwick, Coventry, UK
Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland, Laboratory for Neutron Scattering and Imaging
Department of Physics, Clarendon Laboratory, University of Oxford, Oxford OX1 3PU, UK
ISIS Pulsed Muon Facility, STFC Rutherford Appleton Laboratory, Chilton, UK
National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, USA
Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland, Polytechnic of Milan
Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland
Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, USA

Publication Date:: 2019-01-17

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF); European Research Council (ERC)

OSTI Identifier:: 1523545

Alternate Identifier(s):: OSTI ID: 1488668; OSTI ID: 1561076

Report Number(s):: LA-UR-18-30771
Journal ID: ISSN 1463-9076; PPCPFQ

Grant/Contract Number:: 89233218CNA000001

Resource Type:: Published Article

Journal Name:: Physical Chemistry Chemical Physics. PCCP

Additional Journal Information:: Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Volume: 21 Journal Issue: 3; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Huddart, Benjamin M., Brambleby, Jamie, Lancaster, Tom, Goddard, Paul A., Xiao, Fan, Blundell, Stephen J., Pratt, Francis L., Singleton, John, Macchi, Piero, Scatena, Rebecca, Barton, Alyssa M., and Manson, Jamie L. Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO 3 ) 2 (pyz) 3.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C8CP07160H.

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                    Huddart, Benjamin M., Brambleby, Jamie, Lancaster, Tom, Goddard, Paul A., Xiao, Fan, Blundell, Stephen J., Pratt, Francis L., Singleton, John, Macchi, Piero, Scatena, Rebecca, Barton, Alyssa M., & Manson, Jamie L. Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO 3 ) 2 (pyz) 3.  United Kingdom.  https://doi.org/10.1039/C8CP07160H

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                    Huddart, Benjamin M., Brambleby, Jamie, Lancaster, Tom, Goddard, Paul A., Xiao, Fan, Blundell, Stephen J., Pratt, Francis L., Singleton, John, Macchi, Piero, Scatena, Rebecca, Barton, Alyssa M., and Manson, Jamie L. Thu .  
"Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO 3 ) 2 (pyz) 3".  United Kingdom.  https://doi.org/10.1039/C8CP07160H.

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@article{osti_1523545,

  title        = {Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO 3 ) 2 (pyz) 3},

  author       = {Huddart, Benjamin M. and Brambleby, Jamie and Lancaster, Tom and Goddard, Paul A. and Xiao, Fan and Blundell, Stephen J. and Pratt, Francis L. and Singleton, John and Macchi, Piero and Scatena, Rebecca and Barton, Alyssa M. and Manson, Jamie L.},

  abstractNote = {The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K ($\hat{H}$ = J$^{Σ}_{i}S_{i}$• Si+1) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J'/J| = 3.3 × 10–3, demonstrating a high degree of isolation for the Cu chains.},

  doi          = {10.1039/C8CP07160H},

  journal      = {Physical Chemistry Chemical Physics. PCCP},

  number       = 3,

  volume       = 21,

  place        = {United Kingdom},

  year         = {2019},

  month        = {1}

}

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