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Title: Strong Metal–Support Interactions between Copper and Iron Oxide during the High‐Temperature Water‐Gas Shift Reaction

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2];  [3];  [1];  [3];  [2]; ORCiD logo [4]
  1. State Key Laboratory of Chemical Engineering East China University of Science and Technology Shanghai 200237 China
  2. Operando Molecular Spectroscopy &, Catalysis Laboratory Department of Chemical and Biomolecular Engineering Lehigh University Bethlehem PA 18015 USA
  3. Department of Inorganic Chemistry Fritz-Haber-Institut der Max-Planck-Gesellschaft Faradayweg 4–6 14195 Berlin Germany
  4. State Key Laboratory of Chemical Engineering East China University of Science and Technology Shanghai 200237 China, Research Center of Heterogeneous Catalysis and Engineering Sciences School of Chemical Engineering and Energy Zhengzhou University Zhengzhou 450001 China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1518524
Grant/Contract Number:  
FG02-05ER15688; AC02-98CH10886
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 58 Journal Issue: 27; Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zhu, Minghui, Tian, Pengfei, Kurtz, Ravi, Lunkenbein, Thomas, Xu, Jing, Schlögl, Robert, Wachs, Israel E., and Han, Yi‐Fan. Strong Metal–Support Interactions between Copper and Iron Oxide during the High‐Temperature Water‐Gas Shift Reaction. Germany: N. p., 2019. Web. doi:10.1002/anie.201903298.
Zhu, Minghui, Tian, Pengfei, Kurtz, Ravi, Lunkenbein, Thomas, Xu, Jing, Schlögl, Robert, Wachs, Israel E., & Han, Yi‐Fan. Strong Metal–Support Interactions between Copper and Iron Oxide during the High‐Temperature Water‐Gas Shift Reaction. Germany. https://doi.org/10.1002/anie.201903298
Zhu, Minghui, Tian, Pengfei, Kurtz, Ravi, Lunkenbein, Thomas, Xu, Jing, Schlögl, Robert, Wachs, Israel E., and Han, Yi‐Fan. Tue . "Strong Metal–Support Interactions between Copper and Iron Oxide during the High‐Temperature Water‐Gas Shift Reaction". Germany. https://doi.org/10.1002/anie.201903298.
@article{osti_1518524,
title = {Strong Metal–Support Interactions between Copper and Iron Oxide during the High‐Temperature Water‐Gas Shift Reaction},
author = {Zhu, Minghui and Tian, Pengfei and Kurtz, Ravi and Lunkenbein, Thomas and Xu, Jing and Schlögl, Robert and Wachs, Israel E. and Han, Yi‐Fan},
abstractNote = {},
doi = {10.1002/anie.201903298},
journal = {Angewandte Chemie (International Edition)},
number = 27,
volume = 58,
place = {Germany},
year = {2019},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/anie.201903298

Citation Metrics:
Cited by: 13 works
Citation information provided by
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Works referenced in this record:

High Temperature Water Gas Shift Reaction over Nanocrystalline Copper Codoped-Modified Ferrites
journal, March 2011

  • Reddy, Gunugunuri K.; Gunasekera, Kapila; Boolchand, P.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 15
  • DOI: 10.1021/jp2003084

A facile method for preparation of iron based catalysts for high temperature water gas shift reaction
journal, September 2014

  • Meshkani, Fereshteh; Rezaei, Mehran
  • Journal of Industrial and Engineering Chemistry, Vol. 20, Issue 5
  • DOI: 10.1016/j.jiec.2013.12.011

Some recent results on metal/support interaction effects in NM/CeO2 (NM: noble metal) catalysts
journal, April 1999


Strong Metal–Support Interactions between Gold Nanoparticles and ZnO Nanorods in CO Oxidation
journal, June 2012

  • Liu, Xiaoyan; Liu, Ming-Han; Luo, Yi-Chia
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja3033235

Dry Reforming of Methane on a Highly-Active Ni-CeO 2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking
journal, May 2016

  • Liu, Zongyuan; Grinter, David C.; Lustemberg, Pablo G.
  • Angewandte Chemie International Edition, Vol. 55, Issue 26
  • DOI: 10.1002/anie.201602489

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015

  • Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201411581

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014


Promoted Cu-Fe3O4 catalysts for low-temperature water gas shift reaction: Optimization of Cu content
journal, June 2018


Metal–support interactions in Pt/Al2O3 and Pd/Al2O3 catalysts for CO oxidation
journal, June 2010

  • Ivanova, A. S.; Slavinskaya, E. M.; Gulyaev, R. V.
  • Applied Catalysis B: Environmental, Vol. 97, Issue 1-2
  • DOI: 10.1016/j.apcatb.2010.03.024

Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction
journal, December 2007


Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction
journal, August 2017

  • Li, Siwei; Xu, Yao; Chen, Yifu
  • Angewandte Chemie International Edition, Vol. 56, Issue 36
  • DOI: 10.1002/anie.201705002

A Systematic Theoretical Study of Water Gas Shift Reaction on Cu(111) and Cu(110): Potassium Effect
journal, January 2019


Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
journal, January 1978

  • Tauster, S. J.; Fung, S. C.; Garten, R. L.
  • Journal of the American Chemical Society, Vol. 100, Issue 1
  • DOI: 10.1021/ja00469a029

Advanced Electron Microscopy of Metal-Support Interactions in Supported Metal Catalysts
journal, June 2011


Mechanistic Study on Water Gas Shift Reaction on the Fe 3 O 4 (111) Reconstructed Surface
journal, December 2015

  • Huang, Liang; Han, Bo; Zhang, Qingfan
  • The Journal of Physical Chemistry C, Vol. 119, Issue 52
  • DOI: 10.1021/acs.jpcc.5b09192

Hydrogen production by the water-gas shift reaction using CuNi/Fe 2 O 3 catalyst
journal, January 2015

  • Jha, Ajay; Jeong, Dae-Woon; Shim, Jae-Oh
  • Catalysis Science & Technology, Vol. 5, Issue 5
  • DOI: 10.1039/C5CY00173K

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012


Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003


Performance of spinel ferrite catalysts integrated with mesoporous Al2O3 in the high temperature water–gas shift reaction
journal, April 2015


Metal–Support Interactions between Nanosized Pt and Metal Oxides (WO 3 and TiO 2 ) Studied Using X-ray Photoelectron Spectroscopy
journal, September 2011

  • Lewera, Adam; Timperman, Laure; Roguska, Agata
  • The Journal of Physical Chemistry C, Vol. 115, Issue 41
  • DOI: 10.1021/jp2068446

Promotion Mechanisms of Iron Oxide-Based High Temperature Water–Gas Shift Catalysts by Chromium and Copper
journal, June 2016


Water-gas shift reaction: finding the mechanistic boundary
journal, January 1995


Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions
journal, February 2007

  • Rodriguez, José A.; Liu, Ping; Hrbek, Jan
  • Angewandte Chemie International Edition, Vol. 46, Issue 8
  • DOI: 10.1002/anie.200603931

Dynamic Behavior of the Surface Structure of Cu/ZnO/SiO2 Catalysts
journal, August 2002


Preparation of high temperature water gas shift catalyst with coprecipitation method in microemulsion system
journal, September 2016

  • Meshkani, Fereshteh; Rezaei, Mehran; Aboonasr Shiraz, Mohammad Hossein
  • Chemical Engineering Research and Design, Vol. 113
  • DOI: 10.1016/j.cherd.2016.06.025

In Situ Characterization of CuFe 2 O 4 and Cu/Fe 3 O 4 Water−Gas Shift Catalysts
journal, July 2009

  • Estrella, Michael; Barrio, Laura; Zhou, Gong
  • The Journal of Physical Chemistry C, Vol. 113, Issue 32
  • DOI: 10.1021/jp903818q

Study of iron-promoted Cu/SiO2 catalyst on high temperature reverse water gas shift reaction
journal, January 2004


Unexpected Behavior of Copper in Modified Ferrites during High Temperature WGS Reaction—Aspects of Fe 3+ ↔ Fe 2+ Redox Chemistry from Mössbauer and XPS Studies
journal, May 2012

  • Reddy, Gunugunuri K.; Boolchand, P.; Smirniotis, Panagiotis G.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 20
  • DOI: 10.1021/jp301090d

A rationally designed CuFe2O4–mesoporous Al2O3 composite towards stable performance of high temperature water–gas shift reaction
journal, January 2013

  • Subramanian, Vijayanand; Gnanakumar, Edwin S.; Jeong, Dae-Woon
  • Chemical Communications, Vol. 49, Issue 96
  • DOI: 10.1039/c3cc43699c

Effect of the reduction treatment on the structure and reactivity of silica-supported copper particles
journal, September 1991


The density functional theory studies on the promoting effect of the Cu-modified Fe 3 O 4 catalysts
journal, March 2015


Strong metal-support interactions
journal, November 1987


Effects of the Ce and Cr Contents in Fe–Ce–Cr Ferrite Spinels on the High-Temperature Water–Gas Shift Reaction
journal, February 2017

  • Devaiah, Damma; Smirniotis, Panagiotis G.
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 7
  • DOI: 10.1021/acs.iecr.6b04707

Iron-Based Catalysts for the High-Temperature Water–Gas Shift (HT-WGS) Reaction: A Review
journal, December 2015