Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities
Abstract
Conversion of lignocellulosic biomass to fuels and chemicals has attracted immense research and development around the world. Lowering recalcitrance of biomass in a cost-effective manner is a challenge to commercialize biomass-based technologies. Deep eutectic solvents (DESs) are new ‘green' solvents that have a high potential for biomass processing because of their low cost, low toxicity, biodegradability, easy recycling and reuse. This article discusses the properties of DESs and recent advances in their application for lignocellulosic biomass processing. The effectiveness of DESs in hydrolyzing lignin-carbohydrate complexes, removing lignin/hemicellulose from biomass as well as their effect on biomass deconstruction, crystallinity and enzymatic digestibility have been discussed. Moreover, this review presents recent findings on the compatibility of natural DESs with enzymes and microorganisms.
- Authors:
-
[3];
[4]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Indian Oil Corp., Haryana (India)
- Univ. of Tennessee, Knoxville, TN (United States); Indian Oil Corp., Haryana (India)
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1515640
- Alternate Identifier(s):
- OSTI ID: 1636856
- Grant/Contract Number:
- AC05-00OR22725; FWP ERKP752
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Biotechnology Advances
- Additional Journal Information:
- Journal Volume: 36; Journal Issue: 8; Journal ID: ISSN 0734-9750
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS
Citation Formats
Satlewal, Alok, Agrawal, Ruchi, Bhagia, Samarthya, Sangoro, Joshua, and Ragauskas, Arthur J. Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. United States: N. p., 2018.
Web. doi:10.1016/j.biotechadv.2018.08.009.
Satlewal, Alok, Agrawal, Ruchi, Bhagia, Samarthya, Sangoro, Joshua, & Ragauskas, Arthur J. Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. United States. https://doi.org/10.1016/j.biotechadv.2018.08.009
Satlewal, Alok, Agrawal, Ruchi, Bhagia, Samarthya, Sangoro, Joshua, and Ragauskas, Arthur J. Wed .
"Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities". United States. https://doi.org/10.1016/j.biotechadv.2018.08.009. https://www.osti.gov/servlets/purl/1515640.
@article{osti_1515640,
title = {Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities},
author = {Satlewal, Alok and Agrawal, Ruchi and Bhagia, Samarthya and Sangoro, Joshua and Ragauskas, Arthur J.},
abstractNote = {Conversion of lignocellulosic biomass to fuels and chemicals has attracted immense research and development around the world. Lowering recalcitrance of biomass in a cost-effective manner is a challenge to commercialize biomass-based technologies. Deep eutectic solvents (DESs) are new ‘green' solvents that have a high potential for biomass processing because of their low cost, low toxicity, biodegradability, easy recycling and reuse. This article discusses the properties of DESs and recent advances in their application for lignocellulosic biomass processing. The effectiveness of DESs in hydrolyzing lignin-carbohydrate complexes, removing lignin/hemicellulose from biomass as well as their effect on biomass deconstruction, crystallinity and enzymatic digestibility have been discussed. Moreover, this review presents recent findings on the compatibility of natural DESs with enzymes and microorganisms.},
doi = {10.1016/j.biotechadv.2018.08.009},
journal = {Biotechnology Advances},
number = 8,
volume = 36,
place = {United States},
year = {Wed Sep 05 00:00:00 EDT 2018},
month = {Wed Sep 05 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 198 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Deep Eutectic Solvents Formed between Choline Chloride and Carboxylic Acids: Versatile Alternatives to Ionic Liquids
journal, July 2004
- Abbott, Andrew P.; Boothby, David; Capper, Glen
- Journal of the American Chemical Society, Vol. 126, Issue 29
Potential applications of deep eutectic solvents in nanotechnology
journal, August 2015
- Abo-Hamad, Ali; Hayyan, Maan; AlSaadi, Mohammed AbdulHakim
- Chemical Engineering Journal, Vol. 273
Improved saccharification of pilot-scale acid pretreated wheat straw by exploiting the synergistic behavior of lignocellulose degrading enzymes
journal, January 2015
- Agrawal, Ruchi; Gaur, Ruchi; Mathur, Anshu
- RSC Advances, Vol. 5, Issue 87
Pilot scale pretreatment of wheat straw and comparative evaluation of commercial enzyme preparations for biomass saccharification and fermentation
journal, October 2015
- Agrawal, Ruchi; Satlewal, Alok; Gaur, Ruchi
- Biochemical Engineering Journal, Vol. 102
Application of nanoparticle-immobilized thermostable β-glucosidase for improving the sugarcane juice properties
journal, February 2016
- Agrawal, Ruchi; Verma, A. K.; Satlewal, Alok
- Innovative Food Science & Emerging Technologies, Vol. 33
Investigating the enzyme-lignin binding with surfactants for improved saccharification of pilot scale pretreated wheat straw
journal, January 2017
- Agrawal, Ruchi; Satlewal, Alok; Kapoor, Manali
- Bioresource Technology, Vol. 224
Induction of cellulases by disaccharides or their derivatives in Penicillium janthinellum EMS-UV-8 mutant
journal, October 2016
- Agrawal, Ruchi; Satlewal, Alok; Sharma, Bhawna
- Biofuels, Vol. 8, Issue 5
Toxicological challenges to microbial bioethanol production and strategies for improved tolerance
journal, September 2015
- Akinosho, Hannah; Rydzak, Thomas; Borole, Abhijeet
- Ecotoxicology, Vol. 24, Issue 10
Glycerol-based deep eutectic solvents: Physical properties
journal, March 2016
- AlOmar, Mohamed Khalid; Hayyan, Maan; Alsaadi, Mohammed Abdulhakim
- Journal of Molecular Liquids, Vol. 215
Unique low-molecular-weight lignin with high purity extracted from wood by deep eutectic solvents (DES): a source of lignin for valorization
journal, January 2016
- Alvarez-Vasco, Carlos; Ma, Ruoshui; Quintero, Melissa
- Green Chemistry, Vol. 18, Issue 19
Highly efficient deep eutectic solvent catalyzed ring opening of epoxides
journal, January 2012
- Azizi, Najmadin; Batebi, Elham
- Catalysis Science & Technology, Vol. 2, Issue 12
A highly efficient synthesis of dithiocarbamates in green reaction media
journal, January 2012
- Azizi, Najmadin; Gholibeglo, Elham
- RSC Advances, Vol. 2, Issue 19
Eutectic salts promote green synthesis of bis(indolyl) methanes
journal, January 2012
- Azizi, Najmadin; Manocheri, Zohreh
- Research on Chemical Intermediates, Vol. 38, Issue 7
Deep eutectic solvent promoted highly efficient synthesis of N, N’-diarylamidines and formamides
journal, September 2012
- Azizi, Najmadin; Gholibeglo, Elham; Babapour, Mahbobe
- Comptes Rendus Chimie, Vol. 15, Issue 9
A sustainable approach to the Ugi reaction in deep eutectic solvent
journal, December 2013
- Azizi, Najmedin; Dezfooli, Sahar; Hashemi, Mohammad Mahmoodi
- Comptes Rendus Chimie, Vol. 16, Issue 12
Greener synthesis of spirooxindole in deep eutectic solvent
journal, June 2014
- Azizi, Najmedin; Dezfooli, Sahar; Mahmoudi Hashemi, Mohammad
- Journal of Molecular Liquids, Vol. 194
Flowthrough pretreatment with very dilute acid provides insights into high lignin contribution to biomass recalcitrance
journal, November 2016
- Bhagia, Samarthya; Li, Hongjia; Gao, Xiadi
- Biotechnology for Biofuels, Vol. 9, Issue 1
The regiospecific Fischer indole reaction in choline chloride·2ZnCl 2 with product isolation by direct sublimation from the ionic liquid
journal, January 2004
- Calderon Morales, Raul; Tambyrajah, Vasuki; Jenkins, Paul R.
- Chem. Commun., Issue 2
Green methods of lignocellulose pretreatment for biorefinery development
journal, October 2016
- Capolupo, Laura; Faraco, Vincenza
- Applied Microbiology and Biotechnology, Vol. 100, Issue 22
Mixing cations with different alkyl chain lengths markedly depresses the melting point in deep eutectic solvents formed from alkylammonium bromide salts and urea
journal, January 2017
- Chen, Zhengfei; Greaves, Tamar L.; Warr, Gregory G.
- Chemical Communications, Vol. 53, Issue 15
Novel Brønsted acidic deep eutectic solvent as reaction media for esterification of carboxylic acid with alcohols
journal, September 2012
- De Santi, Valerio; Cardellini, Fabio; Brinchi, Lucia
- Tetrahedron Letters, Vol. 53, Issue 38
Choline chloride·2ZnCl2 ionic liquid: an efficient and reusable catalyst for the solvent free Kabachnik–Fields reaction
journal, May 2012
- Disale, Shamrao T.; Kale, Sandip R.; Kahandal, Sandeep S.
- Tetrahedron Letters, Vol. 53, Issue 18
Recent trends in (ligno)cellulose dissolution using neoteric solvents: switchable, distillable and bio-based ionic liquids: Recent trends in (ligno)cellulose dissolution with ionic liquids
journal, September 2013
- Domínguez de María, Pablo
- Journal of Chemical Technology & Biotechnology, Vol. 89, Issue 1
Green and moisture-stable Lewis acidic ionic liquids (choline chloride ·xZnCl2) catalyzed protection of carbonyls at room temperature under solvent-free conditions
journal, September 2006
- Duan, Zhiying; Gu, Yanlong; Deng, Youquan
- Catalysis Communications, Vol. 7, Issue 9
Cellulose and lignin colocalization at the plant cell wall surface limits microbial hydrolysis of Populus biomass
journal, January 2017
- Dumitrache, Alexandru; Tolbert, Allison; Natzke, Jace
- Green Chemistry, Vol. 19, Issue 9
Characterization of Lignin Streams during Bionic Liquid-Based Pretreatment from Grass, Hardwood, and Softwood
journal, January 2018
- Dutta, Tanmoy; Papa, Gabriella; Wang, Eileen
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 3
Natural designer solvents for greening analytical chemistry
journal, February 2016
- Espino, Magdalena; de los Ángeles Fernández, María; Gomez, Federico J. V.
- TrAC Trends in Analytical Chemistry, Vol. 76
Reviving Pretreatment Effectiveness of Deep Eutectic Solvents on Lignocellulosic Date Palm Residues by Prior Recalcitrance Reduction
journal, March 2017
- Fang, Chuanji; Thomsen, Mette Hedegaard; Frankær, Christian Grundahl
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 12
New natural and renewable low transition temperature mixtures (LTTMs): screening as solvents for lignocellulosic biomass processing
journal, January 2012
- Francisco, María; van den Bruinhorst, Adriaan; Kroon, Maaike C.
- Green Chemistry, Vol. 14, Issue 8
Lignin Extraction from Straw by Ionic Liquids and Enzymatic Hydrolysis of the Cellulosic Residues
journal, March 2010
- Fu, Dongbao; Mazza, Giuseppe; Tamaki, Yukihiro
- Journal of Agricultural and Food Chemistry, Vol. 58, Issue 5
Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications
journal, March 2015
- García, Gregorio; Aparicio, Santiago; Ullah, Ruh
- Energy & Fuels, Vol. 29, Issue 4
Fischer Indole Synthesis in Low Melting Mixtures
journal, August 2012
- Gore, Sangram; Baskaran, Sundarababu; König, Burkhard
- Organic Letters, Vol. 14, Issue 17
Hydrolase-catalyzed biotransformations in deep eutectic solvents
journal, January 2008
- Gorke, Johnathan T.; Srienc, Friedrich; Kazlauskas, Romas J.
- Chemical Communications, Issue 10
Charge Transport and Structural Dynamics in Carboxylic-Acid-Based Deep Eutectic Mixtures
journal, July 2014
- Griffin, Philip J.; Cosby, Tyler; Holt, Adam P.
- The Journal of Physical Chemistry B, Vol. 118, Issue 31
Applicability evaluation of Deep Eutectic Solvents–Cellulase system for lignocellulose hydrolysis
journal, April 2015
- Gunny, Ahmad Anas Nagoor; Arbain, Dachyar; Nashef, Enas Muen
- Bioresource Technology, Vol. 181
Challenges for recycling ionic liquids by using pressure driven membrane processes
journal, January 2010
- Haerens, Kurt; Van Deuren, Stephanie; Matthijs, Edward
- Green Chemistry, Vol. 12, Issue 12
Organic synthesis in deep eutectic solvents: Paal–Knorr reactions
journal, August 2013
- Handy, Scott; Lavender, Kevin
- Tetrahedron Letters, Vol. 54, Issue 33
A mild synthesis of bis(indolyl)methanes using a deep eutectic solvent
journal, August 2014
- Handy, Scott; Westbrook, Nicole M.
- Tetrahedron Letters, Vol. 55, Issue 35
An acid-free Pictet–Spengler reaction using deep eutectic solvents (DES)
journal, June 2014
- Handy, Scott; Wright, Matthew
- Tetrahedron Letters, Vol. 55, Issue 23
Comparison of autohydrolysis and ionic liquid 1-butyl-3-methylimidazolium acetate pretreatment to enhance enzymatic hydrolysis of sugarcane bagasse
journal, January 2017
- Hashmi, Muzna; Sun, Qining; Tao, Jingming
- Bioresource Technology, Vol. 224
Glucose-based deep eutectic solvents: Physical properties
journal, February 2013
- Hayyan, Adeeb; Mjalli, Farouq S.; AlNashef, Inas M.
- Journal of Molecular Liquids, Vol. 178
Assessment of cytotoxicity and toxicity for phosphonium-based deep eutectic solvents
journal, September 2013
- Hayyan, Maan; Hashim, Mohd Ali; Al-Saadi, Mohammed A.
- Chemosphere, Vol. 93, Issue 2
Are deep eutectic solvents benign or toxic?
journal, February 2013
- Hayyan, Maan; Hashim, Mohd Ali; Hayyan, Adeeb
- Chemosphere, Vol. 90, Issue 7
Novel renewable ionic liquids as highly effective solvents for pretreatment of rice straw biomass by selective removal of lignin
journal, April 2012
- Hou, Xue-Dan; Smith, Thomas J.; Li, Ning
- Biotechnology and Bioengineering, Vol. 109, Issue 10
Facile and Simple Pretreatment of Sugar Cane Bagasse without Size Reduction Using Renewable Ionic Liquids–Water Mixtures
journal, March 2013
- Hou, Xue-Dan; Li, Ning; Zong, Min-Hua
- ACS Sustainable Chemistry & Engineering, Vol. 1, Issue 5
Significantly enhanced enzymatic hydrolysis of rice straw via a high-performance two-stage deep eutectic solvents synergistic pretreatment
journal, August 2017
- Hou, Xue-Dan; Feng, Guo-Jian; Ye, Mei
- Bioresource Technology, Vol. 238
Direct conversion of inulin to 5-hydroxymethylfurfural in biorenewable ionic liquids
journal, January 2009
- Hu, Suqin; Zhang, Zhaofu; Zhou, Yinxi
- Green Chemistry, Vol. 11, Issue 6
Low-melting sugar–urea–salt mixtures as solvents for Diels–Alder reactions
journal, January 2005
- Imperato, Giovanni; Eibler, Ernst; Niedermaier, Julia
- Chem. Commun., Issue 9
Low melting sugar–urea–salt mixtures as solvents for organic reactions—estimation of polarity and use in catalysis
journal, January 2006
- Imperato, Giovanni; Höger, Silke; Lenoir, Dieter
- Green Chem., Vol. 8, Issue 12
Tailoring and recycling of deep eutectic solvents as sustainable and efficient extraction media
journal, December 2015
- Jeong, Kyung Min; Lee, Min Sang; Nam, Min Woo
- Journal of Chromatography A, Vol. 1424
A critical review of analytical methods in pretreatment of lignocelluloses: Composition, imaging, and crystallinity
journal, January 2016
- Karimi, Keikhosro; Taherzadeh, Mohammad J.
- Bioresource Technology, Vol. 200
Biomass pretreatment using deep eutectic solvents from lignin derived phenols
journal, January 2018
- Kim, Kwang Ho; Dutta, Tanmoy; Sun, Jian
- Green Chemistry, Vol. 20, Issue 4
Natural deep eutectic solvent mediated pretreatment of rice straw: bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue
journal, June 2015
- Kumar, Adepu K.; Parikh, Bhumika S.; Pravakar, Mohanty
- Environmental Science and Pollution Research, Vol. 23, Issue 10
Reengineering CelA2 cellulase for hydrolysis in aqueous solutions of deep eutectic solvents and concentrated seawater
journal, January 2012
- Lehmann, Christian; Sibilla, Fabrizio; Maugeri, Zaira
- Green Chemistry, Vol. 14, Issue 10
Ionic liquid and deep eutectic solvent-activated CelA2 variants generated by directed evolution
journal, May 2014
- Lehmann, Christian; Bocola, Marco; Streit, Wolfgang R.
- Applied Microbiology and Biotechnology, Vol. 98, Issue 12
Extraction desulfurization process of fuels with ammonium-based deep eutectic solvents
journal, January 2013
- Li, Changping; Li, Dan; Zou, Shuangshuang
- Green Chemistry, Vol. 15, Issue 10
Highly Efficient Low Melting Mixture Catalyzed Synthesis of 1,8-Dioxo-dodecahydroxanthene Derivatives
journal, May 2013
- Li, Peihe; Ma, Feiping; Wang, Ping
- Chinese Journal of Chemistry, Vol. 31, Issue 6
Current Understanding of the Correlation of Lignin Structure with Biomass Recalcitrance
journal, November 2016
- Li, Mi; Pu, Yunqiao; Ragauskas, Arthur J.
- Frontiers in Chemistry, Vol. 4
The effect of ionic liquids pretreatment on the distribution and structure of alkali-soluble hemicelluloses from Eucalyptus
journal, January 2018
- Li, Han-Yin; Chen, Xue; Li, Yi-Jing
- Separation and Purification Technology, Vol. 191
Switchable ionic liquids based on di-carboxylic acids for one-pot conversion of biomass to an advanced biofuel
journal, January 2016
- Liszka, Michael J.; Kang, Aram; Konda, N. V. S. N. Murthy
- Green Chemistry, Vol. 18, Issue 14
Bio-compatible eutectic mixture for multi-component synthesis: A valuable acidic catalyst for synthesis of novel 2,3-dihydroquinazolin-4(1H)-one derivatives
journal, October 2012
- Lobo, Hyacintha Rennet; Singh, Balvant Shyam; Shankarling, Ganapati Subray
- Catalysis Communications, Vol. 27
Deep eutectic solvents and glycerol: a simple, environmentally benign and efficient catalyst/reaction media for synthesis of N- aryl phthalimide derivatives
journal, December 2012
- Lobo, Hyacintha Rennet; Singh, Balvant Shyam; Shankarling, Ganapati Subray
- Green Chemistry Letters and Reviews, Vol. 5, Issue 4
Lipase and Deep Eutectic Mixture Catalyzed Efficient Synthesis of Thiazoles in Water at Room Temperature
journal, September 2012
- Lobo, Hyacintha Rennet; Singh, Balvant Shyam; Shankarling, Ganapati Subray
- Catalysis Letters, Vol. 142, Issue 11
Potential use of deep eutectic solvents to facilitate lignocellulosic biomass utilization and conversion
journal, June 2017
- Loow, Yu-Loong; New, Eng Kein; Yang, Ge Hoa
- Cellulose, Vol. 24, Issue 9
Deep eutectic solvent and inorganic salt pretreatment of lignocellulosic biomass for improving xylose recovery
journal, February 2018
- Loow, Yu-Loong; Wu, Ta Yeong; Yang, Ge Hoa
- Bioresource Technology, Vol. 249
Natural deep eutectic solvents in combination with ultrasonic energy as a green approach for solubilisation of proteins: application to gluten determination by immunoassay
journal, January 2017
- Lores, H.; Romero, V.; Costas, I.
- Talanta, Vol. 162
Deep eutectic solvents’ ability to solubilize lignin, cellulose, and hemicellulose; thermal stability; and density
journal, August 2017
- Lynam, Joan G.; Kumar, Narendra; Wong, Mark J.
- Bioresource Technology, Vol. 238
The grand challenge of cellulosic biofuels
journal, October 2017
- Lynd, Lee R.
- Nature Biotechnology, Vol. 35, Issue 10
Whole-Cell Biocatalysis in Deep-Eutectic-Solvents/Aqueous Mixtures
journal, March 2014
- Maugeri, Zaira; Domínguez de María, Pablo
- ChemCatChem, Vol. 6, Issue 6
Applications of deep eutectic solvents in biotechnology and bioengineering—Promises and challenges
journal, March 2017
- Mbous, Yves Paul; Hayyan, Maan; Hayyan, Adeeb
- Biotechnology Advances, Vol. 35, Issue 2
Deep Eutectic Solvent (DES) as a Pretreatment for Oil Palm Empty Fruit Bunch (OPEFB) in Sugar Production
journal, January 2016
- Nor, Nur Atikah Md; Mustapha, Wan Aida Wan; Hassan, Osman
- Procedia Chemistry, Vol. 18
Contribution of Deep Eutectic Solvents for Biomass Processing: Opportunities, Challenges, and Limitations
journal, March 2015
- Vigier, Karine De Oliveira; Chatel, Gregory; Jérôme, François
- ChemCatChem, Vol. 7, Issue 8
Environmentally benign and energy efficient methodology for condensation: an interesting facet to the classical Perkin reaction
journal, January 2011
- Pawar, Poonam Mahadev; Jarag, Krishna Jagannath; Shankarling, Ganapati Subray
- Green Chemistry, Vol. 13, Issue 8
Halogenation reactions in biodegradable solvent: Efficient bromination of substituted 1-aminoanthra-9,10-quinone in deep eutectic solvent (choline chloride : urea)
journal, January 2010
- Phadtare, Sunanda Balaso; Shankarling, Ganapati Subray
- Green Chemistry, Vol. 12, Issue 3
Greener protocol for one pot synthesis of coumarin styryl dyes
journal, April 2013
- Phadtare, Sunanda B.; Jarag, Krishna J.; Shankarling, Ganapati S.
- Dyes and Pigments, Vol. 97, Issue 1
Deep eutectic solvent pretreatment and subsequent saccharification of corncob
journal, September 2015
- Procentese, Alessandra; Johnson, Erin; Orr, Valerie
- Bioresource Technology, Vol. 192
Deep Eutectic Solvents pretreatment of agro-industrial food waste
journal, February 2018
- Procentese, Alessandra; Raganati, Francesca; Olivieri, Giuseppe
- Biotechnology for Biofuels, Vol. 11, Issue 1
Ionic liquid pretreatment of biomass for sugars production: Driving factors with a plausible mechanism for higher enzymatic digestibility
journal, September 2016
- Raj, Tirath; Gaur, Ruchi; Dixit, Pooja
- Carbohydrate Polymers, Vol. 149
Synthesis of a Novel Allyl-Functionalized Deep Eutectic Solvent to Promote Dissolution of Cellulose
journal, August 2016
- Ren, Hongwei; Chen, Chunmao; Guo, Shaohui
- BioResources, Vol. 11, Issue 4
The Properties of Choline Chloride-based Deep Eutectic Solvents and their Performance in the Dissolution of Cellulose
journal, February 2016
- Ren, Hongwei; Chen, Chunmao; Wang, Qinghong
- BioResources, Vol. 11, Issue 2
Eco-friendly and recyclable media for rapid synthesis of tricyanovinylated aromatics using biocatalyst and deep eutectic solvent
journal, April 2014
- Sanap, Anita Kailas; Shankarling, Ganapati Subray
- Catalysis Communications, Vol. 49
Screening of deep eutectic solvents (DESs) as green CO 2 sorbents: from solubility to viscosity
journal, January 2017
- Sarmad, Shokat; Xie, Yujiao; Mikkola, Jyri-Pekka
- New Journal of Chemistry, Vol. 41, Issue 1
Rice straw as a feedstock for biofuels: Availability, recalcitrance, and chemical properties
journal, October 2017
- Satlewal, Alok; Agrawal, Ruchi; Bhagia, Samarthya
- Biofuels, Bioproducts and Biorefining, Vol. 12, Issue 1
Pretreatment processes for lignocellulosic biomass conversion to biofuels and bioproducts
journal, October 2016
- Seidl, Peter R.; Goulart, Adriana K.
- Current Opinion in Green and Sustainable Chemistry, Vol. 2
Prediction of deep eutectic solvents densities at different temperatures
journal, March 2011
- Shahbaz, K.; Mjalli, F. S.; Hashim, M. A.
- Thermochimica Acta, Vol. 515, Issue 1-2
Selective N-Alkylation of Aromatic Primary Amines Catalyzed by Bio-catalyst or Deep Eutectic Solvent
journal, November 2010
- Singh, Balvant; Lobo, Hyacintha; Shankarling, Ganapati
- Catalysis Letters, Vol. 141, Issue 1
Ultrasound and deep eutectic solvent (DES): A novel blend of techniques for rapid and energy efficient synthesis of oxazoles
journal, January 2013
- Singh, Balvant S.; Lobo, Hyacintha R.; Pinjari, Dipak V.
- Ultrasonics Sonochemistry, Vol. 20, Issue 1
Deep Eutectic Solvents (DESs) and Their Applications
journal, October 2014
- Smith, Emma L.; Abbott, Andrew P.; Ryder, Karl S.
- Chemical Reviews, Vol. 114, Issue 21
Recent developments in deep eutectic solvents in chemical sciences
journal, August 2013
- Tang, Baokun; Row, Kyung Ho
- Monatshefte für Chemie - Chemical Monthly, Vol. 144, Issue 10
Green Processing of Lignocellulosic Biomass and Its Derivatives in Deep Eutectic Solvents
journal, May 2017
- Tang, Xing; Zuo, Miao; Li, Zheng
- ChemSusChem, Vol. 10, Issue 13
A comparison of various lignin-extraction methods to enhance the accessibility and ease of enzymatic hydrolysis of the cellulosic component of steam-pretreated poplar
journal, June 2017
- Tian, Dong; Chandra, Richard P.; Lee, Jin-Suk
- Biotechnology for Biofuels, Vol. 10, Issue 1
Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation
journal, January 2017
- van Osch, Dannie J. G. P.; Kollau, Laura J. B. M.; van den Bruinhorst, Adriaan
- Physical Chemistry Chemical Physics, Vol. 19, Issue 4
Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air
journal, April 2014
- Vidal, Cristian; García-Álvarez, Joaquín; Hernán-Gómez, Alberto
- Angewandte Chemie International Edition, Vol. 53, Issue 23
Comparison of three deep eutectic solvents and 1-ethyl-3-methylimidazolium acetate in the pretreatment of lignocellulose: effect on enzyme stability, lignocellulose digestibility and one-pot hydrolysis
journal, January 2016
- Wahlström, Ronny; Hiltunen, Jaakko; Pitaluga de Souza Nascente Sirkka, Mariáh
- RSC Advances, Vol. 6, Issue 72
Genetic modification of plant cell walls to enhance biomass yield and biofuel production in bioenergy crops
journal, September 2016
- Wang, Yanting; Fan, Chunfen; Hu, Huizhen
- Biotechnology Advances, Vol. 34, Issue 5
Transforming biomass conversion with ionic liquids: process intensification and the development of a high-gravity, one-pot process for the production of cellulosic ethanol
journal, January 2016
- Xu, Feng; Sun, Jian; Konda, N. V. S. N. Murthy
- Energy & Environmental Science, Vol. 9, Issue 3
Enhancing cellulose accessibility of corn stover by deep eutectic solvent pretreatment for butanol fermentation
journal, March 2016
- Xu, Guo-Chao; Ding, Ji-Cai; Han, Rui-Zhi
- Bioresource Technology, Vol. 203
Recent progress on deep eutectic solvents in biocatalysis
journal, July 2017
- Xu, Pei; Zheng, Gao-Wei; Zong, Min-Hua
- Bioresources and Bioprocessing, Vol. 4, Issue 1
Room temperature ionic liquid choline chloride–oxalic acid: A versatile catalyst for acid-catalyzed transformation in organic reactions
journal, March 2014
- Yadav, Urmiladevi Narad; Shankarling, Ganapati Subray
- Journal of Molecular Liquids, Vol. 191
High Regioselective Diels--Alder Reaction of Myrcene with Acrolein Catalyzed by Zinc-Containing Ionic Liquids
journal, January 2005
- Yin, Donghong; Li, Changzhi; Li, Biaomo
- Advanced Synthesis & Catalysis, Vol. 347, Issue 1
Efficient Cleavage of Lignin-Carbohydrate Complexes and Ultrafast Extraction of Lignin Oligomers from Wood Biomass by Microwave-Assisted Treatment with Deep Eutectic Solvent
journal, March 2017
- Liu, Yongzhuang; Chen, Wenshuai; Xia, Qinqin
- ChemSusChem, Vol. 10, Issue 8
Ionic liquids: Promising green solvents for lignocellulosic biomass utilization
journal, June 2017
- Yoo, Chang Geun; Pu, Yunqiao; Ragauskas, Arthur J.
- Current Opinion in Green and Sustainable Chemistry, Vol. 5
Deep eutectic solvents: similia similibus solvuntur?
journal, January 2017
- Zahn, Stefan
- Physical Chemistry Chemical Physics, Vol. 19, Issue 5
Green and Inexpensive Choline-Derived Solvents for Cellulose Decrystallization
journal, December 2011
- Zhang, Qinghua; Benoit, Maud; De Oliveira Vigier, Karine
- Chemistry - A European Journal, Vol. 18, Issue 4
Deep eutectic solvents: syntheses, properties and applications
journal, January 2012
- Zhang, Qinghua; De Oliveira Vigier, Karine; Royer, Sébastien
- Chemical Society Reviews, Vol. 41, Issue 21
Facile pretreatment of lignocellulosic biomass using deep eutectic solvents
journal, November 2016
- Zhang, Cheng-Wu; Xia, Shu-Qian; Ma, Pei-Sheng
- Bioresource Technology, Vol. 219
Supported choline chloride/urea as a heterogeneous catalyst for chemical fixation of carbon dioxide to cyclic carbonates
journal, January 2007
- Zhu, Anlian; Jiang, Tao; Han, Buxing
- Green Chemistry, Vol. 9, Issue 2, p. 169-172
Direct nucleophilic substitution reaction of alcohols mediated by a zinc-based ionic liquid
journal, January 2011
- Zhu, Anlian; Li, Lingjun; Wang, Jianji
- Green Chemistry, Vol. 13, Issue 5
Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk
journal, July 2017
- Zulkefli, Syarilaida; Abdulmalek, Emilia; Abdul Rahman, Mohd. Basyaruddin
- Renewable Energy, Vol. 107
Green process for production of 5-hydroxymethylfurfural from carbohydrates with high purity in deep eutectic solvents
journal, May 2017
- Zuo, Miao; Le, Kai; Li, Zheng
- Industrial Crops and Products, Vol. 99
Works referencing / citing this record:
High value‐added monomer chemicals and functional bio‐based materials derived from polymeric components of lignocellulose by organosolv fractionation
journal, November 2019
- Zhang, Jingzhi; Cai, Di; Qin, Yanlin
- Biofuels, Bioproducts and Biorefining
Engineering microbial pathways for production of bio-based chemicals from lignocellulosic sugars: current status and perspectives
journal, July 2020
- Francois, Jean Marie; Alkim, Ceren; Morin, Nicolas
- Biotechnology for Biofuels, Vol. 13, Issue 1
Green Solvents for the Extraction of High Added-Value Compounds from Agri-food Waste
journal, November 2019
- Torres-Valenzuela, Laura Sofía; Ballesteros-Gómez, Ana; Rubio, Soledad
- Food Engineering Reviews, Vol. 12, Issue 1
Integration of renewable deep eutectic solvents with engineered biomass to achieve a closed-loop biorefinery
journal, June 2019
- Kim, Kwang Ho; Eudes, Aymerick; Jeong, Keunhong
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 28
Deep Eutectic Solvents for Pretreatment, Extraction, and Catalysis of Biomass and Food Waste
journal, November 2019
- Kalhor, Payam; Ghandi, Khashayar
- Molecules, Vol. 24, Issue 22
Quest for Green‐Solvent Design: From Hydrophilic to Hydrophobic (Deep) Eutectic Solvents
journal, April 2019
- Florindo, Catarina; Branco, Luís C.; Marrucho, Isabel M.
- ChemSusChem, Vol. 12, Issue 8
Developing Efficient Thermophilic Cellulose Degrading Consortium for Glucose Production From Different Agro-Residues
journal, July 2019
- Singh, Saurabh; Jaiswal, Durgesh Kumar; Sivakumar, Nallusamy
- Frontiers in Energy Research, Vol. 7
Deep eutectic solvents (DESs) for cellulose dissolution: a mini-review
journal, November 2018
- Chen, Yang-Lei; Zhang, Xun; You, Ting-Ting
- Cellulose, Vol. 26, Issue 1
Pretreatment for biorefineries: a review of common methods for efficient utilisation of lignocellulosic materials
journal, December 2019
- Galbe, Mats; Wallberg, Ola
- Biotechnology for Biofuels, Vol. 12, Issue 1
Production of Nanocellulose Using Hydrated Deep Eutectic Solvent Combined with Ultrasonic Treatment
journal, May 2019
- Ma, Yue; Xia, Qinqin; Liu, Yongzhuang
- ACS Omega, Vol. 4, Issue 5
Deep Eutectic Solvents for Pretreatment, Extraction, and Catalysis of Biomass and Food Waste
journal, November 2019
- Kalhor, Payam; Ghandi, Khashayar
- Molecules, Vol. 24, Issue 22