Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Efficient conversion of lignin into a water-soluble polymer by a chelator-mediated Fenton reaction: optimization of H 2 O 2 use and performance as a dispersant

Abstract

Transforming lignin into a water-soluble polymer.

Authors:
ORCiD logo [1];  [1];  [2];  [2];  [2]; ORCiD logo [2];  [2]; ORCiD logo [2];  [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1];  [2];  [1]
+ Show Author Affiliations
  1. Joint BioEnergy Inst., Emeryville, CA (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
OSTI Identifier:
1515205
Alternate Identifier(s):
OSTI ID: 1440791
Report Number(s):
SAND-2019-4371J
Journal ID: ISSN 1463-9262; GRCHFJ; 674818
Grant/Contract Number:  
AC04-94AL85000; AC02-05CH11231; NA-0003525; AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Green Chemistry
Additional Journal Information:
Journal Volume: 20; Journal Issue: 13; Journal ID: ISSN 1463-9262
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kent, Michael S., Zeng, Jijiao, Rader, Nadeya, Avina, Isaac C., Simoes, Casey T., Brenden, Christopher K., Busse, Michael L., Watt, John, Giron, Nicholas H., Alam, Todd M., Allendorf, Mark D., Simmons, Blake A., Bell, Nelson S., and Sale, Kenneth L. Efficient conversion of lignin into a water-soluble polymer by a chelator-mediated Fenton reaction: optimization of H 2 O 2 use and performance as a dispersant. United States: N. p., 2018. Web. doi:10.1039/C7GC03459H.
Copy to clipboard
Kent, Michael S., Zeng, Jijiao, Rader, Nadeya, Avina, Isaac C., Simoes, Casey T., Brenden, Christopher K., Busse, Michael L., Watt, John, Giron, Nicholas H., Alam, Todd M., Allendorf, Mark D., Simmons, Blake A., Bell, Nelson S., & Sale, Kenneth L. Efficient conversion of lignin into a water-soluble polymer by a chelator-mediated Fenton reaction: optimization of H 2 O 2 use and performance as a dispersant. United States. https://doi.org/10.1039/C7GC03459H
Copy to clipboard
Kent, Michael S., Zeng, Jijiao, Rader, Nadeya, Avina, Isaac C., Simoes, Casey T., Brenden, Christopher K., Busse, Michael L., Watt, John, Giron, Nicholas H., Alam, Todd M., Allendorf, Mark D., Simmons, Blake A., Bell, Nelson S., and Sale, Kenneth L. Thu . "Efficient conversion of lignin into a water-soluble polymer by a chelator-mediated Fenton reaction: optimization of H 2 O 2 use and performance as a dispersant". United States. https://doi.org/10.1039/C7GC03459H. https://www.osti.gov/servlets/purl/1515205.
Copy to clipboard
@article{osti_1515205,
title = {Efficient conversion of lignin into a water-soluble polymer by a chelator-mediated Fenton reaction: optimization of H 2 O 2 use and performance as a dispersant},
author = {Kent, Michael S. and Zeng, Jijiao and Rader, Nadeya and Avina, Isaac C. and Simoes, Casey T. and Brenden, Christopher K. and Busse, Michael L. and Watt, John and Giron, Nicholas H. and Alam, Todd M. and Allendorf, Mark D. and Simmons, Blake A. and Bell, Nelson S. and Sale, Kenneth L.},
abstractNote = {Transforming lignin into a water-soluble polymer.},
doi = {10.1039/C7GC03459H},
journal = {Green Chemistry},
number = 13,
volume = 20,
place = {United States},
year = {Thu May 24 00:00:00 EDT 2018},
month = {Thu May 24 00:00:00 EDT 2018}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C7GC03459H
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 28 works
Citation information provided by
Web of Science

Figures / Tables:

Fig. 1 Fig. 1: a). Decrease in film thickness as a function of [H202]o/ [FeCl2]o for FEN with [FeCl2]o ranging from 0 mM to 2.5 mM and [H202]o ranging from 1 wt % to 15 wt%. b). Decrease in film thickness as a function of [H202]o / [FeCI3}o for CMF with [FeC13]omore » ranging from 0 mM to 4 mM and [H202]o ranging from 1 wt % to 15 wt%. c). Decrease in film thickness normalized to the concentration of H2O2, used for CMF as a function of [FeCI3]o.« less
All figures and tables (9 total)
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Enhanced hydroxyl radical production by dihydroxybenzene-driven Fenton reactions: implications for wood biodegradation
journal, July 2007

  • Contreras, David; Rodríguez, Jaime; Freer, Juanita
  • JBIC Journal of Biological Inorganic Chemistry, Vol. 12, Issue 7
  • DOI: 10.1007/s00775-007-0274-2

The effect of metal ions on the reaction of hydrogen peroxide with Kraft lignin model compounds
journal, June 1999

  • Sun, Yujun; Fenster, Michael; Yu, Annie
  • Canadian Journal of Chemistry, Vol. 77, Issue 5-6
  • DOI: 10.1139/v99-036

Floatability of chalcopyrite and molybdenite in the presence of lignosulfonates. Part I. Adsorption studies
journal, May 2007

Oxidation of Kraft Lignin with Hydrogen Peroxide and its Application as a Dispersant for Kaolin Suspensions
journal, October 2017

Advanced Oxidation Processes for Wastewater Treatment in the Pulp and Paper Industry: A Review
journal, June 2014

  • G. Covinich, Laura; I. Bengoechea, Dora; J. Fenoglio, Rosa
  • American Journal of Environmental Engineering, Vol. 4, Issue 3
  • DOI: 10.5923/j.ajee.20140403.03

Vibrational spectra of two Fe(III)/EDTA complexes useful for iron supplementation
journal, February 2010

  • Wagner, Claudia C.; Baran, Enrique J.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 75, Issue 2
  • DOI: 10.1016/j.saa.2009.11.059

Polymeric surfactants in disperse systems
journal, March 2009

Fenton's reagent revisited
journal, April 1975

Kinetic modeling of Fenton oxidation of phenol and monochlorophenols
journal, June 2002

Importance of H2O2/Fe2+ ratio in Fenton's treatment of a carpet dyeing wastewater
journal, August 2006

Changes in Solution Color During Phenol Oxidation by Fenton Reagent
journal, September 2006

  • Mijangos, Federico; Varona, Fernando; Villota, Natalia
  • Environmental Science & Technology, Vol. 40, Issue 17
  • DOI: 10.1021/es060866q

Steady-state generation of hydrogen peroxide: kinetics and stability of alcohol oxidase immobilized on nanoporous alumina
journal, December 2012

  • Kjellander, Marcus; Götz, Kathrin; Liljeruhm, Josefine
  • Biotechnology Letters, Vol. 35, Issue 4
  • DOI: 10.1007/s10529-012-1110-5

Production and Application of Lignosulfonates and Sulfonated Lignin
journal, April 2017

Biological valorization of low molecular weight lignin
journal, December 2016

Reduction reactivity of catecholamines and their ability to promote a Fenton reaction
journal, November 2016

Structural Characterization of Switchgrass Lignin after Ethanol Organosolv Pretreatment
journal, December 2011

  • Hu, Gang; Cateto, Carolina; Pu, Yunqiao
  • Energy & Fuels, Vol. 26, Issue 1
  • DOI: 10.1021/ef201477p

Characterisation of structure-dependent functional properties of lignin with infrared spectroscopy
journal, September 2004

  • Boeriu, Carmen G.; Bravo, Dominique; Gosselink, Richard J. A.
  • Industrial Crops and Products, Vol. 20, Issue 2
  • DOI: 10.1016/j.indcrop.2004.04.022

Reactive oxygen species as agents of wood decay by fungi
journal, April 2002

  • Hammel, Kenneth E.; Kapich, Alexander N.; Jensen, Kenneth A.
  • Enzyme and Microbial Technology, Vol. 30, Issue 4
  • DOI: 10.1016/S0141-0229(02)00011-X

In‐situ Enzymatic Generation of Hydrogen Peroxide for Bleaching Purposes
journal, June 2008

Advances in modifying lignin for enhanced biofuel production
journal, June 2010

  • Simmons, Blake A.; Loqué, Dominique; Ralph, John
  • Current Opinion in Plant Biology, Vol. 13, Issue 3, p. 312-319
  • DOI: 10.1016/j.pbi.2010.03.001

Infrared Spectroscopy of Aqueous Carboxylic Acids:  Malic Acid
journal, July 2002

  • Max, Jean-Joseph; Chapados, Camille
  • The Journal of Physical Chemistry A, Vol. 106, Issue 27
  • DOI: 10.1021/jp014377i

Dihydroxybenzenes: driven Fenton reactions
journal, September 2001

  • Rodríguez, J.; Parra, C.; Contreras, D.
  • Water Science and Technology, Vol. 44, Issue 5
  • DOI: 10.2166/wst.2001.0299

Lignin valorization through integrated biological funneling and chemical catalysis
journal, August 2014

  • Linger, J. G.; Vardon, D. R.; Guarnieri, M. T.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 33, p. 12013-12018
  • DOI: 10.1073/pnas.1410657111

Lignin depolymerization by fungal secretomes and a microbial sink
journal, January 2016

  • Salvachúa, Davinia; Katahira, Rui; Cleveland, Nicholas S.
  • Green Chemistry, Vol. 18, Issue 22
  • DOI: 10.1039/C6GC01531J

Fe(III)-Coordination Properties of Neuromelanin Components:  5,6-Dihydroxyindole and 5,6-Dihydroxyindole-2-carboxylic Acid
journal, May 2006

  • Charkoudian, Louise K.; Franz, Katherine J.
  • Inorganic Chemistry, Vol. 45, Issue 9
  • DOI: 10.1021/ic060014r

Biorefinery Lignosulfonates from Sulfite-Pretreated Softwoods as Dispersant for Graphite
journal, March 2016

Production of Fenton's reagent by cellobiose oxidase from cellulolytic cultures of Phanerochaete chrysosporium
journal, September 1992

Classification of Lignins from Different Botanical Origins by FT-IR Spectroscopy
journal, January 1991

Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014

  • Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
  • Science, Vol. 344, Issue 6185, p. 1246843-1246843
  • DOI: 10.1126/science.1246843

Comparative study of oxidation of dye-Reactive Black B by different advanced oxidation processes: Fenton, electro-Fenton and photo-Fenton
journal, June 2008

Fenton's Reagent-Mediated Degradation of Residual Kraft Black Liquor
journal, January 2002

  • Araujo, Elisa; Rodríguez-Malaver, Antonio J.; González, Aura M.
  • Applied Biochemistry and Biotechnology, Vol. 97, Issue 2
  • DOI: 10.1385/ABAB:97:2:091

Stochiometry of Fenton's Reagent in the Oxidation of Chlorinated Aliphatic Organic Pollutants
journal, January 1997

Sorbic acid as friendly curing agent for enhanced properties of ethylene propylene diene monomer rubber using gamma radiation
journal, August 2017

Investigation of the Molecular Weight Increase of Commercial Lignosulfonates by Laccase Catalysis
journal, April 2010

  • Areskogh, Dimitri; Li, Jiebing; Gellerstedt, Göran
  • Biomacromolecules, Vol. 11, Issue 4
  • DOI: 10.1021/bm901258v

Degradation of recalcitrant compounds by catechol-driven Fenton reaction
journal, February 2004

  • Rodriguez, J.; Contreras, D.; Oviedo, C.
  • Water Science and Technology, Vol. 49, Issue 4
  • DOI: 10.2166/wst.2004.0226

Physicochemical characterisation of sugar cane bagasse lignin oxidized by hydrogen peroxide
journal, April 2010

Lignocellulosic polysaccharides and lignin degradation by wood decay fungi: the relevance of nonenzymatic Fenton-based reactions
journal, August 2010

  • Arantes, Valdeir; Milagres, Adriane M. F.; Filley, Timothy R.
  • Journal of Industrial Microbiology & Biotechnology, Vol. 38, Issue 4
  • DOI: 10.1007/s10295-010-0798-2

Pretreatment of lignocellulosic biomass using Fenton chemistry
journal, June 2014

Quality carbon fibers from fractionated lignin
journal, January 2017

  • Li, Qiang; Xie, Shangxian; Serem, Wilson K.
  • Green Chemistry, Vol. 19, Issue 7
  • DOI: 10.1039/C6GC03555H

Veratryl alcohol degradation by a catechol-driven Fenton reaction as lignin oxidation by brown-rot fungi model
journal, January 2006

  • Contreras, David; Freer, Juanita; Rodríguez, Jaime
  • International Biodeterioration & Biodegradation, Vol. 57, Issue 1
  • DOI: 10.1016/j.ibiod.2005.11.003

Biomimetic Fenton-Catalyzed Lignin Depolymerization to High-Value Aromatics and Dicarboxylic Acids
journal, February 2015

The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
journal, June 2010

  • Zakzeski, Joseph; Bruijnincx, Pieter C. A.; Jongerius, Anna L.
  • Chemical Reviews, Vol. 110, Issue 6, p. 3552-3599
  • DOI: 10.1021/cr900354u

Opportunities and challenges in biological lignin valorization
journal, December 2016

Influence of Oxygen and Mediators on Laccase-Catalyzed Polymerization of Lignosulfonate
journal, June 2016

  • Huber, Daniela; Ortner, Andreas; Daxbacher, Andreas
  • ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 10
  • DOI: 10.1021/acssuschemeng.6b00692

Understanding pretreatment efficacy of four cholinium and imidazolium ionic liquids by chemistry and computation
journal, January 2014

  • Sun, Ning; Parthasarathi, Ramakrishnan; Socha, Aaron M.
  • Green Chem., Vol. 16, Issue 5
  • DOI: 10.1039/C3GC42401D

Do the extracellular enzymes cellobiose dehydrogenase and manganese peroxidase form a pathway in lignin biodegradation?
journal, July 2000

Degradation and decolorization of a biodegradable-resistant polymeric dye by chelator-mediated Fenton reactions
journal, June 2006

415. Infrared absorption of substituents in aromatic systemes. Part I. Methoxy- and ethoxy-compounds
journal, January 1959

  • Katritzky, A. R.; Coats, N. A.
  • Journal of the Chemical Society (Resumed)
  • DOI: 10.1039/jr9590002062

Assay for lignin breakdown based on lignin films: insights into the Fenton reaction with insoluble lignin
journal, January 2015

  • Kent, Michael S.; Avina, Isaac C.; Rader, Nadeya
  • Green Chemistry, Vol. 17, Issue 10
  • DOI: 10.1039/C5GC01083G

The Reactivity and Reaction Pathway of Fenton Reactions Driven by Substituted 1,2-Dihydroxybenzenes
journal, March 2017

  • Salgado, Pablo; Melin, Victoria; Durán, Yasna
  • Environmental Science & Technology, Vol. 51, Issue 7
  • DOI: 10.1021/acs.est.6b05388

Role of Quinone Intermediates as Electron Shuttles in Fenton and Photoassisted Fenton Oxidations of Aromatic Compounds
journal, August 1997

  • Chen, Ruzhong; Pignatello, Joseph J.
  • Environmental Science & Technology, Vol. 31, Issue 8
  • DOI: 10.1021/es9610646

Base-Catalyzed Depolymerization of Solid Lignin-Rich Streams Enables Microbial Conversion
journal, August 2017

  • Rodriguez, Alberto; Salvachúa, Davinia; Katahira, Rui
  • ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 9
  • DOI: 10.1021/acssuschemeng.7b01818

Poly(maleic acid) – A novel dispersant for aqueous alumina slurry
journal, June 2013

  • Mohanty, Saralasrita; Das, Bodhisatwa; Dhara, Santanu
  • Journal of Asian Ceramic Societies, Vol. 1, Issue 2
  • DOI: 10.1016/j.jascer.2013.05.005

Applications Of Percolation Theory
reference-book, January 2014

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Oxidative Depolymerisation of Lignosulphonate Lignin into Low-Molecular-Weight Products with Cu–Mn/δ-Al2O3
    journal, March 2019

    Ce 3+ self-doped CeO x /FeOCl: an efficient Fenton catalyst for phenol degradation under mild conditions
    journal, January 2019

    • Zhang, Jian; Yang, Mengxue; Lian, Ye
    • Dalton Transactions, Vol. 48, Issue 10
    • DOI: 10.1039/c8dt04269a

    Lignin Biopolymers in the Age of Controlled Polymerization
    journal, July 2019

    • Ganewatta, Mitra S.; Lokupitiya, Hasala N.; Tang, Chuanbing
    • Polymers, Vol. 11, Issue 7
    • DOI: 10.3390/polym11071176
      Sort by:
      [ × clear filter / sort ]

      Figures / Tables found in this record:

      Fig. 1 (p. 4)figure
      Fig. 2 (p. 5)figure
      Fig. 3 (p. 7)figure
      Fig. 4 (p. 8)figure
      Fig. 5 (p. 9)figure
      Fig. 6 (p. 9)figure
      Fig. 7 (p. 10)figure
      Fig. 8 (p. 10)figure
      Fig. 9 (p. 11)figure
        [ × clear filter / sort ]
        Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

        Similar Records in DOE PAGES and OSTI.GOV collections: